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1.
粤北佛冈岩体北缘的白沙岩体细粒黑云母二长花岗岩LA-ICP-MS锆石U-Pb加权平均年龄为130.3±3.0Ma,表明细粒黑云母二长花岗岩侵入于早白垩世。岩体高硅(SiO2=70.64~75.01wt%),高Na2O+K2O(7.62~8.33wt%),低P2O5(0.024~0.100wt%),富集Rb、Th、U、K、Pb、Nd、Zr和Hf等元素,亏损Ba、Nb、Ta、La、Ce、Sr、P和Ti等。明显富集轻稀土元素[(La/Yb)N=6.74~54.69],显示明显的负Eu异常(δEu=0.15~0.35),少量正Eu异常(δEu=0.82~1.19)。这些地球化学特征指示细粒黑云母二长花岗岩为高分异I型花岗岩。锆石Hf同位素研究结果表明,εHf(t)=-7.3^-10.6,其平均值为-8.89。其两阶段模式年龄(T2DM)主要为1654~1865Ma(n=8),平均值为1751Ma。佛冈复式岩体早白垩世细粒黑云母二长花岗岩形成于古太平洋板块向欧亚板块俯冲的陆缘弧构造背景下,其地球化学特征表明其物质主要来源于古元古代地壳的杂砂-泥质源岩部分熔融,并有少量幔源物质参与。 相似文献
2.
通过岩体地质地球化学等特征的调查研究,对万洋山花岗岩体进行了岩石谱系单位划分,认为它是加里东期多阶段岩浆活动形成的复式岩体.花岗岩岩石类型主要为黑云母花岗闪长岩、黑云母二长花岗岩、二云母二长花岗岩,其中,黑云母花岗闪长岩、黑云母二长花岗岩中含有较多的暗色镁铁质微粒包体.SiO2含量为66.99%～73.04%,K2O平均含量为3.91%,Na2O K2O为6.26%～7.39%,K2O/Na2O平均值为1.45,Al2O3平均值为13.74%;Ba、Nb、Sr、P、Ti亏损较明显,Rb、(Th U)、(La Ce)、Nd、(Zr Hf Sm)、(Y Yb)等则相对富集;∑REE平均为264.43×10-6,重稀土富集;∑Ce/∑Y平均比值为1.8;(La/Yb)N比值平均7.13;Eu弱亏损,δEu值平均为0.53;I 值为0.71223～0.71376.εSr(t)值为109.8～131.5,εNd(t)值为-7.1～-8.3,t2DM为1.74～1.86 Ga;研究表明万洋山花岗岩属铁质、(强)过铝高钾钙碱性S型花岗岩,形成于后造山构造环境;岩浆源区的物质是多源的,主要是含有深源岩浆固结产物的地壳物质;或是加里东期间扬子地块和华夏地块间发生碰撞前的侵入有深源岩浆岩或岛弧型岩浆岩的地壳物质:早期次单元花岗岩的岩浆源可能还有幔源岩浆混染或局部混合. 相似文献
3.
扬子板块西北缘新元古代岩浆作用成因的研究对于研究Rodinia超大陆在该区的构造演化具有重要意义。本文对扬子板块西北缘米仓山地区二长花岗岩进行了LA-ICP-MS锆石U-Pb定年和同位素、全岩主量和微量元素分析。结果表明二长花岗岩锆石U-Pb年龄为742.1±5.9 Ma,属于新元古代花岗岩。岩石具有高Si O_2(76.84%~80.08%),高碱(Na_2O+K_2O=7.64%~8.99%),相对富钾(K_2O/Na_2O=0.91~1.36),低P_2O_5含量等特征,铝饱和指数(A/CNK)介于0.77~0.89之间。岩石具有稀土元素含量较高、相对富集轻稀土元素的特征,具有明显负Eu异常,Eu*=0.05~0.13,Rb、U、Th、K、Pb等元素相对富集,Ba、Nb、Sr、P、Zr、Ti和Eu等元素明显亏损。岩石n(~(87)Sr)/n(~(86)Sr)=0.747067~0.795283,n(~(143)Nd)/n(~(144)Nd)=0.512472~0.512661,ε_(Nd)(t)=+3.6~+5.2,二阶段模式年龄T_(2DM)值介于0.96~1.07Ga之间。综合地球化学、同位素特征及米仓山区域构造资料,我们认为坪河二长花岗岩为高钾钙碱性高分异I型花岗岩,该岩浆起源于新生玄武质下地壳岩石的局部熔融,在上升阶段可能经历了地壳的混染作用,形成于伸展的构造环境中,是新元古代晚期Rodinia超大陆裂解作用的岩浆响应。 相似文献
4.
