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1.
在野外地质调查和室内综合研究的基础上,通过对黄梅尖地区辉绿玢岩K-Ar年代学、地球化学和Sr-Nd同位素特征进行研究,探讨辉绿玢岩的形成时代、岩石成因及构造背景。K-Ar年代学研究表明,辉绿玢岩形成于~107 Ma,是早白垩世岩浆活动的产物,形成时代晚于该地区火山岩和侵入岩,与该地区铀成矿年龄基本一致;辉绿玢岩的侵入可能是该地区岩浆作用的最后一幕,铀成矿可能与辉绿玢岩具有成因联系。地球化学特征表明,辉绿玢岩富集大离子亲石元素K、Rb、U、Pb和轻稀土元素,亏损高场强元素Nb、Ta、P、Ti,具有较高的Isr值和负εNd(t)值,具有富集地幔源区特征;辉绿玢岩是在地壳伸展和岩石圈减薄的构造背景下,由俯冲交代作用形成的富集地幔部分熔融形成的,表明~107 Ma时该地区仍处于伸展构造环境下。  相似文献   

2.
对浙西新路火山盆地发育的辉绿岩进行了激光显微探针40Ar-39Ar定年和系统的岩石地球化学特征研究。研究表明, 新路盆地辉绿岩成岩时代为(93±3) Ma, 属晚白垩世产物; 岩石中辉石有单斜辉石和斜方辉石两个种属, 斜长石为拉长石; SiO2含量介于44.00%~50.09%之间, 具有富碱(平均为5.15%)、高钾(K2O/Na2O平均为1.08)、低TiO2含量(平均为1.15%)等特征; 岩石具有原生岩浆特点, 显示典型的钾玄岩特征。钾玄岩富集LREE、大离子亲石元素和强不相容元素, 无Eu亏损; 锶初始值(Isr)介于0.70707~0.70870之间, (143Nd/144Nd)i介于0.512338~0.512407之间; Δ7/4Pb为6.0~9.2、Δ8/4Pb为48.5~68.0、DSr为70.73~87.04, 均表现出富集地幔特征。认为新路盆地钾玄岩的厘定对该区域岩石圈与构造岩浆演化的深入研究具有重要意义; 钾玄岩形成与造山带后碰撞期的热点活动相关; 钾玄岩侵位年龄基本限定了新路地区岩石圈大规模减薄的时限; 推测热点活动导致岩石圈减薄的动力学演化过程及其壳幔作用源区可能对火山岩型铀成矿起着重要的制约作用。  相似文献   

3.
燕山地区中牛代中基性火山岩包括钙碱性-高钾钙碱性-钾玄岩系列,岩石类型包括粗叫玄武岩、玄武质安山岩、玄武质粗面安山岩、粗安岩,具有LREE富集的右倾平滑稀土配分模式,富集LILE(如Ba,K),亏损Nb-Ta和Th—U的微址元素特征,Sr-Nd同位素组成中等富集,与华北内部和兴蒙带中生代基性火山岩具有不同的特征,其Nd同位素组成和(Nb/La)s,(Hf/Sm)s比值都介于华北陆块内部和兴蒙造山带之间,反映了其熔融地幔源区继承了华北陆块内部的EMI型地幔特征外,还很可能受到俯冲板片交代作用的影响,暗示了古亚洲洋板块消减过程对华北陆缘岩石圈地幔的改造作用。类似于华北陆块南缘岩石圈减薄和置换机制,古亚洲洋俯冲板块对燕山地区古老岩石圈的交代作用在岩石圈减薄和置换过程中起了很重要的作用,而不同于华北板块内部以软流圈沿地幔薄弱带或剪切带上升熔蚀和置换岩石圈的机制  相似文献   

4.
鄂尔多斯盆地西南边部出露的铜城超钾质岩,分布在甘肃省崇信县铜城镇以南的桃梢屲—庙滩一带,为浅成侵入岩墙,斑状结构,块状构造;岩性为霓辉黑榴二长斑岩与假白榴石斑岩.斑晶矿物成分以含白榴石、黑榴石、霓辉石及两种长石为特征;地球化学显示:主量元素以富集K2O、Al2O3、CaO而贫SiO2、MgO、TiO2、P2O5为特征,微量元素以富含大离子亲石元素(LILE)K、Rb、Sr、Ba、Pb而贫高场强元素(HFSE)Nb、Ta、Zr、Hf为特征,地幔起源环境可能为EMI型富集地幔;两种岩性锆石U-Pb年龄显示其形成年龄(110.8±1.0)Ma和(107.6±0.9)Ma,为早白垩世.因此笔者认为:早白垩世华北克拉通东部陆块发生岩石圈大幅减薄作用过程中,陆块西部岩石圈也有相应岩石圈减薄作用发生.  相似文献   

