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1.
茶庵岩体位于秦岭造山带东段,岩体的主要岩性为二云母花岗岩。岩石地球化学分析结果显示,茶庵岩体w(SiO2)为73.22%~75.29%,w(K_2O)为4.11%~4.74%,w(Na_2O)为3.68%~4.34%,w(Al_2 O_3)为13.90%~15.31%,具有高钾钙碱性和过铝质(ACNK=1.03~1.17)特征。岩石稀土总量较低(22.02×10-6~84.18×10-6),轻稀土元素相对富集,重稀土元素相对亏损,具有Eu的负异常,岩体富集Rb、U、Hf和Y,亏损Ba、Nb、Ta和Ti,显示出I型花岗岩的特点,形成于碰撞造山后的伸展构造环境。  相似文献   

2.
北祁连山中段北大坂岩体成因及构造环境讨论   总被引:1,自引:0,他引:1  
运用岩石学的研究方法对出露于北祁连造山带中段北大坂一带的北大坂岩体进行岩石及元素分析结果表明:其岩性为斑状粗粒二长花岗岩、粗中粒二长花岗岩及中细粒二长花岗岩,含少量黑云母、角闪石及榍石,属钾质钙碱性花岗岩类;主量元素w(SiO2)=63.66%~74.38%,w(K2O)/w(Na2O)=2.61~3.31,总体为高钾钙碱性弱过铝质花岗岩,岩石富集LILE元素(Rb,Th,K等),亏损HFSE元素(Y,Yb,Ta,Nb等),稀土元素分配模式为轻稀土富集型,具中等负Eu异常(δEu=0.59~0.82)。微量、稀土元素分配模式与北祁连西段的金佛寺岩体(碰撞型花岗岩)基本一致。单颗粒锆石U-Pb年龄为414Ma±4Ma,综合分析认为北大坂岩体形成于同碰撞末-后碰撞初期的构造转换期,岩浆源区为下地壳。  相似文献   

3.
为了解赣中金滩岩体黑云母花岗岩和二云母花岗岩的岩石成因及其差异,探讨二云母花岗岩中铀的富集机制,利用电子探针对两类岩石中的黑云母进行了分析,并进行了岩相学和矿物化学研究。结果显示,黑云母花岗岩中的黑云母为镁质黑云母和铁质黑云母,二云母花岗岩中的黑云母为铁质黑云母。黑云母花岗岩的结晶温度为660~722℃(平均692℃),二云母花岗岩的结晶温度为630~691℃(平均669℃);二云母花岗岩相对黑云母花岗岩具有更低的氧逸度条件,但二者都具有相当高的氟含量。综合黑云母化学成分和岩石地球化学特征,认为二云母花岗岩的源区富铀特征是导致铀富集并形成富铀花岗岩的物质前提,低温、低氧逸度和高F含量等物理化学条件是促使U富集的有利因素。  相似文献   

4.
燕山晚期花岗岩小岩体的岩性为细粒二云母花岗岩,出露于诸广岩体中南部塘湾矿床北部约4km的范围内。针对细粒二云母花岗岩进行了6块样品的主量元素、微量元素和稀土元素的分析。结果表明:该岩体表现为高钾钙碱性,SiO2质量分数高(75.27%~76.55%,平均值为75.86%);富碱(Na_2O+K_2O=7.48%~7.66%,平均值为7.55%),且钾大于钠;铝过饱和(A/CNK值介于1.11~1.22之间,平均1.16)的特点。微量元素中,富集Rb,Th,U,明显亏损Ba,Zr和Hf。稀土总含量不高,配分模式呈海鸥型,轻稀土分馏较明显,重稀土分馏较弱,以及强烈的铕负异常(δEu=0.15~0.20)等特征。推测其形成于岩石圈伸展减薄的环境下,源区主要由泥质岩组成。细粒二云母花岗岩与塘湾岩体的内外接触带与近SN向、NNE向构造复合部位为成矿的有利部位。  相似文献   

