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1.
采用物种分布图与核磁共振实验研究了五硼酸钾溶液中含硼物种的类型、含量和溶液浓度间关系。研究表明五硼酸钾在稀溶液(0.05 mol/kg(H2O))中几乎全部水解,主要物种为B(OH)3和B(OH)-4;在较浓溶液(0.20 mol/kg(H2O))中主要物种为B(OH)3和B3O3(OH)-4,而B5O6(OH)-4和[B4O5(OH)2-4]的含量较小。核磁共振实验研究给出了B(OH)-4、B3O3(OH)-4和B5O6(OH)-4的生成常数K1、K3,、K5,研究得出B5O6(OH)-4含量很少的原因是其解聚为其它类型硼酸根离子。外加离子促进五硼酸根离子的生成,而高温条件促进B5O6(OH)-4发生解聚反应。 相似文献
2.
基于密度泛函理论,采用ωB97XD方法和6-311++G(d,p)基组,系统研究了[K(H2O)n]+,[NO3(H2O)n]-和KNO3(H2O)n水合团簇的结构和性质;并结合经典分子动力学、OPLS-AA全原子力场以及SPC/E水模型模拟了不同水盐比(WSR) KNO3溶液,目的在于深入理解KNO3溶液中K+和 NO-3的微观水合结构,以及K+-NO-3离子间缔合作用特征。研究发现,对于KNO3(H2O)n (n=6,8,10和12)水合团簇,K+第一水合层稳定结构为四、五和六水合结构,其中五水合结构最稳定。K+和NO-3主要以溶剂共享离子对形式存在。随着团簇尺寸减小,直接接触离子对(CIP)物种出现。同时,分子动力学模拟证实KNO3溶液中形成了直接接触K+-NO-3离子对,且随着溶液浓度增加,CIP物种形成需越过更大能垒。以上结果表明在KNO3稀溶液中主要存在物种为水合K+和NO-3,随浓度增大,单齿直接接触离子对(MCIP)逐渐出现。在高浓溶液或过饱和溶液中,K+-NO-3离子缔合主要以单齿CIP和少量双齿CIP结构存在。 相似文献
3.
崇明东滩湿地CO2 、CH4和N2O 排放的时空差异 总被引：10，自引：0，他引：10
通过静态暗箱—气相色谱法研究了长江口崇明东滩四类典型湿地(围垦湿地、高潮滩、中潮滩和低潮滩)CO2、CH4和N2O排放特征及影响因素。结果表明,在生长季尺度下,CO2、CH4和N2O均以排放为主;在昼夜尺度下,CO2和CH4在夜间排放量大于白昼排放量,而N2O的排放高峰出现在下午;在潮水退去、潮滩暴露初期,CH4和N2O有大量排放,CO2正好相反。崇明东滩温室气体排放通量自岸向海有明显的梯度变化,总体趋势是越近岸通量值越大。观测与实验表明,温度、潮汐、土壤理化性质、植物和土地利用变化都对温室气体排放通量有明显的影响,其中滨海潮滩湿地特有环境因子潮汐以"淹没—暴露"光滩沉积物的方式控制温室气体的排放。 相似文献
4.
在Pitzer电解质溶液理论的基础上采用两种模型计算了KCl-K2SO4-KBO2-H2O体系及其子体系的溶解度。模型I假设溶液中只有一种硼物种B(OH)4-,模型II假设溶液中有4种硼物种,分别对应于B(OH)3、B(OH)4-、B3O3(OH)4-和B4O5(OH)42-。模型I与模型II的溶解度计算结果接近,且与实验值吻合较好。采用模型II计算了上述体系溶液中的硼物种和OH-的浓度。各硼物种的浓度主要受溶液中总硼浓度的影响,而很少受KCl和K2SO4的影响。计算结果说明在计算偏硼酸钾溶液体系溶解度时,可近似认为溶液中硼物种只有B(OH)4-。模型II可用于计算含偏硼酸钾体系的pH值。本文的计算结果可为复杂偏硼酸钾体系模型的构建提供理论基础。 相似文献
5.
