Formation and stability of schwertmannite in acidic mining lakes     

Simona Regenspurg  Andreas Brand 《Geochimica et cosmochimica acta》2004,68(6):1185-1197

Schwertmannite (ideal formula: Fe₈O₈(OH)₆SO₄) is typically found as a secondary iron mineral in pyrite oxidizing environments. In this study, geochemical constraints upon its formation are established and its role in the geochemical cycling of iron between reducing and oxidizing conditions are discussed. The composition of surface waters was analyzed and sediments characterized by X-ray diffraction, FTIR spectroscopy and determination of the Fe:S ratio in the oxalate extractable fraction from 18 acidic mining lakes. The lakes are exposed to a permanent supply of pyritegenous ferrous iron from adjacent ground water. In 3 of the lakes the suspended matter was fractionated using ultra filtration and analyzed with respect to their mineral composition. In addition, stability experiments with synthetic schwertmannite were performed. The examined lake surface waters were O₂-saturated and have sulfate concentrations (10.3 ± 5.5 mM) and pH values (3.0 ± 0.6) that are characteristic for the stability window of schwertmannite. Geochemical modeling implied that i) the waters were saturated with respect to schwertmannite, which controlled the activity of Fe³⁺ and sulfate, and ii) a redox equilibrium exists between Fe²⁺ and schwertmannite. In the uppermost sediment layers (1 to 5 cm depth), schwertmannite was detectable in 16 lakes—in 5 of them by all three methods. FTIR spectroscopy also proved its occurrence in the colloidal fraction (1-10 kDa) in all of the 3 investigated lake surface waters. The stability of synthetic schwertmannite was examined as a function of pH (2-7) by a 1-yr experiment. The transformation rate into goethite increased with increasing pH. Our study suggests that schwertmannite is the first mineral formed after oxidation and hydrolysis of a slightly acidic (pH 5-6), Fe(II)-SO₄ solution, a process that directly affects the pH of the receiving water. Its occurrence is transient and restricted to environments, such as acidic mining lakes, where the coordination chemistry of Fe³⁺ is controlled by the competition between sulfate and hydroxy ions (i.e. mildly acidic).  相似文献   

The dynamic model Seemod applied to the Southern Basin of Lake Lugano   总被引：1，自引：1，他引：1  

F. Zamboni  A. Barbieri  B. Polli  G. Salvadè  M. Simona 《Aquatic Sciences - Research Across Boundaries》1992,54(3-4):367-380

The dynamic model Seemod developed at the EAWAG (Imboden and Gächter, 1978) and modified by Bührer (Ambühl and Bührer, 1984), was adapted to the South Basin of the Lake of Lugano (Lago di Lugano). The model can predict the evolution of the state of the lake, described by the concentrations of dissolved phosphorus, dissolved oxygen particulate phosphorus and organic particulate carbon, in function of phosphorus load and taking into account physical and biochemical initial- and boundary conditions. The model parameters were chosen through measurements and calibrations by short runs. A 10-year-long simulation was done, starting from the data of 1980, and its results agree quite well with the measurements. Then some 15-year-long simulations were done, which corresponded to different scenarios related to a progressive linking up of sewage systems to water treatment plants. The model predicts that a satisfactory water quality level can only be reached by reducing the total phosphorus input to less than 25 t/a.  相似文献   

The altitudinal temperature lapse rates applied to high elevation rockfalls studies in the Western European Alps     

Nigrelli  Guido  Fratianni  Simona  Zampollo  Arianna  Turconi  Laura  Chiarle  Marta 《Theoretical and Applied Climatology》2018,131(3-4):1479-1491

Theoretical and Applied Climatology - Temperature is one of the most important aspects of mountain climates. The relationships between air temperature and rockfalls at high-elevation sites are very...  相似文献   

The evolution of temperature extremes in the Gaspé Peninsula,Quebec, Canada (1974–2013)     

Guillaume?FortinEmail authorView author&#;s OrcID profile  Fiorella?Acquaotta  Simona?Fratianni 《Theoretical and Applied Climatology》2017,130(1-2):163-172