南岭西段加里东期苗儿山岩体锆石SHRIMPU-Pb年龄、地球化学特征及其构造意义 总被引：1，自引：0，他引：1
苗儿山岩体位于南岭西段,主体为加里东期花岗岩,少量印支期和早燕山期花岗岩。加里东期花岗岩具块状构造,由早期黑云母花岗闪长岩、中期斑状黑云母二长花岗岩和晚期细粒黑(二)云母二长花岗岩组成,以斑状黑云母二长花岗岩为主。对中期斑状黑云母二长花岗岩和晚期细粒二云母二长花岗岩各进行了1个样品的锆石SHRIMP U-Pb年龄测试,分别得到428.5±3.8 Ma、409±4 Ma的年龄值,反映出早志留世末、志留纪末-泥盆纪初2期岩浆事件。中期主体花岗岩具有富硅(SiO2=70.09%~76.59%)、中铝(Al2O3=12.71%~14.72%)、高钾(K2O=4.48%~5.73%)、中碱(Na2O+K2O=7.24%~7.91%)、高ASI(平均1.15)的特点,总体属高钾钙碱性系列过铝质花岗岩类。主体花岗岩微量元素中Ba、Nb、Sr、P、Ti表现为明显亏损,Rb、(Th+U+K)、(La+Ce)、Nd、(Zr+Hf+Sm)、(Y+Yb+Lu)等则相对富集,稀土总量中等(179.8×10-6~270.6×10-6),轻稀土富集[(La/Yb)N=5.07~14.33],具明显的负Eu异常(δEu=0.15~0.46)。岩体具有较高的ISr值(0.70660~0.72082)和较低的εNd(t)值(-8.29~-7.94),两阶段Nd模式年龄(t2DM)为1.81~1.84 Ga。C/MF-A/MF图解显示源岩为变质泥质岩和碎屑岩。上述地球化学特征表明花岗岩为S型花岗岩,源岩主要为中、上地壳岩石。花岗岩氧化物和微量元素构造环境判别图解指示岩体形成于后碰撞构造环境。基于岩石成因、构造环境判别以及区域构造演化过程,推断加里东期苗儿山花岗岩的具体形成机制为:在陆内强挤压之后挤压应力相对松弛、压力降低的后碰撞构造环境下,因地壳增厚而升温的中、上地壳岩石减压熔融并向上侵位。结合区域资料分析,苗儿山地区在奥陶纪末-志留纪初北流运动和志留纪后期的广西运动中均产生过强烈的陆内挤压和地壳增厚。 相似文献
5.
南秦岭华阳花岗岩LA-ICP-MS锆石U-Pb
年龄、地球化学和Hf同位素组成
——对五龙岩体群成因的约束 总被引：4，自引：0，他引：4
华阳岩体位于南秦岭中部地区,岩体主体岩性为黑云母二长花岗岩。对中粒黑云母二长花岗岩和细粒黑云母二长花岗岩的LA-ICP-MS锆石U-Pb定年分别获得214Ma±2Ma和228Ma±2Ma的年龄,表明该岩体形成于晚三叠世。华阳花岗岩属于弱过铝质和高钾钙碱性系列,具有I-A型花岗岩过渡的特征,A/CNK值为1.01~1.14,Na2O为3.15%~3.83%,K2O为3.04%~5.70%,K2O/Na2O为0.84~1.80,Mg#为0.24~0.48;稀土元素配分曲线表现为右倾型,轻、重稀土元素分馏明显,具有显著的Eu负异常。该花岗岩富集Rb、K、Pb、Sr等大离子亲石元素,亏损Zr、Hf、Ta、Nb、P、Ti等高场强元素,表明华阳花岗岩的物源以壳源物质为主。锆石饱和温度和Ti温度计等的估算显示,华阳岩体岩浆源区的初始温度为750~800℃。花岗岩的锆石εHf(t)值变化范围较小,为-6.17~2.27,平均值为-3.19;二阶段模式年龄TDM2为1.65~1.12Ga,加权平均值为1.46Ga,结合区域地质背景和前人研究成果认为,华阳花岗岩是早—中元古代古老地壳物质部分熔融的结果,伴有少量幔源物质的加入;岩体的形成与华南板块和华北板块碰撞有关,是同碰撞向后碰撞构造体制转变或后碰撞伸展早期的产物。 相似文献
6.