硫酸镁亚型盐湖老卤是MgCl2、MgSO4的饱和溶液体系,富集了Mg、B、Li等元素。本文针对含硼水盐体系热力学难以表达的问题,开展了硼在水盐体系存在形态及其平衡关系的研究。利用易于水解的Mg(BO2)2作为硼源,借助拉曼光谱和X射线衍射(XRD)为检测手段,定量研究Mg(BO2)2在MgSO4-H2O、MgSO4-MgCl2-H2O体系中水解硼物种转化规律。结果表明:(1)Mg(BO2)2在MgSO4溶液中的水解固相为MgB2O(OH)6、MgB4O7·9H2O和Mg(OH)2;在MgSO4-MgCl2-H2O溶液中水解固相为Mg2B6O11·15H2O、MgB4O7·9H2O、Mg2Cl(OH)3·4H2O。(2)Mg(BO2)2在MgSO4溶液中水解,液相硼物种主要有B3O3(OH)-4、B3O3(OH)52-、B(OH)-4、B4O5(OH)42-、H3BO3,其分布受MgSO4浓度影响很大,MgSO4浓度从0增加至饱和,B3O3(OH)-4始终占总硼量的50.07%以上,B3O3(OH)52-占液相总硼从4.77%上升至37.16%为第2化学物种。(3)在MgSO4-MgCl2-H2O溶液中,硼物种的主要形态有B3O3(OH)-4、B3O3(OH)52-、B(OH)-4,其分布 随[Cl22-]/([Cl22-]+[SO42-])变化很大,在MgCl2和MgSO4的共饱溶液中,分别占液相总硼量的58.91%,14.62%和12.81%。(4)液相硼物种之间平衡关系的活度商lnQ,不仅与溶液pH、水活度有关,还与MgSO4、MgCl2摩尔浓度呈二元线性关系,这样就可将硼在H3BO3-NaOH体系物种分布关系的lnQ扩展到 (MgSO4,MgCl2,MgSO4-MgCl2)水溶液的多元体系。由此获得硼物种的量化关系,可为推算硼在水盐体系的物种分布,进而计算含硼电解质溶液热力学性质提供依据。 相似文献
6.
《湿地科学》2015,(5)
在闽江河口塔礁洲采集土样,在室内设置4个实验组,分别添加盐度为5‰、15‰和25‰的人造海水以及盐度为0‰的去离子水,通过室内淹水厌氧培养实验,研究模拟海水入侵对淡水洲滩土壤潜在反硝化速率的影响。结果表明,培养1 d,盐度为0‰的实验组土壤的潜在反硝化速率最大,其次是盐度为5‰的实验组,盐度为15‰的实验组土壤的潜在反硝化速率更低,盐度为25‰的实验组土壤的潜在反硝化速率最小,盐度为0‰实验组的土壤潜在反硝化速率显著高于其他实验组(p0.05);培养3 d,盐度为25‰的实验组土壤的潜在反硝化速率最大,其次是盐度为5‰的实验组,盐度为15‰的实验组土壤的潜在反硝化速率更低,盐度为0‰的实验组土壤的潜在反硝化速率最小,盐度为0‰实验组的土壤潜在反硝化速率显著低于其他实验组(p0.05);培养3 d以后,各盐度实验组之间的土壤潜在反硝化速率无显著差异(p0.05)。盐度对淡水洲滩土壤潜在反硝化速率的影响可能是短暂的,随着时间的延续,影响可能消失。指数函数模型较好地描述了4个盐度实验组的土壤潜在反硝化速率与培养时间的关系;除盐度为0‰的实验组,其他盐度实验组的洲滩土壤反硝化活性都随时间的推移而增强;洲滩土壤有较好的潜在脱氮效率,整个培养期以盐度15‰实验组潜在脱氮效率最大,潜在脱氮总量为(436.54±45.04)mg/kg,潜在脱氮效率为(87.31±9.01)%。 相似文献
7.