5.
对青藏高原西部燕山晚期花岗岩进行了地质,地球化学综合研究,结果表明,燕山晚期早白垩世花岗岩为I型,形成于火山弧环境,岩石组合为石英二长闪长岩-花岗闪长岩-二长花岗岩,岩石系列为高钾钙碱性系列,A/CNK〈1,稀土元素含量中等,并且属轻稀土富集型,铕亏损不明显,LILE有选择地得到富集,HFSE相对亏损;晚白垩世花风岩为S型,形成于同碰撞环境,岩石组合为二云母花岗岩-二云化岗岩,岩石系列为高钾钙碱性  相似文献   

6.
湖南邓阜仙复式花岗岩体的锆石U-Pb年代学研究   总被引:3,自引:0,他引:3  
邓阜仙钨矿及其所赋存的邓阜仙复式花岗岩体地处湘赣边境,位于茶陵县北东,距茶陵县城约50km。邓阜仙岩体由三期花岗岩体组成,分别是粗粒斑状黑云母花岗岩、中细粒二云母花岗岩和细粒白云母花岗岩,与石英脉型钨(锡)矿和岩体型铌钽矿有关。本文通过对黑云母花岗岩和二云母花岗岩样品的LA-ICP-MS锆石U-Pb年代学研究,初步探讨湖南邓阜仙复式花岗岩  相似文献   

7.
对藏东地区浪拉山糜棱岩化二长花岗岩进行了LA-ICP-MS锆石U-Pb年龄测试,获得了该岩体的206Pb/238 U年龄加权平均值为470.5 Ma±3.7 Ma(MSWD=1.7,n=15),属于中奥陶世的产物。岩石地球化学特征表明,岩石具有高钾(Na2O/K2O=13.12~162.89)、铝(A/CNK值平均为1.30)、低钛的特征,岩石属于高钾钙碱性过铝质S型花岗岩。岩石具有明显Eu负异常,表现为Nb,Sr,P、Ti等高场强元素相对亏损,相对富集K,Rb,Th,U等大离子亲石元素,具有岛弧型花岗岩的特征。结合区域地质资料分析,该岩体与区内原特提斯洋的俯冲存在成因联系,藏东地区浪拉山糜棱岩化二长花岗岩的发现有助于进一步探索原特提斯洋演化过程。  相似文献   

8.
秦岭造山带地处华北板块与扬子板块结合带,经历了复杂的构造演化过程,其板块拼合机制及碰撞时限一直备受争议.对东秦岭南召县五朵山岩体二云母花岗岩进行岩石地球化学和LA-ICP-MS锆石U-Pb年代学研究,结果表明岩石具有高硅(SiO2=69.32%~74.28%)、高铝(Al2O3=14.14~17.28)、高碱含量(Na2O+K2O=7.68%~9.03%)等特征,且相对富钾贫钠,在岩石类型上属于强过铝质"S"型花岗岩类.岩石具有中等的稀土元素含量,呈现轻稀土富集、重稀土亏损的右倾配分模式,中等的负Eu异常,富集K、Rb、Th等大离子亲石元素,亏损Ba、Nb、Sr、P、Ti等元素,表明南召县二云母花岗岩可能形成于陆陆碰撞所导致的陆壳加厚环境.LA-ICP-MS锆石U-Pb分析结果表明,二云母花岗岩锆石均具有明显的韵律环带,Th/U比值均大于0.4,暗示岩浆成因特征,206Pb/238U加权平均年龄为433±2 Ma;结合构造环境特征,表明东秦岭南召地区在早志留世末期由俯冲环境转换为陆陆碰撞环境.   相似文献   