5.
诸广岩体南部的晚白垩世辉绿玢岩位于西部九峰岩体中部,呈近SN向展布.它具有较高的Al2O3(15.76%~18.70%),K2O(1.97%~3.17%),Na2O(4.20%~4.98%)含量和较低的TiO2(2.76%~2.84%),SiO2(46.75%~50.41%)含量.所有样品Na2O>K2O(Na2O/K2O=1.37~2.13)、大离子亲石元素(Ba,Rb,K,Th)富集明显、Cr和Ni的含量明显低于原始玄武岩浆的参考值;样品中稀土总量较高(158.4×10-6~191.6×10-6),轻稀土富集(LREE/HREE=6.45~6.56),基本无Eu异常(δEu=0.93~0.96).且具有低的εNd(t)值(-0.9~-2.2)、较高的(87Sr/86Sr)I值(0.71276~0.71312)和典型的Dupal异常铅特征.在Nd-Sr和Nd-Pb图解上,辉绿玢岩具有DMM和EMⅡ端员混合特征.这种富集特征不是由地幔岩浆上升过程中与地壳物质之间的同化混染作用造成.而是归因于俯冲带流体对上覆地幔楔的交代改造.因此,诸广岩体南部的辉绿玢岩是在晚白垩世时期地壳伸展和岩石圈减薄的构造环境下,由具有DMM和EMⅡ地幔端员混合特征的富集地幔源区部分熔融形成的.  相似文献   

6.
吉林晚古生代榆木川基性岩的地球化学特征及其岩石成因   总被引:2,自引:0,他引:2  
位于兴蒙造山带张广才岭块体的榆木川辉绿玢岩,K—AT年龄测定表明其形成年龄为262~264Ma,主微量元素研究表明,辉绿玢岩SiO2含量为47.02%~52.60%,贫K2O(0.13%~0.47%),Na2O〉K2O,属于低钾拉斑系列,稀土分布模式属于轻稀土略亏损的平坦型,微量元素原始地幔标准化图解中大离子亲石元素(Rh、Ba、Sr)较为富集,但不存在高场强元素(Nb、Ta)的亏损,同位素组成显示Sr同位素初始比值在0.704958~0.705631之间,εNd(t)值(72~81)较高且变化较小,表明其来源于亏损地幔的部分熔融且成岩过程中未受到地壳物质的混染。基性岩形成于造山后的伸展拉张背景,并结合前人的研究成果,认为晚古生代(约270Ma)兴蒙造山带已经进入晚期,此时加厚的岩石圈由于重力不稳定发生拆沉减薄作用,导致软流圈的大量上涌和岩石圈拉张,从而引起先存亏损岩石圈地幔的部分熔融,最后侵入地壳深部形成研究区辉绿玢岩。  相似文献   

7.
卡拉麦里钾质火山岩位于准噶尔盆地的东北缘下石炭统巴塔玛依内山组内。这些火山岩以粗面玄武岩和玄武质粗面安山岩为主,SiO2含量稳定(46.29%~51.56%),具有较高的碱含量(K2O+Na2O=5.39%~6.96%)以及高K2O/Na2O比值(K2O/Na2O=0.5~1.4),TiO2含量相对稳定(0.94%~1.21%),显示钾玄质岩石特征。岩石地球化学表明,钾玄岩强烈富集LILE(如K、Rb和Sr)和LREE((La/Yb)N=4.39~6.25),Eu正异常明显(δEu=1.3~1.7),相对亏损HFSE(如Zr、Hf),Ta、Nb和Ti呈明显的"TNT"负异常,及较高Ba/Nb和Ba/Ta比值(分别为38~93,574~1470),显示典型岛弧岩浆特征,而Nd-Sr同位素显示亏损地幔源区特征。不相容元素(Nb/La)N和Ba/La比值(分别为0.33~0.41,11.07~18.82)以及高Nb含量(4.45×10-6~7.76×10-6),表明这些岩石来自一个交代作用富集的地幔源区。通过钾质火山岩环境的梯次判别图研究,发现巴塔玛依内山组钾玄岩形成于后碰撞环境,显示岛弧的岩石地球化学特征。在后碰撞期,由于陆内调整和均衡作用,东准噶尔东北缘的岩石圈伸展减薄,随着岩石圈地幔的减薄,前期交代富集的下部地幔楔(金云母和/或钾质角闪石-尖晶石相二辉橄榄岩)发生低度部分熔融形成钾玄质母岩浆,诱发了后碰撞型钾玄质岩浆活动(具有弧火山岩岩石地球化学特征),形成了卡拉麦里巴塔玛依内山组钾质玄武岩。  相似文献   