Li+,Na+,K+/Cl-,SO2-4-H2O五元体系相图对于硫酸钠亚型富锂卤水分离提取锂盐、锂辉石加工利用和锂盐产品的开发利用工艺制定都有指导作用。20世纪50年代曾有人研究过这一体系25 ℃时的相图,限于当时的科研水平,液相组成确定不准确,对平衡固相的判断,后来诸多研究结果证明也有错误。50多年来再没有人研究这一五元体系相图。利用我们提出的Li+,Na+,K+/Cl-,SO2-4-H2O六元体系热力学模型,对该五元体系的平衡溶液组成和正确的平衡固相进行理论预测,给出了该体系的完整相图。结合硫酸锂混盐分离、加工实例阐述了该五元体系相图的应用。 相似文献
8.
系统测定了青海湟水河枯水期河水的硝酸盐(NO-3)含量及其氮同位素组成(δ15N-NO-3),详细分析了青海湟水河流域硝酸盐浓度及氮同位素组成的变化特征,基于此初步探讨了河水中可能的氮污染来源。结果显示,研究时段内湟水河河水的NO-3浓度范围为0.1~38.0 mg/L,平均值为15.9 mg/L,约56%的河水样品中的NO-3含量超过我国《地表水环境质量标准》中V类水氮含量的标准限值。湟水河河水δ15N-NO-3值的变化范围为+2.7‰~+16.8‰,平均值为+8.5‰,反映出受不同氮来源的影响。总体而言,湟水河NO-3浓度自源头至下游整体呈增大趋势,但各区段δ15N-NO-3值的变化幅度却存在较大差异。对比分析发现,流域内河水较高的δ15N-NO-3值可能指示河水中的硝态氮主要来源于工业生产以及人类生活排放的污水或粪便;而较低的δ15N-NO-3值指示河水中的硝态氮主要来源于大气氮沉降或与农业活动有关的土壤。 相似文献
9.
The crystal structure of metal borates has been extensively investigated by X-ray and neutron diffraction,but,the structure of aqueous polyborate solutions are still largely unknown.Over the last decade,our group has focused on studying the structure of complex aqueous polyborate solutions of Li,Na,K,Rb,Cs,and Mg using synchrotron radiation X-ray scattering(XRS),EXAFS,Raman,NMR,and DFT,as well as determining the density,conductivity and pH of such solutions.Polyborate species distributions were calculated using pH measurements,and the main species in the solution have been confirmed by NMR and Raman spectra.For alkali-metal metaborates,the dominant species is always B(OH)-4in a wide range of concentration,while the presence of others species is negligible.For alkali metal tetraborates,when concentration is in the extreme low range,only B(OH)3 and B(OH)-4 are present in these solutions.As the total boron concentration increases,B(OH)3 and B(OH)-4 polycondensated to form more complex oligomers.Of them,while B4O5(OH)2-4 in the tetraborate solutions is the main species,B(OH)3,B(OH)-4,and B3O3(OH)-4 are minor species,and B3O3(OH)2-5 and B5O6OH)-4 are present only in negligible amounts.As solution continues to concentrate,B4O5(OH)2-4 eventually becomes the dominant species,which is consistent with the congruent compound M2B4O7·nH2O(M=Li,Na,K,Rb,Cs) in the system M2O-B2O3-H2O(M=Li,Na,K,Rb,Cs).For alkali metal pentaborates,B(OH)3 and B(OH)-4 are the main species at low concentrations.The species distribution,Raman and NMR spectroscopy results verified that the dominant species in concentrated pentaborate solutions with Li and Na is pentaborate B5O6OH)-4,but it is surprising that the main species with K,Rb,and Cs is always the triborate monoanion