9.
巴斯铁列克钨多金属矿床位于新疆阿尔泰造山带南缘,是近年来在区内发现的首例中型钨多金属矿床。矿体主要产于二叠纪花岗岩与上志留统-下泥盆统康布铁堡组火山-沉积岩接触带的矽卡岩中。钨矿化与矿区花岗质岩石有明显的空间关系。然而,与钨矿化有关的花岗质岩石成因尚不清楚。本文对矿区出露的与矿化关系密切的黑云母花岗岩、二长花岗岩和二云母花岗岩进行了锆石U-Pb年代学和岩石地球化学研究。3个样品的LA-ICP-MS锆石U-Pb加权平均年龄分别为282.3±3.2Ma、284.3±2.2Ma和284.8±2.3Ma,属早二叠世岩浆活动的产物,与成矿年龄一致。所有岩石具有高硅(Si O_2=73.6%~78.3%)、富碱(K_2O+Na_2O=5.15%~9.62%)富钾(K_2O/Na_2O> 1.1)、贫钙(Ca O=0.19%~0.75%)和钛(Ti O_2=0.04%~0.24%)、弱过铝-强过铝质(A/CNK=1.01~1.39)特征。这些岩石稀土元素总量(∑REE)变化较大(变化于20.3×10-6~328×10-6),但二云母花岗岩显示轻重稀土元素分异不明显((La/Yb)N=0.96~2.06)、Eu强烈负异常(δEu=0.07~0.41)的深"V"型稀土元素分布特征,黑云母花岗岩和二长花岗岩显示轻稀土略富集((La/Yb)N分别为2.8~5.5和4.8~7.4)且Eu负异常(δEu=0.33~0.39和0.34~0.63)明显的右倾型稀土元素分布特征。所有样品均显示相对富集Rb、Th、U、Pb元素和相对亏损Nb、Ti、P、Sr、Ba元素,但二云母花岗岩中W含量(4.6×10-6~9.4×10-6)相对低于黑云母花岗岩和二长花岗岩中W含量(分别为15.1×10-6~168×10-6和8.4×10-6~16.0×10-6)。所有样品的锆石具有正的高εHf(t)值(+3.8~+11)和相对年轻的亏损地幔模式年龄(Hf的tDM2为0.60~1.0Ga)。以上特征说明,这些岩石属高钾钙碱性分异I-A过渡型花岗岩。结合区域地质背景,认为这些岩体是二叠纪时期后碰撞伸展环境下两个独立岩浆事件的产物,母岩浆均来源于新生地壳熔体与幔源岩浆,经过高度分异演化后结晶形成矿区岩石。花岗质岩浆活动为巴斯铁列克钨矿床提供了成矿物质,岩浆演化过程(结晶分异与熔体-流体作用)对成矿元素有富集作用。  相似文献   

10.
青海南山构造带发育北西—南东向展布的印支期花岗岩带,其研究对厘清古特提斯演化阶段西秦岭造山带与南祁连构造带的衔接转换关系具有重要意义。当家寺花岗岩体是由花岗闪长岩和二长花岗岩组成的复合花岗岩基。本文对当家寺花岗岩体进行了详细的岩石学、岩石地球化学和LA-ICP-MS锆石U-Pb同位素年代学研究。结果表明,花岗闪长岩和二长花岗岩的结晶年龄分别为240.1±2.1 Ma和241.0±2.6 Ma,属于中三叠世。地球化学研究显示岩体相对高硅(SiO_2=66.37%~73.99%)和富钾(K_2O=3.37%~4.73%),属于准铝质—弱过铝质高钾钙碱性I型花岗岩。岩石稀土配分曲线表现为轻稀土富集的右倾型,具中等程度的铕负异常(δEu=0.32~0.64)。微量元素显示富集大离子亲石元素Cs、Rb、K,相对亏损高场强元素Nb、Ta、P、Ti。岩石成因研究表明其形成于下地壳基性岩为主的源岩的部分熔融,同时存在一定程度幔源岩浆贡献。结合区域地质背景资料,认为当家寺花岗岩体形成于洋壳俯冲阶段,可能为宗务隆洋向南俯冲的地球动力学背景下的产物。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

15.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

16.
17.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

19.
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2O3-SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.  相似文献   

20.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

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