柴北缘滩间山地区独树沟金矿花岗斑岩锆石U- Pb年代学、地球化学和Hf同位素   总被引：1，自引：0，他引：1  

李治华  李碧乐  李鹏 《地质学报》2020,94(12):3625-3642

本文报道了柴北缘滩间山地区独树沟金矿区花岗斑岩的地球化学、锆石U- Pb定年和Hf同位素的研究结果。全岩化学分析显示岩石具有富硅（SiO2=75. 23%~77. 28%）、钠（Na2O/K2O=1. 71~2. 41），贫铁（TFe2O3=1. 04%~3. 24%）、镁（MgO=0. 28%~0. 39%）、钙（CaO=0. 23%~0. 75%）、铝（Al2O3=13. 09%~13. 73%）的特征；样品富集大离子亲石元素如Rb、K、Th和U，明显亏损高场强元素Nb、Ta、Ti和 P，富集轻稀土元素，亏损重稀土元素，岩石具有较强的Eu负异常（δEu=0. 49~0. 53），分异指数DI为90. 76~93. 71，指示岩石发生了较强的结晶分异作用，通过与邻区花岗岩进行特征对比，判断独树沟花岗斑岩为高分异I型花岗岩；锆石U- Pb定年显示，独树沟花岗斑岩形成于350. 8±1. 7Ma；锆石Hf同位素显示，独树沟花岗斑岩的锆石εHf( t )值为+1. 82~+9. 19，平均值为+6. 85，二阶段模式年龄（ t DM2）为768~1238Ma，独树沟花岗斑岩的Hf同位素组成变化较大，指示其源区物质组成较为复杂，以新元古代新生地壳物质为主，有中元古代甚至更古老的地壳物质存在。结合柴北缘古生代构造演化历史，认为独树沟花岗斑岩形成于早古生代碰撞造山之后的伸展环境。  相似文献   

柴北缘锡铁山花岗斑岩锆石U—Pb年代学、地球化学及Hf同位素     

高歌悦  李碧乐  杨佰慧  廖宇斌 《世界地质》2018,37(3):747-760

对锡铁山北东侧的花岗斑岩体进行锆石U—Pb年代学、岩石地球化学及Hf同位素研究。通过LA—ICP—MS锆石U—Pb同位素测年,获得花岗斑岩的成岩年龄为373. 9±2. 2 Ma (MSWD=0. 069),属于晚泥盆世岩浆活动的产物。岩石地球化学特征显示岩石富硅(SiO_2=76. 33%～76. 99%)和碱(K_2O+Na_2O=7. 28%～8. 19%),低钙(CaO=0. 58%～0. 75%)、镁(MgO=0. 20%～0. 31%)和Mg~#值(Mg~#=23. 29～30. 17),A/CNK介于0. 97～0. 98,属于准铝质钙碱性岩石系列。岩石相对富集Rb、Th、U等大离子亲石元素,亏损Nb、Ta、Ti、P等高场强元素及Ba、Sr等部分大离子亲石元素。稀土元素配分曲线呈右倾型,轻稀土元素分馏明显,重稀土元素分馏较弱,且相对富集轻稀土元素,亏损重稀土元素,显示明显的负Eu异常(δEu=0. 36～0. 43)。锆石Hf同位素ε_(Hf)(t)比值为+6. 6～+9. 6,二阶段模式年龄T_(DM2)为760～950 Ma。综合岩石地球化学及同位素的研究表明,锡铁山花岗斑岩为高分异的I型花岗岩,岩浆源区主要为起源亏损地幔的新元古代新生地壳物质的部分熔融。结合区域构造背景和前人研究成果,认为本文锡铁山花岗斑岩形成于柴达木地块与祁连地块碰撞后伸展的大地构造环境。  相似文献   