B3O3(OH)-4.Although all M[B5O6OH)4]·nH2O(M=Li,Na,K,Rb,Cs) are all congruent compounds in the system M2O-B2O3-H2O(M=Li,Na,K,Rb,Cs) ,the main species in aqueous solutions are quite different because of various cation hydration distance(d),hydration number(CN),and configuration,especially charge(Z).For bivalent Mg2+,three borate minerals,namely,Inderite(2MgO·3B2O3·15H2O),Hungchaoite(MgO·2B2O3·9H2O),and Mcallisterite(MgO·3B2O3·7.5H2O),exist in the system MgO-B2O3-H2O at 298K.Inderite is a congruent compound,but Hungchaoite and Mcallisterite are incongruent compounds.The species distribution and Raman spectra demonstrat that the predominant species in all the solutions with magnesium borates is bivalent triborate B3O3(OH)2-5,while the subordinate species are B(OH)-4 at a low B2O3/MgO ratio and B(OH)3at a high B2O3/MgO ratio,and the other anions are negligible,as the high Z of the borate anion must match that of Mg2+.The disappearance of divalent B4O5(OH)2-4 is in agreement with its incongruent nature.The DFT and XRS results showed that tetrahedral Li(H2O)+4(d=0.20 nm,CN=4),octahedral Na(H2O)6+(d=0.236 nm,CN=6),and Mg(H2O)2+6(d=0.210 nm,CN=6) in the first hydration shell belong to Platonic polyhedra.However,K(H2O)+8(d=0.28 nm,CN=8,XRS and DFT),Rb(H2O)+8(d=0.293 nm,CN=7.7-8.2,EXAFS),and Cs(H2O)+8(d=0.320-0.326 nm,CN=7.6-7.9,EXAFS) are inclined Voronoi polyhedra.Therefore,the effects of cation Z and d on the structure of polyborates in aqueous solutions are deterministic,while the effect of hydrated-cation symmetry is secondary.Their hydrolysis order was:Mg＞Li＞Na＞K＞Rb＞Cs,in step with hydration power.Among them,Mg2+ and Li+have a strong tendency towards hydrolysis,but Na+ scarcely hydrolyzes,especially Rb+ and Cs+ have a little protonation.X-ray scattering of aqueous alkaline sodium borohydride solutions confirmed that dihydrogen bonds exist in an aqueous solution.The four distinct features of dihydrogen bonds in aqueous solution-unidirectionality,divaricativity,multicentricity,and multidentativity have been also described here in brief. 相似文献
10.
以察尔汗盐湖达布逊区段补水溶采区为研究区,靠近补水渠的D01、D03以及D05水文观测孔地下卤水为研究对象,通过水化学、相图等分析方法,研究了地下卤水在固液转化过程中水化学的时空变化特征及其影响因素。研究结果表明,储卤层中卤水化学特性在空间上具有明显差异性。在纵向上,随深度增加Na+、SO42-浓度、pH值降低,而Mg2+、Cl-、HCO3-、Li+、B3+浓度、TDS和比重升高;在横向上,D01孔中卤水具有较高的Na+、SO42-、HCO3-、Li+浓度、pH值以及较低的TDS和比重;D03孔中卤水具有较高的K+、B3+浓度;D05孔中具有较高的TDS、比重、Mg2+、Ca2+、Cl-以及Sr2+浓度。揭示了卤水在盐层中的滞留时间、盐层渗透性差异、矿物组合与分布及温度变化是影响地下卤水水化学分布特征的主要因素,并初步研究认为补水溶矿具有局限性,D01孔受补水影响最大,D03孔次之,D05孔受补水影响较弱。 相似文献
11.
