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西昆仑康西瓦北侧蒙古包—普守—带早古生代花岗岩锆石SHRIMP U—Pb测年 总被引：2，自引：0，他引：2
依据1:25万康西瓦幅区域地质调查成果,重点对西昆仑康西瓦北侧蒙古包—普守一带早古生代花岗岩的岩石学、岩石地球化学及同位素年代学进行了综合研究。岩石学和地球化学特征表明,该花岗岩为高钾钙碱性花岗岩类,锆石SHRIMP U-Pb年龄为443.1 Ma±2.3Ma和430.7Ma±2,6Ma,形成时代为晚奥陶世—早志留世。该成果的获得,为进一步系统地研究蒙古包—普守早古生代蛇绿混杂岩带及与其配套的早古生代花岗岩提供了直接的时代证据,为进一步深入地研究西昆仑造山带的地质构造演化提供了新的实际资料。 相似文献
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依据1∶25万康西瓦幅区域地质调查成果,重点对西昆仑康西瓦北侧蒙古包-普守一带早古生代花岗岩的岩石学、岩石地球化学及同位素年代学进行了综合研究.岩石学和地球化学特征表明,该花岗岩为高钾钙碱性花岗岩类,锆石SHRIMP U-Pb年龄为443.1 Ma±2.3 Ma和430.7 Ma±2.6 Ma,形成时代为晚奥陶世-早志留世.该成果的获得,为进一步系统地研究蒙古包-普守早古生代蛇绿混杂岩带及与其配套的早古生代花岗岩提供了直接的时代证据,为进一步深入地研究西昆仑造山带的地质构造演化提供了新的实际资料. 相似文献
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西昆仑康西瓦北侧早古生代角闪闪长岩、英云闪长岩的地质特征及其锆石SHRIMP U-pb测试 总被引：7，自引：3，他引：7
西昆仑康西瓦北侧蒙古包-普守一带的早古生代俯冲-碰撞型角闪闪长岩、英云闪长岩和黑云二长花岗岩,是开展125万康西瓦幅等4幅区域地质调查项目时发现的.重点对蒙古包早古生代俯冲型角闪闪长岩、英云闪长岩的岩石学、岩石地球化学特征及锆石同位素年代学进行了综合研究,获得了锆石SHRIMP U-Pb年龄440.5Ma±4.6Ma,其形成时代为晚奥陶世.该成果为进一步深入研究西昆仑造山带的地质构造演化提供了新的实际资料. 相似文献
4.
西昆仑康西瓦西北部库尔良早古生代角闪闪长岩花岗闪长岩锆石SHRIMP U—Pb测年 总被引：2，自引：3，他引：2
依据1:25万康西瓦幅区域地质调查成果,重点对库尔良早古生代深成岩的同位素年代学进行了详细的研究,获得了裂解期细粒黑云母角闪闪长岩锆石SHRIMP U-Pb年龄均值506.8Ma±9.8Ma,中粒似斑状花岗闪长岩单颗粒锆石U-Pb法年龄500.2Ma±1.2Ma,表明其形成时代均为中寒武世。该同位素年龄的获得,为进一步详细地研究库地-其曼于特早古生代构造-岩浆岩带的裂解时限提供了直接的时代证据。 相似文献
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西昆仑康西瓦西北部库尔良早古生代角闪闪长岩花岗闪长岩锆石ＳＨＲＩＭＰ Ｕ－Ｐｂ测年 总被引：1，自引：0，他引：1
依据１∶２５万康西瓦幅区域地质调查成果，重点对库尔良早古生代深成岩的同位素年代学进行了详细的研究，获得了裂解期细粒黑云母角闪闪长岩锆石ＳＨＲＩＭＰ Ｕ－Ｐｂ年龄均值５０６．８Ｍａ±９．８Ｍａ，中粒似斑状花岗闪长岩单颗粒锆石Ｕ－Ｐｂ法年龄５００．２Ｍａ±１．２Ｍａ，表明其形成时代均为中寒武世。该同位素年龄的获得，为进一步详细地研究库地－其曼于特早古生代构造－岩浆岩带的裂解时限提供了直接的时代证据。 相似文献
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康西瓦-苏巴什-鲸鱼湖混杂岩带作为昆仑造山带一条重要的混杂岩带,通常被认为是古特提斯洋的残存带,其形成时限一直受到地质界的密切关注。在该带新识别出一套蛇绿岩,采用LA-ICP-MS锆石U-Pb测年,获得该蛇绿岩铁镁质单元中辉长岩的年龄为270.3±0.7Ma(MSWD=0.65),枕状玄武岩年龄为263.4±7.4Ma(MSWD=1.5),属于晚二叠世,代表蛇绿岩的形成年龄。通过岩石地球化学特征、区域背景等分析,认为其形成于洋中脊环境,属于典型的MORB型蛇绿岩。结合主量、微量元素特征、构造环境及同位素年龄讨论,认为古特提斯洋主洋盆至少持续到晚二叠世。 相似文献
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四川木里杨房沟闪长岩体锆石U-Pb定年、地球化学特征及其构造意义 总被引：1，自引：0，他引：1
四川木里地区杨房沟黑云母石英闪长岩体位于甘孜-理塘蛇绿混杂岩带南段以东,其锆石U-Pb年龄值为210±1Ma,表明其成岩年龄为晚三叠世。岩体属于高钾钙碱性系列,其稀土元素配分曲线呈向右缓倾型,轻稀土元素富集明显,Eu负异常明显,表明岩浆演化过程中部分斜长石经历了结晶分离过程。构造环境判别图解显示,木里杨房沟黑云母石英闪长岩形成于与甘孜-理塘蛇绿混杂岩带闭合的火山弧构造环境。 相似文献
10.