The majority of natural hazards that affect Canadian territory are the result of extreme climate and weather conditions. Among these weather hazards, some can be calculated from the application of thresholds for minimum and maximum temperatures at a daily or monthly timescale. These thermal indices allowed the prediction of extreme conditions that may have an impact on the human population by affecting, for example, health, agriculture, and water resources. In this article, we discuss the methods used (RHtestsV4, SPLIDHOM, ClimPACT) then describe the steps followed to calculate the indices, including how we dealt with the problem of missing data and the necessity to identify a common methodology to analyze the time series. We also present possible solutions for ensuring the quality of meteorological data. We then present an overview of the results, namely the main trends and variability of extreme temperature for seven stations located in the Gaspé Peninsula from 1974 to 2013. Our results indicate some break points in time series and positive trends for most indices related to the rise of the temperatures but indicate a negative trend for the indices related to low temperatures for most stations during the study period.  相似文献   

Interannual-decadal variability of wintertime mixed layer depths in the North Pacific detected by an ensemble of ocean syntheses     

Toyoda  Takahiro  Fujii  Yosuke  Kuragano  Tsurane  Kosugi  Naohiro  Sasano  Daisuke  Kamachi  Masafumi  Ishikawa  Yoichi  Masuda  Shuhei  Sato  Kanako  Awaji  Toshiyuki  Hernandez  Fabrice  Ferry  Nicolas  Guinehut  Stéphanie  Martin  Matthew  Andrew Peterson  K.  Good  Simon A.  Valdivieso  Maria  Haines  Keith  Storto  Andrea  Masina  Simona  Köhl  Armin  Yin  Yonghong  Shi  Li  Alves  Oscar  Smith  Gregory  Chang  You-Soon  Vernieres  Guillaume  Wang  Xiaochun  Forget  Gael  Heimbach  Patrick  Wang  Ou  Fukumori  Ichiro  Lee  Tong  Zuo  Hao  Balmaseda  Magdalena 《Climate Dynamics》2017,49(3):891-907

Climate Dynamics - The interannual-decadal variability of the wintertime mixed layer depths (MLDs) over the North Pacific is investigated from an empirical orthogonal function (EOF) analysis of an...  相似文献   

Spatial and temporal structure of Tropical Pacific interannual variability in 20th century coupled simulations   总被引：1，自引：0，他引：1  

Antonietta Capotondi  Andrew Wittenberg  Simona Masina 《Ocean Modelling》2006,15(3-4):274

Tropical Pacific interannual variability is examined in nine state-of-the-art coupled climate models, and compared with observations and ocean analyses data sets, the primary focus being on the spatial structure and spectral characteristics of El Niño-Southern Oscillation (ENSO). The spatial patterns of interannual sea surface temperature (SST) anomalies from the coupled models are characterized by maximum variations displaced from the coast of South America, and generally extending too far west with respect to observations. Thermocline variability is characterized by dominant modes that are qualitatively similar in all the models, and consistent with the “recharge oscillator” paradigm for ENSO. The meridional scale of the thermocline depth anomalies is generally narrower than observed, a result that can be related to the pattern of zonal wind stress perturbations in the central-western equatorial Pacific. The wind stress response to eastern equatorial Pacific SST anomalies in the models is narrower and displaced further west than observed. The meridional scale of the wind stress can affect the amount of warm water involved in the recharge/discharge of the equatorial thermocline, while the longitudinal location of the wind stress anomalies can influence the advection of the mean zonal temperature gradient by the anomalous zonal currents, a process that may favor the growth and longer duration of ENSO events when the wind stress perturbations are displaced eastwards. Thus, both discrepancies of the wind stress anomaly patterns in the coupled models with respect to observations (narrow meridional extent, and westward displacement along the equator) may be responsible for the ENSO timescale being shorter in the models than in observations. The examination of the leading advective processes in the SST tendency equation indicates that vertical advection of temperature anomalies tends to favor ENSO growth in all the CGCMs, but at a smaller rate than in observations. In some models it can also promote a phase transition. Longer periods tend to be associated with thermocline and advective feedbacks that are in phase with the SST anomalies, while advective tendencies that lead the SST anomalies by a quarter cycle favor ENSO transitions, thus leading to a shorter period.  相似文献   