于 1 998年 1 2月至 1 999年 1月南极夏季 ,对南大洋普里兹湾临近海域两种主要浮游桡足类Calanoides acutus和 Metridia gerlachei的耗氧率和排氨率进行了现场调查 ,同时对其代谢产物对海洋初级生产的贡献进行了探讨。调查结果表明 ,C. acutus的体碳、氮含量占干重百分比分别为 48.4%～ 48.6%和 6.1 %～ 6.5% ;M.gerlachei分别为 47.1 %～ 50 .1 %和 5.9%～ 7.4%。C.acutus在不同海区耗氧率有一定的差异 (0 .2 2 6～ 0 .558μl O2 mg- 1h- 1)。排氨率变化范围为 0 .0 1 4～ 1 .0 58μg N mg- 1h- 1,最高值位于浮冰区 - 9站 ,在陆冰缘区 (FI站 )最小。不同海域其排氨率的高低与现场水温无相关性。不同站位上 C.acutus的 O:N比相差 5～ 6倍。M.gerlachei耗氧率为 0 .488～ 0 .644μl O2 mg- 1h- 1,排氨率为 0 .0 1 5～ 0 .0 34μg N mg- 1h- 1。根据代谢实验结果和桡足类自身碳氮含量推算 ,其维持正常代谢的碳、氮日损失率分别为 0 .59%～ 1 .99%和 0 .44%～ 3.2 7%。桡足类群体每天的碳需求量占初级生产力的 0 .6%～ 2 9.2 % ,氨氮日输出量占初级生产所需氮盐的 0 .2 %～ 38.0 %。 相似文献
12.
东日本自然湿地的土壤反硝化 总被引：1，自引：0，他引：1
地表水和地下水中硝酸盐污染已成为重要的环境问题之一。随着对全球变暖的贡献增加,N2O（氧化亚氮）也得到IPCC越来越多的关注。反硝化在水生生态系统氮循环过程中起着极为重要的作用。反硝化过程中,厌氧细菌将硝酸盐转化成可溶性亚硝酸盐,最终以N2形式排放到大气。为理解自然湿地生态系统的脱氮机理,以日本千叶县的越智小流域为例开展研究。沿地下水流动方向取原状土,包括2个非饱和带点和2个饱和带点。用乙炔抑制法和带ECD检测器的气相色谱仪于0, 2, 6, 12, 24h测定土壤反硝化能力。同时分析土壤全碳、全氮和反硝化细菌。结果发现,饱和带的反硝化能力高于非饱和带。乙炔抑制后,N2O排放从0-1.17 g Nm-2h-1,前6h增至最大,随后降低。 相似文献
13.
High N2O emissions have been observed in semi-arid grasslands, especially during freeze/thaw periods, when denitrification might be the main process of N2O production. However, there have been few denitrification studies in semi-arid grassland. This study was designed to determine the denitrification potential of four representative land cover types (typical steppe, meadow steppe, marshland, arid steppe) in two grasslands in Inner Mongolia, China. We found that soils from different land cover types exhibited significantly different denitrification potentials, with highest rates in marshland and lowest rates in arid steppe. Denitrification potentials were maximal in the upper layer and generally decreased with depth for all soils. Soil water content, soil carbon and nitrogen availability, and C/N ratio were found to be significantly correlated with denitrification potentials in all soils. Addition of glucose or/and nitrate significantly increased denitrification activities throughout the profile for all soils, suggesting that both bioavailable carbon and nitrogen were limiting factors of denitrification in these grasslands soils. However, further field studies are needed to translate the denitrification potentials determined in laboratory measurements to denitrification rates under field conditions. 相似文献
14.
为了解中亚热带地区不同植被类型土壤真菌生物量特征及影响因子,采用玻璃珠细胞破碎提取麦角甾醇法对福建省建瓯市万木林自然保护区内米槠天然林和杉木人工林土壤真菌进行研究,结果表明：1）米槠天然林和杉木人工林0~10 cm土层真菌生物量均显著高于10~20 cm土层。2）相同植被类型,随着海拔高度增加,米槠天然林0~10 cm和10~20 cm土层真菌生物量分别由1.34 mg·g^-1和0.63 mg·g^-1增加到3.28 mg·g^-1和1.46 mg·g^-1,增幅分别达到144.8%和131.7%,但只有0~10 cm土层差异显著。3）不同植被类型,米槠天然林0~10 cm和10~20 cm土层真菌生物量均显著高于杉木人工林相应土层,分别是杉木人工林的1.65和1.91倍。真菌生物量与土壤理化因子的相关分析结果表明：中亚热带地区森林土壤真菌生物量主要受pH值、土壤有机碳、硝态氮、总氮和C/N的影响,表现为真菌生物量与总氮呈显著正相关,与土壤有机碳和C/N呈极显著正相关,与pH值和硝态氮呈极显著负相关。 相似文献
15.