北祁连干沙鄂博稀土元素矿床地质和矿床地球化学特征     

黄增保  李葆华  董晓燕  傅太宇  许龙  高昆丽  陈晨  郑慧  朱永新 《矿床地质》2019,38(1):129-143

干沙鄂博稀土元素矿床位于北祁连造山带中段,是该地区唯一大型稀土元素矿床。矿体产于早泥盆世碱性岩体及其接触带中,围岩蚀变表现为霓长岩化、碳酸岩化和萤石化,矿石类型主要为霓辉正长岩型和霓辉正长斑岩型,矿物组合为氟碳钙铈矿+黄铜矿+霓辉石+钠长石+钠闪石+萤石+方解石。通过详细的岩相学和矿相学观察,划分出4个成矿期,包括岩浆成矿期(Ⅰ)、早期热液成矿期(Ⅱ)、晚期热液成矿期(Ⅲ)和表生成矿期(Ⅳ)。其中,早期热液成矿期为主成矿期,包括3个成矿阶段:霓石-钠长石-氟碳钙铈矿阶段(Ⅱ_1)、钠闪石-氟碳钙铈矿阶段(Ⅱ_2)、霓石-方解石-氟碳钙铈矿阶段(Ⅱ_3)。脉石矿物石英的δ~(18)O值为7.3‰～11.3‰,δD值为-89.4‰～-68.8‰,δ~(13)C_(V-PDB)值为-10.5‰～-7.9‰,表明成矿流体以岩浆热液为主,有大气降水的参与。矿石中硫化物δ~(34)S_(V-CDT)值介于-7.1‰～-1.3‰之间,平均-4.4‰,总硫同位素δ~(34)S_(ΣS)为-3.9‰;矿石硫化物铅同位素组成基本一致,~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb和~(208)Pb/~(204)Pb比值分别为18.417～18.524、15.637～15.769和38.425～38.863,与矿区早泥盆世含矿碱性岩体岩石铅同位素组成十分相似,推测成矿物质主要来源于该碱性岩体。  相似文献   

甘肃干沙鄂博稀土矿床地质特征及矿床成因分析          下载免费PDF全文

陈耀宇  代文军  魏学平  冯兰君 《甘肃地质》2014,23(4):52-62

干沙鄂博稀土多金属矿床位于北祁连加里东褶皱带东段,成矿与干沙鄂博碱性斑岩体有关。干沙鄂博斑岩体为一小型岩株,地表出露面积约0.29km^2,岩性以霓辉正长斑岩为主,其次为霓辉碱长石英正长斑岩。岩体具全岩面型蚀变矿化特征,与稀土矿化关系密切的围岩蚀变主要为萤石化、碳酸盐化和硅化。矿化范围大,矿带长约800m,延深大于420m,5个主矿体长70-260m,平均厚度12-29m。矿石品位较低,稀土氧化物平均品位1.39%-1.65%,矿石中伴生金属元素有Cu、Pb、Mo。矿石矿物以氟碳钙铈矿为主,其他金属矿物有黄铜矿、方铅矿、斑铜矿及辉钼矿等。含矿斑岩体为一套准铝质和碱性岩石,总体具有高硅低钛、富钾低钠的特点。岩石富集K、Rb、Sr、Ba等不相容元素,亏损Ta、Nb、Zr、Ti等高场强元素;轻重稀土分馏强烈,显著富集轻稀土,具Eu负异常。以上地球化学特征表明干沙鄂博碱性斑岩体的成因可能与华力西晚期后造山伸展环境下富集地幔的部分熔融有关,并经历了显著的分离结晶作用。通过与国内外典型稀土矿床的对比分析认为,干沙鄂博稀土矿矿床成因类型为碱性斑岩岩浆期后热液型多金属稀土矿床,与冕宁牦牛坪和美国加里诺斯稀土矿的矿床成因类似。  相似文献   

滇西北红牛—红山铜矿床斑岩锆石U- Pb年龄、Hf同位素及地球化学特征     

周杰虎  陶兴雄  刘学龙  李守奎  周云满  魏志毅  曹振梁  李方兰  陆波德  刘雪 《地质论评》2023,69(3):2023030012-2023030012

