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吉林夹皮沟金矿床含金石英的40Ar/39Ar快中子活化年龄测定 总被引：16，自引：0，他引：16
该文对夹皮沟金矿区有代表性的两个矿床及一个矿点的含金石英脉，用快中子活化法测定了40Ar/39Ar年龄。其年龄谱都以马鞍形为特征，年龄谱的最低坪年龄可作为石英脉的生成时代。3个数据分别为(1824±24)Ma、(1253±17)Ma和(203±60)Ma。由此认为夹皮沟矿区，金的成矿作用是多阶段的，吕梁期、晋宁期和燕山早期。而金矿的成因主要与吕梁期和晋宁期的变质作用有关，因此夹皮沟金矿可划为变质热液型金矿床。 相似文献
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新疆阿尔泰南缘东段哈腊苏斑岩铜(钼金)矿床地质 总被引：1，自引：0，他引：1
近几年阿尔泰南缘斑岩型铜矿勘查进展明显，哈腊苏铜（钼金）矿床倍受关注。该矿床以中泥盆世阿尔泰南缘特殊的裂谷为背景形成。矿化发生在侵入于中泥盆统玄武岩内的花岗闪长斑岩、花岗斑岩内及其附近围岩中。从岩体到玄武岩依次出现钾长石化、黑云母化、青磐岩化以及叠加于其上的团块/脉状钾化、硅化等蚀变。矿石中可同时见到细脉浸染状斑岩型和团块/脉状热液型两种组构，且后者叠加到前者之上。斑岩型矿化存在海西（381±8.7 Ma，375±8.7 Ma）和印支（213±4.2 Ma）两期，印支期（230±5 Ma）还发育构造-流体叠加矿化。矿石中硫化物的硫、铅同位素（δ34S=-6.5‰～-1.6‰，206Pb/204Pb=18.052～19.362，207Pb/204Pb=15.501～15.606，208Pb/204Pb=37.813～39.355）表明S和Pb来自岩浆或地幔/下地壳，成矿流体中水（δ18OSMOW=7.4‰～9.2‰，δDSMOW= -89‰～-80‰）为岩浆水。斑岩期成矿温度420～560℃。不同时期小斑岩体、玄武岩围岩及后期矿化叠加是成矿重要条件。 相似文献
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云南马厂箐铜多金属矿床的成岩成矿时代及成矿动力学背景 总被引：2，自引：0，他引：2
云南马厂箐铜多金属矿床是西南三江成矿带上著名的与喜马拉雅期富碱斑岩有关的典型矿床。与铜、钼、金等多金属成矿关系密切的马厂箐富碱斑岩为一复式岩体,存在多期次岩浆侵入活动,早期岩浆活动始于54～56 Ma,中期岩浆活动时间为45～49 Ma,晚期岩浆活动最强烈,发生在29～37 Ma,末期岩浆活动时间为23～25 Ma。采用辉钼矿Re-Os测年法,对马厂箐矿床的斑岩型铜钼矿石进行了精确测年,获得斑岩型铜钼矿石Re-Os模式年龄（35.3±0.7）Ma。利用40Ar-39Ar同位素方法对乱硐山地段矽卡岩型铜钼矿石和人头箐地段蚀变岩型金矿石中热液白云母进行同位素定年,得到矽卡岩化矿石中白云母的40Ar-39Ar坪年龄为（35.25±0.36） Ma,等时线年龄和反等时线年龄分别为（35.0±1.8） Ma和（34.8±1.9） Ma;蚀变岩型金矿石中白云母的40Ar-39Ar坪年龄为（35.35±0.32） Ma,等时线年龄和反等时线年龄分别为（34.44±0.99） Ma和（34.4±1.2） Ma。证明马厂箐斑岩型铜、钼、金多金属矿形成于同一成岩成矿地质事件,成矿作用主要与矿区晚期富碱岩浆活动关系密切,其形成的地球动力学背景应处于印度大陆与欧亚大陆发生碰撞造山之后的晚碰撞走滑阶段,总体上属于西南三江地区第一次成矿高峰期,即斑岩型Cu-Au成矿高峰期（65～35 Ma）。 相似文献
