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1.
以小波勒山地区1:5万水系沉积物数据为对象,利用相关分析和R型聚类分析确定研究区成矿元素组合为Pb-Ag-Zn-Cu-Bi(铅多金属成矿组合)和Mo-W-Sn(钼多金属成矿组合),以线性方法构置组合变量F1(Pb-Ag-Zn-Cu-Bi)、F2(Mo-W-Sn),组合变量中的各元素权重根据该元素对主成矿元素的相关性强度来确定;运用趋势面分析方法圈定研究区两个组合变量的异常图。结果显示,根据组合变量所圈定的综合异常与研究区已知矿化地段重合性很强。结合成矿地质条件对所圈定异常进行评价,确定出具Ⅰ级找矿潜力异常区3个,Ⅱ级、Ⅲ级找矿潜力异常区各2个,为研究区下一步找矿方向的确定提供了科学的依据。  相似文献   

2.
小波勒山地区1颐5 万地球化学数据处理与异常评价   总被引:2,自引:0,他引:2  
以小波勒山地区1:5万水系沉积物数据为对象,利用相关分析和R型聚类分析确定研究区成矿元素组合为Pb-Ag-Zn-Cu-Bi(铅多金属成矿组合)和Mo-W-Sn(钼多金属成矿组合),以线性方法构置组合变量F1(Pb-Ag-Zn-Cu-Bi)、F2(Mo-W-Sn),组合变量中的各元素权重根据该元素对主成矿元素的相关性强度来确定;运用趋势面分析方法圈定研究区两个组合变量的异常图.结果显示,根据组合变量所圈定的综合异常与研究区已知矿化地段重合性很强.结合成矿地质条件对所圈定异常进行评价.确定出具Ⅰ级找矿潜力异常区3个,Ⅱ级、Ⅲ级找矿潜力异常区各2个,为研究区下一步找矿方向的确定提供了科学的依据.  相似文献   

3.
青海沟里园以地区位于东昆仑造山带的东段,根据水系沉积物地球化学测量信息提取发现多个矿床(点),具有较好的找矿潜力。文章以沟里园以地区1:5万水系沉积物地球化学测量数据为研究对象,对数据剔值处理来确定元素异常下限并圈定单元素异常与组合异常,结合区内地质找矿特征对圈定的元素异常进行解释与推断。通过对元素地球化学特征、元素组合特征及单元素异常特征综合研究表明,Au、Ag、Pb、Zn、Cu、Co等元素与成矿关系密切;提取出2个元素组合,确定套合性和相关性好的Ag-Bi-Pb-Zn与Cu-Co组合异常为预测对象;结合区内成矿地质条件,进一步圈定3个找矿远景区。  相似文献   

4.
化探的数据处理和评价(尤其是多种方法数据处理及组合异常圈定等)目前尚无明确的技术规范,实际应用中多采用2种处理方法:①所选元素为成矿的指示元素,将分析的元素全部叠加来圈定全元素组合异常;②强调指示元素的相关性,按元素相关性圈定相关元素组合异常.文章以吉林延吉纺织厂金矿化探勘查为例,对比2种方法产生的不同异常特征,认为重视元素间的相关分析、运用相关元素组合异常更加符合地球化学找矿原理,所圈定的组合异常找矿意义更明显.  相似文献   

5.
地球化学异常下限的确定对圈定成矿有利靶区及指导找矿非常关键。本文以青海省锡铁山地区水系沉积物测量中As、Cr、Ni、Sn、Th等5个元素为例,分别运用剔除法、EDA法、迭代法对数据进行处理,确定异常下限,圈定异常。通过三种方法圈定异常结果对比发现,剔除法和EDA法确定的异常下限值偏高,不能够有效的圈出成矿有利靶区,而迭代法确定的异常下限,圈出了很多弱异常,与客观实际相符,故迭代法是适合本区比较合理的方法。  相似文献   

6.
利用摩洛哥苏斯—马萨—德拉地区内的地球化学信息,采用绘制三元图的方法推测地质体覆盖情况、元素组合异常强弱、预测矿产类型。该方法是在筛选相关性强的造岩(成矿)元素基础之上,利用三个单元的元素含量数据成图,依据三元图色标推断地质体和对成矿元素组合异常作出评价。结果显示三元图方法划分的地质体,圈定成矿元素组合异常、预测多金属矿产分布效果较好,证明该方法能反映地球化学分区特征。  相似文献   

7.
龚晶晶 《地质与勘探》2015,51(2):312-322
强调了统计域的正确选择对区域地球化学数据分析的重要性。本文以南岭研究区的W元素原始异常作为统计域,分析得出了研究区内不同成矿类型钨矿一种量化的简单元素组合特征。以此量化的元素组合特征,并结合相似度分析方法,统计了研究区内样点与各典型钨矿元素组合特征的相似性系数,其成图结果非常准确地圈定了已知的各类型钨矿,相比W元素原始异常其准确率得到了明显提升。该方法亦可认为是对地球化学场的一种成因分解,能够准确提取其中与成矿有关的异常信息。该研究可作为区域异常结构模式研究的重要补充,也可以为扩大南岭地区钨矿找矿远景提供线索。  相似文献   

8.
根据青海南部绝玛拉地区1:2.5万水系沉积物测量成果,划分出以Cu-Co、Pb-Zn-Ba以及As-Sb为主的3种元素组合类型.通过异常查证,在研究区圈定4处综合异常,在元素地球化学特征及元素组合特征分析的基础上,结合研究区成矿地质背景,确定找矿有利部位.通过槽探工程揭露,圈出矿化带2条,圈定铜矿化体4条,取得了较好的...  相似文献   

9.
内蒙古沙锡拉特地区位于大兴安岭多金属成矿带中段,为明确找矿方向,对研究区进行1∶1万土壤地球化学测量。采用单元素异常、组合异常与因子分析对研究区土壤地球化学数据进行评价。单元素异常显示,Ag、Pb、Zn与Sn元素的异常规模大、强度高。组合异常圈定4个异常,分为Ag—Au—As—Sb与Bi—W—Pb—Zn—Sn两类。因子分析将所分析元素分为五组,其中F1因子由Ag—Au—As—Sb元素组成,F2因子由Pb—Zn—Sn元素组成。根据土壤地球化学异常特征与区域成矿地质条件,在本区圈定2个找矿靶区,BQ—1为Pb—Zn—Sn找矿靶区,BQ—2为Ag找矿靶区。  相似文献   

10.
牧原地区位于大兴安岭岭脊西翼,在开展了4幅1∶5万土壤地球化学测量工作后,获得了较丰富的区域地球化学测量成果。通过对土壤地球化学测量样品系统整理、地球化学参数计算,总结了本区元素分布特征、综合异常特征、相关性及异常元素组合特征,全区共圈定单元素异常417个,综合异常41个,根据异常分布和元素成矿特征,结合地质条件优选出了5处找矿靶区。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

15.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

16.
17.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

19.
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2O3-SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.  相似文献   

20.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

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