2008 a夏对可可西里地区东部4个新发现的盐湖,进行了卤水水化学组分、矿物组成及其石盐元素含量分析。结果表明,该区水体卤水矿化度高,湖表卤水富硼锂等组分。通过对化学组分及水化学特征系数的研究,卤水的水化学类型主要为硫酸镁亚型和硫酸钠亚型。卤水pH值随着矿化度的增加而降低。Na+、Cl-含量与总矿化度呈正相关,SO42-"与矿化度呈负相关。Li与Mg物源、迁移规律近似。本区盐类沉积物以石盐为主,石盐中Si、Al、Fe、Sr含量低,其间相关性好,物质来源可能为周围岩石风化。布查盐湖盐类沉积存在少量硬石膏、半水石膏和铁白云石,表明布查盐湖的盐类物质来源很可能与地下热水作用有关。 相似文献
16.
We conducted a paleolimnological investigation of late Holocene deposits on a distal, constrained floodplain of the Cauca River, northern Colombia, i.e. the La Caimana sedimentary succession. The record starts sometime between 4,500 and 4,000 cal yr BP, when the first high-energy fluvial events inundated an ancient soil surface. From that time until about 3,260 cal yr BP, a stable and probably seasonal flooding regime was established on the floodplain. From ~3,260 to ~2,800 cal yr BP, ephemeral and shallow swamps developed on the floodplain. Their formation and duration depended on their connection with the Cauca River. From ~2,800 to ~2,400 cal yr BP, fluvial influence became more dominant, establishing a semi-permanent connection between the river and the floodplain. From ~2,400 to 1,400 cal yr BP, episodic formation of ephemeral swamps occurred. During this stage, floodplain lakes displayed high salinity and nutrient concentrations, and possibly alkaline conditions as a consequence of reduced water volume when the connection with the river was reduced or lost completely. A change in the hydrological regime occurred from ~1,400 to ~850 cal yr BP, when high-energy fluvial events were punctuated by periods of reduced flooding that enabled soil formation. Generally, connection with the Cauca River resulted in lake waters with low salinity and nutrient concentration, whereas loss of connection with the river led to lakes with greater salinity and nutrient content. Paleocurrent analyses indicate that flows came predominantly from the Cauca River, suggesting the lakes were formed by the impoundment of La Caimana Creek. The sedimentary succession of La Caimana offers a unique, high-resolution record of the evolution and dynamics of an ancient floodplain of the Cauca River and its aquatic ecosystems. 相似文献
17.
Water isotopic and hydrochemical evolution of a lake chain in the northern Great Plains and its paleoclimatic implications 总被引：2，自引：2，他引：0
Oxygen isotopes and geochemistry from lake sediments are commonly used as proxies of past hydrologic and climatic conditions, but the importance of present-day hydrologic processes in controlling these proxies are sometimes not well established and understood. Here we use present-day hydrochemical data from 13 lakes in a hydrologically connected lake chain in the northern Great Plains (NGP) to investigate isotopic and solute evolution along a hydrologic gradient. The 18O and 2H of water from the chain of lakes, when plotted in 2H - 18O space, form a line with a slope of 5.9, indicating that these waters fall on an evaporation trend. However, 10 of the 13 lakes are isotopically similar (18O = –6 ± 1 VSMOW) and show no correlation with salinity (which ranges from 1 to 65). The lack of correlation implies that the isotopic composition of various source waters rather than in-lake evaporation is the main control of the 18O of the lakes. Groundwater, an important input in the water budget of this chain of lakes, has a lower 18O value (–16.7 in 1998) than that of mean annual precipitation (–11) owing to selective recharge from snow melt. For the lakes in this chain with salinity < 15, the water Mg/Ca ratios are strongly correlated with salinity, whereas Sr/Ca is not. The poor correlation between Sr/Ca and salinity results from uptake of Sr by endogenic aragonite. These new results indicate that 18O records may not be interpreted simply in term of climate in the NGP, and that local hydrology needs to be adequately investigated before a meaningful interpretation of sedimentary records can be reached. 相似文献
18.