8.
闫峻  陈江峰  谢智  杨刚  喻钢  钱卉 《地球化学》2005,34(5):455-469
长江中下游地区繁昌火山盆地蝌蚪山晚白垩世玄武岩为硅饱和岩石, SiO2含量在 47.63%~ 50.02%之间,在 TAS图上位于碱性和亚碱性的分界线上,多数属于玄武岩,少数为粗面玄武岩. MgO含量较低( 3.72%~ 5.58%),但 Mg#值较高( 61~ 71).岩石富集大离子亲石元素 Ba、 Th、 U、 LREE和 Pb,亏损高场强元素 Nb、 Zr和 Ti,具富集的 Sr、 Nd和 Pb同位素组成.初始 87Sr/86Sr(t)比值介于 0.706 5~ 0.706 6之间,ε Nd(t)值介于-5.5~-7.3之间.在 87Sr/86Sr(t)-ε Nd(t)相关图上投在富集的第Ⅳ象限,并趋向于 EMⅡ地幔端员. 206Pb/204Pb(t)、 207Pb/204Pb(t)和 208Pb/204Pb(t)比值分别为 17.928~ 18.311、 15.426~ 15.621和 37.785~ 38.525,在 Pb同位素相关图上处在 DMM和 EMⅡ地幔端员之间.蝌蚪山玄武岩的地球化学特征表明其原始岩浆来源于岩石圈地幔,底侵到壳幔边界后曾有一段时间的滞留,并经历了一定程度的以橄榄石和斜方辉石为主的结晶分异,随后在上升过程中没有受到明显的地壳物质的混染.本地区晚中生代时期陆下岩石圈地幔具有同位素富集的性质,曾受到过古老俯冲事件中析出流体 /熔体的交代.与本地区新生代玄武岩地球化学性质的对比表明,从晚中生代至新生代,由于岩石圈拉张和软流圈的上涌,长江中下游地区发生了岩石圈的减薄,其过程和华北地块东部的岩石圈减薄事件基本一致.造成华北地块东部和华南地块东部的岩石圈减薄具有一致的动力学机制和背景,很可能是晚中生代时期古太平洋板块向亚洲大陆之下俯冲造成的弧后盆地的拉张减薄.  相似文献   

9.
新疆东天山黄山岩体岩石地球化学特征与岩石成因   总被引:1,自引:0,他引:1  
黄山岩体位于东天山北部的土墩-黄山-图拉尔根镁铁-超镁铁质岩带中段,受康古尔塔格-黄山韧性剪切带控制,主要由橄榄岩、橄榄二辉岩、辉石岩、辉长苏长岩、辉长岩以及辉长闪长岩组成.岩石化学组成属拉斑玄武岩系列,普遍富集大离子亲石元素(Rb,Ba,Sr),亏损高场强元素(Nb,Ta,Ti).岩体εNd(t)=+4.1~+9.2,除3件样品εSr(t)为+2.2,+12.5和+15.4,大部分εSr(t)=(-22.5~-4.5),Nd,Sr同位素组成基本属亏损型地幔特征;Pb同住素初始值(206Pb/204Pb)i=18.081~18.413,(207Pb/204Pb)i=15.441~15.513,(208Pb/204Pb)i=37.461 6~37.899,具有MORB亲和性.岩相学及岩石地球化学特征显示岩浆演化过程中主要发生了橄榄石、斜方辉石、单斜辉石和斜长石的分离结晶作用.岩浆演化晚期阶段发生了一定程度的同化混染作用,元素地球化学和Nd,Sr,Pb同位素体系证明,岩浆源区主体由软流圈地幔物质组成,同时也有一定量富集型岩石圈地幔组份加入.黄山岩体是岩石圈根部拆沉加热熔融和软流圈地幔上涌减压熔融的产物,这种地幔动力学机制应该对应于后碰撞伸展环境.  相似文献   

10.
内蒙古四子王旗地区发现有一套早白垩世钾玄岩。主量元素、微量元素、稀土元素以及 Sr-Nd 同位素测试结果表明,岩石以低硅(SiO_2含量为48.11%~52.77%)、高钛(TiO_2含量为1.94%~2.77%,平均2.48%)、高钾高碱(K_2O Na_2O 为5.32%~7.02%、K_2O/Na_2O 比值为0.48~1.10)为特征,属于钾玄岩系列。它们富集大离子亲石元素、轻稀土元素,亏损高场强元素,具有微弱的 Eu 负异常(δEu=0.81~0.98),其地球化学特征总体与洋岛玄武岩(OIB)相似。Rb/Nb、Ba/Nb、La/Nb、K/Nb 和 Zr/Nb 比值主要落在 EM I OIB 范围内。~(87)Sr/~(86)Sr 和~(143)Nd/~(144)Nd 比值分别变化在0.7063~0.7077和0.51196~0.51243之间,岩石的 Nd、Sr 同位素组成接近 EM I 地幔端元。随着ε_(Nd)的减小,P_2O_5、Rh、Sr、Ba 和 Zr 逐渐富集,表明四子王旗钾玄岩没有经历明显的地壳物质混染。利用微量元素地球化学原理,推断四子王旗钾玄岩母岩浆源于含金云母地幔橄榄岩减压低度部分熔融。根据其地球化学特征可以认为,四子王旗钾玄岩是华北板块早白垩世岩石圈减薄事件的产物。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

15.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

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17.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

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We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2O3-SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.  相似文献   

20.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

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