南岭西段加里东期越城岭岩体锆石SHRIMP U-Pb年龄、地质地球化学特征及其形成构造背景 总被引：1，自引：0，他引：1
越城岭岩体位于南岭西段,主体为南部的加里东期花岗岩,北部为印支期花岗岩。加里东期花岗岩自早至晚依次为中细粒斑状黑云母二长花岗岩、细中粒斑状黑(二)云母二长花岗岩、细粒斑状黑(二)云母二长花岗岩和细粒黑(二)云母二长花岗岩。岩体东部和西部花岗岩分别具块状构造和片麻状构造。岩体西缘尚叠加了燕山期左行走滑-伸展型韧性剪切带。对中细粒斑状黑云母二长花岗岩和(糜棱岩化)细中粒斑状黑云母二长花岗岩各进行了1个样品的锆石SHRIMP U-Pb年龄测试,分别得到(436.6±4.8)Ma、(430.5±4.3)Ma的年龄值,反映花岗岩形成于早志留世晚期。岩石高硅、富铝、高钾、中碱,Si O2含量68.35%~78.10%,平均73.29%;Al2O3含量11.95%~15.55%,平均14.18%;K2O含量4.12%~5.62%,平均4.95%;全碱(Na2O+K2O)含量为6.18%~8.30%,平均7.58%;K2O/Na2O值在1.36~2.82之间,平均1.94。ASI值1.04~1.66,平均1.23。总体属高钾钙碱性系列过铝质花岗岩类。大多数样品Ba、Nb、Sr、P、Ti表现为较强烈亏损,Rb、(Th+U+K)、(La+Ce)、Nd、(Zr+Hf+Sm)、(Y+Yb+Lu)等则相对富集;∑REE含量为50.43~328.81μg/g,平均173.39μg/g;δEu值0.21~0.68,平均为0.40;(La/Yb)N值为0.54~14.04,平均7.93;ISr值为0.71912和0.72415,εSr(t)值为208和279,εNd(t)值为–11.76~–7.80,t2DM为1.80~2.12 Ga。A/MF-C/MF图解显示源岩为泥质岩和碎屑岩。上述地球化学特征表明花岗岩为S型花岗岩,是陆壳碎屑岩石部分熔融的产物。花岗岩氧化物构造环境判别图解指示岩体形成于后碰撞构造环境。基于岩石成因、构造环境判别以及区域构造演化过程,推断加里东期越城岭花岗岩的具体形成机制为:奥陶纪末—志留纪初的北流运动导致地壳增厚、升温,早志留世中晚期在挤压减弱、应力松弛的后碰撞-减压构造环境下,中、上地壳酸性岩石发生部分熔融并向上侵位。 相似文献
7.
江西省东坪钨矿床位于江南造山带东段,是中国新发现的超大型"五层楼式"石英脉型黑钨矿矿床.为探讨东坪钨矿床的成矿岩浆岩形成时代、来源及其构造背景,在详实的野外地质调查基础上对东坪成矿黑云母花岗岩进行了详细的锆石U-Pb年代学、主量、微量元素地球化学以及Sr-Nd同位素研究.LA-ICP-MS锆石U-Pb定年测得东坪黑云母花岗岩结晶年龄为132.9±1.4 Ma (MSWD=0.40,n=25);岩石地球化学特征表明黑云母花岗岩为高硅高钾钙碱性过铝质高分异S型花岗岩,ω(SiO_2)为73.19%~75.21%、ω(Na_2O+K_2O)为6.84%~8.45%、A/CNK为1.21~1.44,亏损Sr、Ba、Ti,富集Rb、Th、U、P;∑REE为43.52~60.88μg/g,轻稀土富集,重稀土亏损,强负铕异常(Eu/Eu*=0.21~0.41),稀土配分曲线呈右倾深"V"型.黑云母花岗岩(87Sr/86Sr)?值介于0.715 1~0.725 8,εNd(t)值介于-3.28~-5.99,两阶段模式年龄TDM2为1.57~1.84 Ga(t=132.9 Ma).综合分析认为,东坪成矿岩浆岩来源于富泥质岩石熔融,其源区岩石很可能是华南中元代古老基底物质的再循环,形成于太平洋板块俯冲引起的陆内"伸展-拉张"动力学背景. 相似文献
8.