生物结皮恢复过程中土壤生态因子分异特征 总被引：19，自引：14，他引：5
对新疆古尔班通古特沙漠生物结皮恢复过程中土壤因子的动态变化进行关联性测度、方差分析、相关性分析相结合的定量研究,着重分析结皮恢复年限对土壤微生物数量、养分、盐分、土壤酶的影响,有机质与土壤盐分、pH值、土壤酶的线性关系及土壤生态因子间的相关性。结果表明：相对于土层深度,有机养分、土壤酶等生态因子与生物结皮恢复年限的联系更加紧密。结皮恢复年限对全P、全K、有机质、脲酶、真菌的影响极显著（P<0.01）;对速效P、速效K、全N、总盐、中性碱性磷酸酶、蛋白酶的影响显著(P<0.05)。随结皮恢复年限的增加,结皮层和结皮以下土层中有机养分、土壤酶均有不同程度的增加,逐步具备较高的生物学活性,沙土性状变化较快,渐渐形成抗风蚀、抗干扰能力较强的地衣苔藓结皮。结皮恢复过程中pH值与有机质呈显著线性负相关（R2＝0.701,P<0.05）,土壤盐分与有机质存在线性正相关（R2＝0.653）,但显著性不强（P>0.05）。电导率、脲酶、碱性磷酸酶、中性磷酸酶、蛋白酶与有机质存在极为显著的线性正相关（R2分别为0.888、0.993、0.958、0.948、0.911,P<0.01）,土壤生态因子的协调发展和紧密配合促进了生物结皮的恢复。 相似文献
19.
运用静态箱-气相色谱法对中亚热带地区米槠天然林和阿丁枫天然林土壤N2O排放速率进行了1年（2012年1月—2013年1月）原位观测,分析了土壤温度及含水量对土壤N2O排放速率的影响,并探讨土壤无机N含量变化与土壤N2O排放速率的关系。结果表明,观测期间,2种天然林均表现为大气N2O排放源,米槠天然林和阿丁枫天然林平均土壤N2O排放速率分别为7.29μg·m^-2·h^-1、7.41μg·m^-2·h^-1;米槠天然林和阿丁枫天然林土壤N2O排放速率季节变化明显,最高排放速率均出现在夏季6月,分别为16.51μg·m^-2·h^-1、18.86μg·m^-2·h^-1;2个林分N2O排放速率最低值分别出现在2012年1月和2012年9月,分别为3.04μg·m^-2·h^-1和2.17μg·m^-2·h^-1。2种天然林土壤N2O排放速率均与土壤温度无显著相关性,与土壤含水量显著正相关（P〈0.05）;2种天然林土壤N2O排放速率与NH4＋含量均无显著相关性,米槠天然林和阿丁枫天然土壤N2O排放速率与NO3-含量分别呈显著负相关和显著正相关（P〈0.05）。研究结果表明,土壤含水量及NO3-含量的变化对中亚热带天然林土壤N2O排放速率有着重要的影响。 相似文献
20.
草原土壤的碳氮含量及其与温室气体通量的相关性 总被引：61，自引：0，他引：61
通过采样分析研究内蒙古锡林流域温带草原土壤有机碳及全N的含量特征,探讨它们的含量与温室气体CO2、N2O、CH4通量的相关性。结果表明：沿470－150mm年降水梯度线，土壤表层（0－20cm）有机碳含量从2．38％递减到1．23％，全N含量从0．218％递减到0．136％，而且放牧和开垦都有使有机碳及全N含量降低的趋势；CO2通量与有机碳含量、全N含量、C／N及N2O通量显著相关，N2O通量与有机碳含量、C／N及CO2通量显著相关，且CO2和N2O的通量都有沿降水梯度递减的趋势；CH4通量与有机碳含量、全N含量、C／N、CO2通量及N2O通量都没有显著相关性。 相似文献