莫钦乌拉山尤尔敦蛇绿混杂岩位于天山山脉东北部莫钦乌拉山,该区构造上为东准噶尔卡拉麦里构造带的向东延伸。通过野外地质调查、地球化学和年代学研究,初步查明尤尔敦蛇绿混杂岩基质与外来岩块的主要特征。基岩岩石化学特征表明,洋岩石圈残片形成于弧相关盆地,获得洋壳辉长岩锆石U-Pb年龄为（411.5±2.7）Ma。结合前人资料和区域地质特征,认为尤尔敦蛇绿混杂岩所代表的洋盆是卡拉麦里有限洋盆的向东延伸,形成于早—中泥盆世,晚泥盆世开始俯冲消减,于石炭世晚期闭合。 相似文献
11.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
12.
奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
14.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
16.
Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
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《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
20.
The Samchampi-Samteran alkaline igneous complex (SAC) is a near circular, plug-like body approximately 12 km2 area and is emplaced into the Precambrian gneissic terrain of the Karbi Anglong district of Assam. The host rocks, which
are exposed in immediate vicinity of the intrusion, comprise granite gneiss, migmatite, granodiorite, amphibolite, pegmatite
and quartz veins.
The SAC is composed of a wide variety of lithologies identified as syenitic fenite, magnetite ± perovskite ± apatite rock,
alkali pyroxenite, ijolite-melteigite, carbonatite, nepheline syenite with leucocratic and mesocratic variants, phonolite,
volcanic tuff, phosphatic rock and chert breccia.
The magnetite ± perovskite ± apatite rock was generated as a cumulus phase owing to the partitioning of Ti, Fe at a shallow
level magma chamber (not evolved DI = O1). The highly alkaline hydrous fluid activity indicated by the presence of strongly
alkalic minerals in carbonatites and associated alkaline rocks suggests that the composition of original melt was more alkalic
than those now found and represent a silica undersaturated ultramafic rock of carbonated olivine-poor nephelinite which splits
with falling temperature into two immiscible fractions—one ultimately crystallises as alkali pyroxenite/ijolite and the other
as carbonatite. The spatial distribution of varied lithotypes of SAC and their genetic relationships suggests that the silicate
and carbonate melts, produced through liquid immiscibility, during ascent generated into an array of lithotypes and also reaction
with the country rocks by alkali emanations produced fenitic aureoles (nephelinisation process). Isotopic studies (δ18O and δ13C) on carbonatites of Samchampi have indicated that the δ13C of the source magma is related to contamination from recycled carbon. 相似文献