腾冲地块江东花岗岩体分布于芒市江东镇—项丘一带,主要由黑云母二长花岗岩组成。该花岗岩锆石LA-ICP-MS U-Pb定年结果表明,锆石U-Pb年龄加权平均值为58.29±0.44 Ma,表明该花岗岩体的形成时代属于古新世。岩石地球化学研究表明,该花岗岩具有中等SiO2(68.66%~73.50%),高碱(K2O+Na2O=6.87%~9.04%),高钾(K2O/Na2O=1.87~2.20),铝饱和指数(A/CNK)为0.97~1.36的特征。岩石属钾玄岩—高钾钙碱性系列,为过铝质S型花岗岩。稀土元素总量(ΣREE)为158.85×10-6~304.26×10-6,稀土元素配分曲线呈右倾型,具有弱到中等程度的负铕异常。根据岩石地球化学特征判别,该花岗岩的源岩可能是富含粘土的变质杂砂岩,在构造体制由挤压向拉张转变的后碰撞环境下部分熔融形成的。江东古新世后碰撞环境黑云母二长花岗岩的形成,预示着印度板块与冈底斯-波密-腾冲板块的主体碰撞在60Ma之前(即古新世初期之前)已经发生。冈底斯-滕冲构造带古新世构造岩浆造山事件与新特提斯洋的闭合及印度板块与冈底斯-滕冲板块间的俯冲、碰撞造山作用密切相关。 相似文献
9.
北祁连东段冷龙岭地区毛藏寺岩体和黄羊河岩体的岩石成因及其构造意义 总被引：5，自引：0，他引：5
文中研究了北祁连东段冷龙岭地区毛藏寺岩体和黄羊河岩体的年代学、地球化学和Sr-Nd同位素组成。毛藏寺岩体主要岩石类型为花岗闪长岩。锆石U Pb定年获得花岗闪长岩岩浆结晶年龄为（424±4） Ma。花岗闪长岩具有高的Mg#（约55）,K2O/Na2O=0.77~0.91,A/CNK=0.92~0.94,表明岩石属准铝质。在微量元素组成上,花岗闪长岩富集LILE、亏损HFSE,轻重稀土分异明显［(La/Yb)N=16.9~19.5］,具有弱的Eu负异常（Eu/Eu*=0.75~0.83）;花岗闪长岩具有ISr=0.706 3~0.706 5,εNd(t) =-1.5~-1.1,TDM=1.10~1.16 Ga。这些地球化学特征和Sr Nd同位素组成表明,花岗闪长岩岩浆源区为基性下地壳变玄武质岩石,但在成岩过程中有少量幔源物质的加入。黄羊河岩体主要由钾长花岗岩组成,其岩浆结晶年龄为（402±4） Ma。岩石富碱（K2O+Na2O=6.91‰~7.66%）,K2O/Na2O>1,A/CNK=0.97~1.05。钾长花岗岩富集LILE及HFSE,轻重稀土元素分馏中等［(La/Yb)N =10.6~17.8］,并具有明显的负Eu异常（Eu/Eu*=0.43~0.68）,表明钾长花岗岩具有铝质A型花岗岩的地球化学特征。钾长花岗岩具有ISr=0.710 3~0.711 3,εNd(t)=-6.7~-6.0,TDM=1.46~1.55 Ga,反映岩浆主要来自地壳中长英质物质的部分熔融。冷龙岭地区花岗岩类的岩石成因及其岩浆演化揭示了北祁连山造山带从加里东早期的挤压构造体制向加里东晚期的伸展构造体制的演化。这些花岗岩类形成于碰撞后构造背景,岩浆的产生可能与俯冲的北祁连洋板片的断离作用有密切联系。 相似文献
10.