Tenoumer impact crater,Mauritania: Impact melt genesis from a lithologically diverse target          下载免费PDF全文

Dina Simona Schultze  Fred Jourdan  Lutz Hecht  Wolf Uwe Reimold  Ralf‐Thomas Schmitt 《Meteoritics & planetary science》2016,51(2):323-350

Impact melt rocks from the 1.9 km diameter, simple bowl‐shaped Tenoumer impact crater in Mauritania have been analyzed chemically and petrologically. They are heterogeneous and can be subdivided into three types based on melt matrix color, occurrence of lithic clast components, amount of vesiculation (melt degassing), different proportions of carbonate melt mingled into silicate melt, and bulk rock chemical composition. These heterogeneities have two main causes (1) due to the small size of the impact crater, there was probably no coherent melt pool where a homogeneous mixture of melts, derived from different target lithologies, could be created; and (2) melt rock heterogeneity occurring at the thin section scale is due to fast cooling during and after the dynamic ejection and emplacement process. The overall period of crystal growth from these diverse melts was extremely short, which provides a further indication that complete chemical equilibration of the phases could not be achieved in such short time. Melt mixing processes involved in the generation of impact melts are, thus, recorded in nonequilibrium growth features. Variable mixing processes between chemically different melt phases and the formation of hybrid melts can be observed even at millimeter scales. Due to extreme cooling rates, different mixing and mingling stages are preserved in the varied parageneses of matrix minerals and in the mineral chemistry of microlites. ⁴⁰Ar³⁹Ar step‐heating chronology on specimens from three melt rock samples yielded five concordant inverse isochron ages. The inverse isochron plots show that minute amounts of inherited ⁴⁰Ar* are present in the system. We calculated a weighted mean age of 1.57 ± 0.14 Ma for these new results. This preferred age represents a refinement from the previous range of 21 ka to 2.5 Ma ages based on K/Ar and fission track dating.  相似文献   

Representivity of incompletely sampled fall deposits in estimating eruption source parameters: a test using the 12–13 January 2011 lava fountain deposit from Mt. Etna volcano,Italy     

Daniele Andronico  Simona Scollo  Antonio Cristaldi  Maria Deborah Lo Castro 《Bulletin of Volcanology》2014,76(10):1-14

The Southeast Crater (SEC) of Mt. Etna, Italy, is renowned for its high activity, mainly long-lived eruptions consisting of sequences of individual paroxysmal episodes which have produced more than 150 eruptive events since 1998. Each episode typically forms eruption columns followed by tephra fallout over distances of up to about 100 km from the vent. One of the last sequences consisted of 25 lava fountaining events, which took place between January 2011 and April 2012 from a pit-vent on the eastern flank of the SEC and built a new scoria cone renamed New Southeast Crater. The first episode on 12–13 January 2011 produced tephra fallout which was unusually dispersed toward to the South extending out over the Mediterranean Sea. The southerly deposition of tephra permitted an extensive survey at distances between ~1 and ~100 km, providing an excellent characterization of the tephra deposit. Here, we document the stratigraphy of the 12–13 January fallout deposit, draw its dispersal, and reconstruct its isopleth map. These data are then used to estimate the main eruption source parameters. The total erupted mass (TEM) was calculated by using four different methodologies which give a mean value of 1.5?±?0.4?×?10⁸ kg. The mass eruption rate (MER) is 2.5?±?0.7?×?10⁴ kg/s using eruption duration of 100 min. The total grain-size (TGS) distribution, peaked at ?3 phi, ranges between ?5 and 5 phi and has a median value of ?1.4 phi. Further, for the eruption column height, we obtained respective values of 6.8–13.8 km by using the method of Carey and Sparks (1986) and 3.4?±?0.3 km by using the methods of Wilson and Walker (1987), Mastin et al. (2009), and Pistolesi et al. (2011) and considering the mean value of MER from the deposit. We also evaluated the uncertainty and reliability of TEM and TGS for scenarios where the proximal and distal samples are not obtainable. This is achieved by only using a sector spanning the downwind distances between 6 and 23 km. This scenario is typical for Etna when the tephra plume is dispersed eastward, i.e., in the prevailing wind direction. Our results show that, if the analyzed deposit has poorer sample coverage than presented in this study, the TEM (3.4?×?10⁷ kg) is 22 % than the TEM obtained from the whole deposit. The lack of the proximal (<6 km) deposit may cause more significant differences in the TGS estimations.  相似文献   