滇西北格咱铜多金属矿集区是西南三江特提斯构造域重要的Cu—Mo多金属成矿带之一,燕山期伴随着构造—岩浆—热液作用形成了一系列的斑岩—矽卡岩型Cu（Mo）多金属矿床。其中红牛—红山铜矿床是区内代表性矿床。本文在系统的野外工作基础上对红牛—红山铜矿花岗斑岩—石英二长斑岩复式岩体进行了LA- ICP- MS锆石U- Pb定年、岩石地球化学和锆石Lu—Hf 同位素分析。结果表明,斑岩富硅（SiO2 =59. 19%~72. 20%）、富碱（K2O＋Na2O=6. 65%~12. 33%）,具有较高的稀土元素含量（ΣREE=163×10-6~588×10-6,平均值为272×10-6）,轻重稀土元素分馏程度较高（LREE/HREE=17. 2~31. 7）,负铕异常（δEu=0. 64~0. 84）,相对富集Rb、Th、U、K等大离子亲石元素（LILE）,而相对亏损Nb、Ti、Ta、P等高场强元素（HFSE）,为一套准铝质—过铝质的高钾钙碱性—钾玄岩系列高分异I型花岗岩,有向A型花岗岩演化趋势,具高锶低钇特征。3件花岗斑岩样品锆石LA- ICP- MS U- Pb年龄分别为80. 11±0. 63 Ma、76. 59±0. 53 Ma、76. 49±0. 63 Ma,2件石英二长斑岩锆石LA- ICP- MS U- Pb年龄为77. 27±0. 70 Ma、76. 99±0. 75 Ma,均属于燕山晚期。锆石εHf(t)值为-10. 3~-4. 6,两阶段模式年龄TDM2为1. 277~1. 582 Ga,峰值为1. 35~1. 40 Ga,揭示了红牛—红山花岗斑岩—石英二长斑岩源于中元古代地壳基底的深熔作用。综合认为红牛—红山花岗斑岩—石英二长斑岩的形成与早期形成的印支期格咱岛弧加厚地壳部分熔融密切相关。  相似文献   

华北地块中部早白垩世富碱侵入岩的成因:锆石U-Pb年代学和Sr-Nd-Hf同位素制约   总被引：7，自引：5，他引：2  

霍腾飞  杨德彬  师江朋  许文良  杨浩田 《岩石学报》2016,32(3):697-712

本文对华北地块中部早白垩世富碱侵入岩:山西的二峰山霓辉二长岩、塔儿山二长闪长斑岩、狐偃山石英二长岩、万荣石英二长闪长岩和河南的黄龙垴霓辉正长岩、水冶霓霞正长岩、东冶角闪闪长岩进行了岩石地球化学和Sr-Nd同位素分析以及4个侵入岩中锆石LA-ICP-MS U-Pb年代学和Hf同位素的测试。结果表明,二峰山、狐偃山、万荣和黄龙垴侵入岩中锆石有两种,多数为自形-半自形晶、内部结构均匀、发育震荡环带和条纹状吸收以及具有相对高Th/U比值(0.13~4.40)的岩浆锆石,其206Pb/238U加权平均年龄分别为130±1Ma、130±3Ma、127±1Ma和127±2Ma,即富碱侵入岩形成于早白垩世;少量为继承锆石,发育核-边结构,核部呈浑圆状和弱的震荡环带,给出了三叠纪(207~226Ma)和古元古代-新太古代(1791Ma、1979Ma、2088Ma、2370Ma和2559Ma)的年龄;岩石的SiO 2=55.33%~65.00%、MgO=0.21%~7.66%、Mg#=19~62、(Na2O+K2O)=5.89%~14.38%,属于弱碱性-过碱性岩石;富集大离子亲石元素(Rb、Ba、Sr)和轻稀土元素,亏损高场强元素(Nb、Ta、Ti)和重稀土元素,具有明显的Pb正异常和弱的Eu异常;其87Sr/86Sr初始值多数介于0.7049~0.7062之间,εNd(t)值变化于-20.1~-13.3之间,岩浆锆石的Hf同位素组成为εHf(t)=-28.9~-17.4。上述结果结合符山高镁闪长岩及其中地幔橄榄岩包体的研究暗示,华北地块中部早白垩世富碱侵入岩起源于受拆沉陆壳物质熔融的熔体改造的富集岩石圈地幔物质的部分熔融,其形成于古太平洋板块西向俯冲动力学背景下的岩石圈伸展环境。  相似文献   