闽西南虎岗地区晚中生代花岗岩LA-MC-ICP-MS锆石U-Pb年龄、地球化学特征及地质意义 总被引：1，自引：0，他引：1
选取福建虎岗地区灌洋和增坑二个岩体进行LA-MC-ICP-MS锆石U-Pb测年.增坑细粒二长花岗岩岩体单颗粒锆石U-Pb年龄为145.4±18.2～151.4±7.9 Ma,加权平均值为147.98±0.86 Ma(可信度95%,MSWD=0.62).灌洋中细粒黑云母二长花岗岩岩体单颗粒锆石年龄为141.2±4.1 ～ 145.5±1.9Ma,加权平均值为143.0±1.1Ma(可信度95%,MSWD=0.41).二岩体形成于挤压碰撞的构造环境,微量元素含量表明,岩浆分异作用较强,酸性程度较高,n(A12O3) ＞n(CaO) +n(Na2O) +n(K2O),且有较高的Rb/Sr和Rb/Nb比值,低含量的Ni、Cr含量和右倾型的稀土元素模式,表明岩体岩浆起源于大陆地壳中沉积的源岩,属于铝过饱和S型花岗岩.增坑和灌洋岩体形成年代都为晚侏罗世(燕山中晚期),且为铁铜多金属矿成矿提供了物质基础. 相似文献
11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
12.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world. 相似文献
13.
《Geoforum》2017
This article advances critical geographies of youth through examining the spatiality implicit in the imagined futures of young women in rural India. Geographers and other scholars of youth have begun to pay more attention to the interplay between young people’s past, present, and imagined futures. Within this emerging body of scholarship the role of the family and peer group in influencing young people’s orientations toward the future remain underexamined. Drawing on eleven months of ethnographic fieldwork, my research focuses on a first generation of college-going young women from socioeconomically marginalized backgrounds in India’s westernmost state of Gujarat. I draw on the “possible selves” theoretical construct in order to deploy a flexible conceptual framework that links imagined post-educational trajectories with motivation to act in the present. In tracing the physical movement of these young women as they navigate and complete college, my analysis highlights the ways in which particular kinds of spaces and spatial arrangements facilitate and limit intra- and inter-generational contact, and the extent to which this affects young women’s conceptions of the future. I conclude by considering the wider implications of my research for ongoing debates surrounding youth transitions, relational geographies of age, and education in the Global South. 相似文献
14.
15.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
16.
I. Bejarano-Ramirez Jose M. Jurado R. Muñiz-Valencia Á. Alcázar Silvia G. Ceballos-Magaña A. Olivos-Ortiz O. Rangel 《International Journal of Environmental Science and Technology》2017,14(6):1333-1342
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments). 相似文献
17.
Models have become so fashionable that many scientists and engineers cannot imagine working without them. The predominant use of computer codes to execute model calculations has blurred the distinction between code and model. The recent controversy regarding model validation has brought into question what we mean by a ‘model’ and by ‘validation.’ It has become apparent that the usual meaning of validation may be common in engineering practice and seems useful in legal practice but it is contrary to scientific practice and brings into question our understanding of science and how it can best be applied to such problems as hazardous waste characterization, remediation, and aqueous geochemistry in general. This review summarizes arguments against using the phrase model validation and examines efforts to validate models for high-level radioactive waste management and for permitting and monitoring open-pit mines. Part of the controversy comes from a misunderstanding of ‘prediction’ and the need to distinguish logical from temporal prediction. Another problem stems from the difference in the engineering approach contrasted with the scientific approach. The reductionist influence on the way we approach environmental investigations also limits our ability to model the interconnected nature of reality. Guidelines are proposed to improve our perceptions and proper utilization of models. Use of the word ‘validation’ is strongly discouraged when discussing model reliability. 相似文献
18.
The shape of sedimentary particles may carry important information on their history. Current approaches to shape classification
(e.g. the Zingg or the Sneed and Folk system) rely on shape indices derived from the measurement of the three principal axes
of the approximating tri-axial ellipsoid. While these systems have undoubtedly proved to be useful tools, their application
inevitably requires tedious and ambiguous measurements, also classification involves the introduction of arbitrarily chosen
constants. Here we propose an alternative classification system based on the (integer) number of static equilibria. The latter
are points of the surface where the pebble is at rest on a horizontal, frictionless support. As opposed to the Zingg system,
our method relies on counting rather than measuring. We show that equilibria typically exist on two well-separated (micro
and macro) scales. Equilibria can be readily counted by simple hand experiments, i.e. the new classification scheme is practically
applicable. Based on statistical results from two different locations we demonstrate that pebbles are well mixed with respect
to the new classes, i.e. the new classification is reliable and stable in that sense. We also show that the Zingg statistics
can be extracted from the new statistics; however, substantial additional information is also available. From the practical
point of view, E-classification is substantially faster than the Zingg method. 相似文献
19.
Hirokazu Fujimaki 《Contributions to Mineralogy and Petrology》1986,94(1):42-45
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite. 相似文献
20.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献