Use of sedimentary pigments to infer past phosphorus concentration in lakes     

Piero Guilizzoni  Aldo Marchetto  Andrea Lami  Stefano Gerli  Simona Musazzi 《Journal of Paleolimnology》2011,45(4):433-445

We propose a palaeolimnological method for inferring past total phosphorus (TP) concentrations in lake water from spectrophotometrically-measured sedimentary pigments, particularly total carotenoids (TC). Our approach is based on a highly significant statistical correlation (P < 0.0001) between pigment concentrations (total carotenoids) in the surface sediment of 28 Italian lakes (subalpine, large, deep, shallow, volcanic) and TP concentrations measured in these lakes at overturn when the core was collected. A transfer function was developed from this “training” set, and used to estimate past TP concentrations from pigment concentrations in sediment cores. The results generally agreed with TP values as measured by long-term water quality monitoring programs. Contrasting results were obtained by a comparison with diatom-inferred TP. While the diatom model showed a tendency to overestimate TP values higher than 100 μg l⁻¹, the pigment model correctly estimated TP in lakes when TP was <100 μg l⁻¹, but not when lakes were rich in macrophytes. In fact, lakes with extensive populations of aquatic submersed macrophytes and epiphytes are outliers in terms of the TC versus TP relationship. The root mean square error of prediction of the pigment model is lower than those derived from certain diatom—based inference models. The predicted and residual values are not related to the estimated values and their average is not statistically different from zero. Errors were estimated via a ‘leave-one-out’ re-sampling technique. The proposed method permits rapid and relatively inexpensive determination of reference trophic conditions.  相似文献   

K-feldspar rich shales from Jurassic bedded cherts in southeastern Slovenia     

Simona Skobe  Špela Goričan  Dragomir Skaberne  Tomaž Verbič  Miha Mišič  Nina Zupančič 《Swiss Journal of Geoscience》2013,106(3):491-504

The study area in southeastern Slovenia is part of the transitional zone between the internal and the external Dinarides. Within Jurassic bedded cherts there are up to 2 cm thick shale intercalations, consisting of laminated, soft, fine-grained, green to brown material whose origin has been in question. In the majority of Tethyan cherts, the interbedded material is reported to be volcanogenic and/or terrigenous, although a detailed mineralogical analysis of the material is lacking. An XRD analysis confirmed the presence of quartz, illite, chlorite and K-feldspar, which is the prevailing component in some samples. Major and trace element data exclude both a volcanogenic and an hydrothermal origin. Several discrimination diagrams indicate the upper crustal terrigenous nature of shales and a biogenic silica source. The source material was probably from a Variscan crust, which at the time of deposition had already been weathered to kaolinite, and some sporadic muscovite. The MnO/Al₂O₃ ratio suggests a slow sedimentation rate of cherts and a faster one for shales, which probably settled from distal turbidity currents. The negative Ce anomaly indicates prolonged contact with ocean water. Sediments were deposited on a Tethyan passive margin, originally as silica-rich carbonate beds intercalated with mud. During late diagenesis, the mixing of marine and meteoric waters caused the further silicification of limestone and simultaneous potassium enrichment of shale which led to their alteration into illite or chlorite and, in sediments already rich in K-minerals, into K-feldspar.  相似文献