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内蒙碾子沟钼矿床辉钼矿Re-Os同位素年龄及其地质意义 总被引：21，自引：4，他引：17
内蒙古碾子沟石英脉型钼矿床是一新发现的钼矿床,通过对主要钼矿体6件辉钼矿样品的Re-Os同位素分析,获得了150.2±2.2~154.4±2.2Ma之间、平均152.4±1.3Ma（2σ误差,MSWD=1.6）的同位素模式年龄,及一个相关性很好的等时线年龄154.3±3.6Ma（2σ误差,MSWD=1.9）,表明碾子沟钼矿床形成于晚侏罗世,属中国东部燕山期大规模钼成矿期成矿,是中国东部中生代构造体制大转折背景下的产物。碾子沟钼矿床辉钼矿的铼含量介于12.6×10-6~37.0×10-6,平均24.9×10-6,通过与其它钼矿床对比,初步认为碾子沟钼矿床成矿物质具有壳幔混源、偏壳源特征。 相似文献
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延边小西南岔大型富金铜矿床矿区内暗色脉岩的锆石年代学及其地质意义 总被引：4，自引：0，他引：4
本文对小西南岔富金铜矿床矿区内与成矿空间密切的成矿前辉绿辉长岩、成矿期闪长玢岩岩脉进行了单颗粒锆石SHRIMP、LAICPMS UPb年龄的测定。实验数据表明：辉绿辉长岩的16个锆石或单点有387.0±11.8Ma、292.0~251.1Ma (加权平均值270±14Ma, n=10)、129.8±2.6 Ma、107.0～95.4Ma（加权平均年龄为103±13Ma,n=3）和46.8±2.6Ma五组谐和年龄; 闪长玢岩的11个锆石、12个单点仅获一组谐和年龄,变化在108～98Ma之间（加权平均值102.1±2.2Ma）。结合CL图像特征,初步厘定成矿前辉绿辉长岩形成于早二叠世晚期（270±14Ma,n=10;273±14Ma,n=6）,岩浆上侵过程中捕获了少量的泥盆世碎屑锆石,在成岩后的早白垩世、新生代始新世中期曾被热液改造;而闪长玢岩则形成于早白垩世晚期。考虑到伴生闪长玢岩的年龄与辉绿辉长岩的107.0～95.4Ma相匹配,且辉绿辉长岩的热液锆石年龄在103~95.4Ma之间,进而限定该富金铜矿床的成矿热事件应发生在108～98Ma,成矿作用发生在晚中生代地壳强烈伸展、减薄作用末期,经晚白垩世—古近世的后期抬升被剥露于现今地表,其成矿滞后于中国东北部晚中生代岩浆热液金矿床大规模成矿峰期（120Ma）约10Ma。 相似文献
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云南大坪金矿床赋矿闪长岩锆石SHRIMP U-Pb定年及其地质意义 总被引：2，自引：0，他引：2
云南大坪金矿床是哀牢山金矿带中最重要的金矿之一,主要赋存在受到强烈剪切和水-岩反应的闪长岩中,是典型的喜马拉雅期造山型金矿。本文对大坪金矿床赋矿闪长岩中锆石进行了SHRIMP U-Pb定年,得出闪长岩围岩的年龄为773±12Ma,为晚元古代,显示该岩体为华南地区晋宁-澄江期大规模基性到酸性岩浆活动的产物,是Rodinia 超大陆形成、裂解后冈瓦纳大陆形成过程的响应,而不是前人普遍认为的加里东期岩体。该岩体侵入年龄与大坪金矿脉石英流体包裹体40Ar-39Ar 年龄测定给出的高温坪年龄(765.5±7.0Ma)基本一致,显示大坪金矿床具有多期成矿的特征,其主体形成于喜马拉雅期碰撞造山运动,但早在晋宁造山运动中就有金的初步富集。在闪长岩中还发现了年龄为33.7±1.1Ma的锆石,其时代与大坪金矿床含金石英脉中热液绢云母的40Ar-39Ar定年结果(33.76Ma)基本一致,显示它们很可能为该区强烈的韧性剪切和局部岩浆部分熔融作用的产物。 相似文献