东秦岭磨沟碱性岩体年代学、地球化学及岩石成因     

曹晶  叶会寿  李正远  张兴康  王鹏  贺文 《岩石矿物学杂志》2015,34(5):665-684

河南嵩县磨沟碱性岩体位于华北陆块南缘,其主体岩性为霓辉正长岩,局部出露正长岩和少量似斑状(霓辉)正长岩,发育岩浆暗色包体。LA-ICP-MS锆石U-Pb定年结果显示,霓辉正长岩和正长岩成岩年龄分别为210.4±2.0Ma(MSWD=0.39)和237.6±2.9Ma(MSWD=0.95),结合前人研究成果,认为该岩体是中三叠世和晚三叠世两期岩浆活动的产物。岩石地球化学特征显示,霓辉正长岩的σ值为8.93~11.08,K2O含量为10.70%~13.76%,K2O/Na2O值为3.87~10.35,属于过碱性岩石系列的钾质碱性岩;在微量元素组成上,富集轻稀土和大离子亲石元素,亏损高场强元素,具有弱或不明显的负铕异常。在同位素组成上,霓辉正长岩具有偏高的、变化范围很大的(87Sr/86Sr)i值和显著偏低的εNd(t)值;锆石的εHf(t)值变化于-21.6~-4.5之间,两阶段Hf模式年龄为1 555~2 629 Ma。磨沟岩体是由含金云母的富集地幔部分熔融产生的幔源岩浆与壳源岩浆混合并经一定程度的分异演化形成的,岩石中高含量的K来源于这种含金云母的富集地幔。磨沟岩体早期岩浆活动发生于秦岭造山带主碰撞峰期的局部伸展环境,晚期岩浆活动则发生于后碰撞伸展环境。  相似文献   

东昆仑拉陵高里河沟脑地区晚三叠世花岗闪长斑岩年代学、岩石地球化学及Hf同位素特征     

刘建栋  张焜  王秉璋  王春涛  李五福  张新远  曹锦山  袁锦鹏  李青  陈丽娟 《地质论评》2023,69(1):2023010019-2023010019

本文对东昆仑拉陵高里河沟脑花岗闪长斑岩开展详细的全岩地球化学、LA- ICP- MS锆石U- Pb年代学、锆石Hf同位素研究,确定其形成时代,并探讨其岩石成因及成岩构造背景。结果显示,花岗闪长斑岩LA- ICP- MS锆石U- Pb年龄为231. 1±1. 2 Ma,指示其侵位于晚三叠世早期。全岩K2O/Na2O值为0. 69～0. 71,Mg#值为40. 5～41. 6,里特曼指数σ为1. 90～2. 09,A/CNK=1. 01～1. 03,属弱过铝质中—高钾钙碱性岩石系列。岩石的轻重稀土元素分异明显,(La/Yb)N值为19. 54～25. 52,具弱负Eu异常（δEu为0. 96～0. 97）,富集大离子亲石元素K、Rb、Ba、Th,亏损高场强元素Nb、Ta、Ti等,具有高的Sr含量(606. 0×10-6～647. 9×10-6)和Sr/Y值(60. 38～62. 99),较低的Y(9. 62×10-6～10. 66×10-6)和Yb(0. 86-6～0. 92×10-6)含量,显示Adakite（高锶低钇中酸性岩）的地球化学特征。锆石Hf同位素εHf(t)值介于-6. 93~-2. 94,地壳模式年龄（TDM2）范围为1. 45~1. 70 Ga。综合分析表明,拉陵高里河沟脑花岗闪长斑岩形成于东昆仑洋壳俯冲末期至局部碰撞的转换阶段,岩浆源于高压条件下的加厚下地壳部分熔融。  相似文献   

大兴安岭北段宜里地区早侏罗世二长花岗岩U-Pb年龄、地球化学特征及其构造意义     

骆念岗  高莲凤  张璟  张振国  尹志刚  谢忠  崔建宇  吴子杰 《地质论评》2021,67(6):1649-1669

本文对大兴安岭北段宜里地区二长花岗岩进行了系统的地球化学及锆石U- Pb同位素年代学研究,旨在查明其成岩时代及岩石成因,并探讨其构造意义。宜里地区二长花岗岩中的锆石均呈半自形—自形,振荡生长环带明显,暗示其岩浆成因。锆石LA- ICP- MS U- Pb同位素定年结果显示,宜里地区二长花岗岩形成于175.8~174.5 Ma,为早侏罗世岩浆事件的产物。岩石具有富硅（SiO2=71. 23%~74.52%）、富碱更富钾（Na2O+K2O=6.31%~8.31%,K2O=2.58%~4.78%）、贫镁（MgO=0.43%~1.50%）、贫钙（CaO=0.91%~1.81%）的特征,铝饱和指数（A/CNK=0.97~1.16）,属于准铝质—弱过铝质高钾钙碱性花岗岩。富集Rb、Th、K等大离子亲石元素,相对亏损Nb、Ta等高场强元素和P、Ti等元素,轻重稀土元素分馏较强（La/Yb）N=14.07~50.34,无明显Eu异常（δEu=0.88~1.71）。花岗岩熔体的锆石饱和温度（714~745℃）明显低于A型花岗岩（＞800℃）,显示出高分异I型花岗岩的特征。岩石学及地球化学特征表明,宜里地区二长花岗岩的形成与俯冲形成的上涌热流加热新增生下地壳发生部分熔融有关。结合区域构造演化及构造判别,认为研究区早侏罗世二长花岗岩形成于蒙古—鄂霍茨克大洋板片南向俯冲作用相关的活动大陆边缘环境。  相似文献   

新疆东昆仑木孜塔格地区碎石沟花岗岩锆石 U-Pb年龄、岩石地球化学特征及地质意义     

鲁浩  刘欢  万鹏  薄军委  李金涛  孙景耀 《地质论评》2021,67(3):67040027-67040027

碎石沟花岗岩体位于东昆仑造山带西段木孜塔格地区,是该地区几个主要花岗岩体之一。为了查明该岩体的成因类型、物质来源及形成时代,并在此基础上进一步探讨木孜塔格地区的区域构造演化过程及东昆仑造山带地球动力学背景,对该岩体进行了详细的岩石学、地球化学及锆石U- Pb年代学研究。岩石学特征表明,碎石沟花岗岩主要由灰白色中细粒二长花岗岩组成,在岩体边部可见少量灰白色花岗闪长岩。岩石地球化学研究表明,该岩体具有高硅（SiO2=67.54 %~71.56 %）、高碱（Na2O=3.08%~4.50%、K2O=3.05%~4.20%）、富铝的特点（Al2O3=14.26%~16.58%）,属于准铝质—弱过铝质高钾钙碱性系列;稀土元素含量较高（126.31×10-6~160.13×10-6）,总体表现出轻稀土富集,重稀土亏损的右倾式配分模式,具有Eu的弱负异常（δEu=0.68~0.85）;微量元素相对富集Rb、Th、K等大离子亲石元素,亏损Nb、Ta、Hf、Sr等高场强元素,显示出 I 型花岗岩的特征。本次研究获得碎石沟岩体二长花岗岩的锆石U- Pb年龄为208.0±1.1 Ma（MSWD=1.0）,属于晚三叠世岩浆活动产物。结合区域构造演化特征,碎石沟花岗岩来源于下地壳物质部分熔融,并且在形成过程中存在幔源岩浆底侵及壳幔岩浆混合作用,其构造背景为后碰撞环境。  相似文献   

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites     

S. Viswanathan  K. Surya Prakash Rao  B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits     

E. M. Prasolov  S. A. Sergeev  B. V. Belyatsky  E. S. Bogomolov  K. A. Gruzdov  I. N. Kapitonov  R. Sh. Krymsky  V. O. Khalenev 《Geochemistry International》2018,56(1):46-64

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定     

肖德明  甘璇玑  卜正才 《铀矿地质》1986,(4)

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌     

奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定   总被引：5，自引：0，他引：5  

李国会  刘德慧  苏幼銮 《物探与化探》1986,10(1):60-65

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow     

Habib Alehossein   《International Journal of Mineral Processing》2009,93(1):11-19

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

Bellechester,Minnesota, USA,lagoon collapses     

Alexander  E. C.  Broberg  J. S.  Kehren  A. R.  Graziani  M. M.  Turri  W. L. 《Environmental Geology》1993,22(4):353-361

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

岩石密度和超高压岩石折返速率   总被引：1，自引：3，他引：1  

杨建平金振民  欧新功徐海军 《岩石学报》2005,21(2):427-437

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

Marine geotechnics,H. G. Poulos,Unwin Hyman,London, Boston,Sydney, Wellington     

M. Budhu 《国际地质力学数值与分析法杂志》1989,13(6):675-675

  相似文献   

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA   总被引：1，自引：0，他引：1  

Harvey E. Belkin  Harold M. Sparck 《Environmental Geology》1993,22(2):106-110

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献