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桂西巴马料屯金矿床成矿年代上限的确定——对滇黔桂“金三角”卡林型金矿年代学研究的启示 总被引：1，自引：0，他引：1
广西巴马料屯金矿床是较为典型的卡林型金矿床,金矿体与燕山晚期石英斑岩脉空间上相关。矿床勘查成果和野外露头观察均表明石英斑岩脉切割金矿体,说明岩浆岩形成于矿体之后。成矿元素地球化学测量结果表明,Au、As元素沿石英斑岩脉走向出现明显的分异,表现为在导矿和容矿断层区段Au、As质量分数高,局部形成矿（化）体;远离矿体的砂泥岩和灰岩围岩地段,则逐渐降低至正常背景值,说明石英斑岩侵位过程中切割早期的矿体或含矿断层,萃取了矿（化）体中成矿元素Au、As,从而在这些断层之间形成一定宽度的高值带。成矿元素地球化学测量支持岩浆岩形成于矿体之后的结论。石英斑岩脉白云母斑晶的40Ar/39Ar坪年龄为（95.5±0.7） Ma,代表了岩浆侵位年龄,由于岩脉形成于矿体之后,此年龄可以作为成矿年代的上限年龄。本矿床及滇黔桂"金三角"其他卡林型金矿的确切成矿年代,尚需更多高精度直接成矿年龄数据的约束。 相似文献
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西藏波龙斑岩铜金矿床钾长石和绢云母40Ar/39Ar年龄及其地质意义 总被引：5，自引：1，他引：4
西藏波龙斑岩铜金矿床是新近在青藏高原中部发现的规模最大的斑岩型矿床。文章对该矿床内的蚀变钾长石和蚀变绢云母进行了40Ar/39Ar年代学测试,获得蚀变钾长石的40Ar/39Ar坪年龄为(118.33±0.60) Ma,反等时线年龄为(118.49±0.74) Ma (初始40Ar/36Ar=286.1±8.4),表明波龙斑岩铜金矿床的钾化蚀变年龄为118~119 Ma;蚀变绢云母的40Ar/39Ar坪年龄为(121.61±0.67) Ma,反等时线年龄为(121.1±2.0) Ma (初始40Ar/36Ar=279±19)。由于蚀变绢云母测试样品内可能混入了斜长石,受其影响,蚀变绢云母测年结果的下限可能代表了该矿床绢英岩化蚀变年龄。这些蚀变钾长石和蚀变绢云母40Ar/39Ar测年结果与波龙矿床的成岩年龄值和成矿年龄值在误差范围内基本一致,表明该矿床的钾化和绢英岩化与成岩、成矿同期,该矿床的岩浆-热液活动过程的时限为121~118 Ma。 相似文献
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崇义—大余—上犹矿集区是世界著名的黑钨矿床集中区,本文选择钨锡多金属硫化物石英脉型（柯树岭和漂塘矿床）和锡钨石英脉型（仙鹅塘矿床）3个矿床石英中的白云母开展40Ar/39Ar年代学研究,测得坪年龄分别是：钨锡多金属硫化物石英脉型是 158.9 ± 1.4 Ma（漂塘）、158.8 ± 1.2 Ma（柯树岭）;钨锡石英脉型的是231.4 ± 2.4 Ma（仙鹅塘）,在反等时线图上,其对应的截距年龄分别是158.8 ± 1.6 Ma、158.7 ± 1.9Ma和232.5 ± 2.4 Ma。由此表明,在崇余犹矿集区内存在两个不同成矿时期,即以黑钨矿为主的多金属硫化物石英脉型矿床形成于中侏罗世,集中于160~150Ma之间,与南岭地区钨锡矿床的主成矿期是一致的;而以锡石为主的,并含有大量白钨矿的石英脉型矿床可形成于印支期 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
20.
Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献