Carbonaceous chondrites as analogs for the composition and alteration of Ceres          下载免费PDF全文

Harry Y. McSween Jr.  Joshua P. Emery  Andrew S. Rivkin  Michael J. Toplis  Julie C. Castillo‐Rogez  Thomas H. Prettyman  M. Cristina De Sanctis  Carle M. Pieters  Carol A. Raymond  Christopher T. Russell 《Meteoritics & planetary science》2018,53(9):1793-1804

The mineralogy and geochemistry of Ceres, as constrained by Dawn's instruments, are broadly consistent with a carbonaceous chondrite (CM/CI) bulk composition. Differences explainable by Ceres’s more advanced alteration include the formation of Mg‐rich serpentine and ammoniated clay; a greater proportion of carbonate and lesser organic matter; amounts of magnetite, sulfide, and carbon that could act as spectral darkening agents; and partial fractionation of water ice and silicates in the interior and regolith. Ceres is not spectrally unique, but is similar to a few other C‐class asteroids, which may also have suffered extensive alteration. All these bodies are among the largest carbonaceous chondrite asteroids, and they orbit in the same part of the Main Belt. Thus, the degree of alteration is apparently related to the size of the body. Although the ammonia now incorporated into clay likely condensed in the outer nebula, we cannot presently determine whether Ceres itself formed in the outer solar system and migrated inward or was assembled within the Main Belt, along with other carbonaceous chondrite bodies.  相似文献   

Best practices for the use of meteorite names in publications     

Philipp R. Heck  Christopher Herd  Jeffrey N. Grossman  Dmitry Badjukov  Audrey Bouvier  Emma Bullock  Hasnaa Chennaoui‐Aoudjehane  Vinciane Debaille  Tasha L. Dunn  Denton S. Ebel  Ludovic Ferrire  Laurence Garvie  Jrme Gattacceca  Matthieu Gounelle  Richard Herd  Trevor Ireland  Emmanuel Jacquet  Robert J. Macke  Tim McCoy  Francis M. McCubbin  Takashi Mikouchi  Knut Metzler  Mathieu Roskosz  Caroline Smith  Meenakshi Wadhwa  Linda Welzenbach‐Fries  Toru Yada  Akira Yamaguchi  Ryan A. Zeigler  Michael Zolensky 《Meteoritics & planetary science》2019,54(7):1397-1400

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Insights into agricultural influences and weathering processes from major ion patterns          下载免费PDF全文

Robert van Geldern  Peter Schulte  Michael Mader  Alfons Baier  Johannes A.C. Barth  Tobias R. Juhlke  Kern Lee 《水文研究》2018,32(7):891-903

Karst areas and their catchments pose a great challenge for protection because fast conduit flow results in low natural attenuation of anthropogenic contaminants. Studies of the hydrochemistry of karst sources and river solutes are an important tool for securing and managing water resources. A study of the geochemical downriver evolution of the Wiesent River and its tributaries, located in a typical karst terrain, revealed unexpected downstream decreases of nitrate with maximum mean values of 30 mg/L at the source to minimum values of 18 mg/L near the river mouth. This trend persisted over the length of the river even though increased agricultural activities are evident in the downstream section of the catchment. This pattern is caused by fertilizer inputs via diffusive and fast conduits flow from karst lithology in the upstream area that may have reached the river's source even from beyond the hydrological catchment boundaries. Further downstream, these influences became diluted by tributary inputs that drain subcatchments dominated by claystone and sandstone lithologies that increased potassium and sulphate concentrations. Our findings indicate that bedrock geology remains the dominant control on the major ion chemistry of the Wiesent River and that agricultural influences are strongest near the headwaters despite increased land use further downstream, due to long‐term storage and accumulation in karst aquifers. This feature may not be unique to the Wiesent River system, as carbonates cover significant portions of the Earth's surface and subsequent work in other river systems could establish whether such patterns are ubiquitous worldwide.  相似文献   

Calibration of oxygen isotope fractionation and calcite-corundum thermometry in emery at Naxos,Greece     

Rachelle B. Turnier  Yaron Katzir  Kouki Kitajima  Ian J. Orland  Michael J. Spicuzza  John W. Valley 《Journal of Metamorphic Geology》2020,38(1):53-70

Corundum (Crn), including sapphire, occurs in emery pods surrounded by marble on the island of Naxos, Greece. The emery formed from bauxite deposited in karst that was metamorphosed to 400–700°C at 20–15 Ma. Many of these rocks initially appeared well suited for refractory accessory mineral (RAM) thermometry, which uses oxygen isotope fractionation between a RAM – corundum – and a modally dominant phase with faster diffusion of oxygen – calcite (Cc) – to determine peak metamorphic temperatures. However, previous attempts at oxygen isotope thermometry were confounded by highly variable fractionations (Δ¹⁸O) measured at mm-scale and the uncertain calibration of Δ¹⁸O(Cc-Crn) versus temperature. Secondary ion mass spectrometry (SIMS) permits in situ analysis of δ¹⁸O in corundum and calcite at the 10-μm scale in adjacent grains where textures suggest peak metamorphic equilibrium was attained. SIMS analyses of adjacent mineral pairs in eight rocks yield values of Δ(Cc-Crn) that systematically decrease from 7.2 to 2.9‰ at higher metamorphic grade. Pairing these data with independent temperature estimates from mineral isograds yields an empirical calibration of 1,000 lnα(Cc-Crn) = 2.72 ± 0.3 × 10⁶/T² (T in K). The new fractionations (2.7‰ at 1,000 K) are significantly smaller than those calculated from the modified increment method (6.5‰ at 1,000 K; Zheng, Geochimica et Cosmochimica Acta, 1991, 55:2299–2307; Zheng, Mineral Mag, 1994, 58A:1000–1001), which yield unreasonably high temperatures of 630 to 1,140°C when applied to the new Naxos data. The new calibration of Δ(Cc-Crn) can be combined with published fractionations to calculate A-factors for corundum versus a range of 14 other minerals. These new fractionation factors can be used for thermometry or to constrain the genesis of corundum. A compilation of gem corundum δ¹⁸O values shows that many igneous sapphires, including important deposits of basalt-associated sapphire, are mildly elevated in δ¹⁸O relative to the calculated range in equilibrium with mantle values (4.4–5.7‰) and formed from evolved magmas.  相似文献   

Untangling global change impacts on hydrological processes: Resisting climatization     

Michael L. Wine  Jason H. Davison 《水文研究》2019,33(15):2148-2155

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Titanite dates crystallization: Slow Pb diffusion during super‐solidus re‐equilibration     

Michael I. H. Hartnady  Christopher L. Kirkland  Chris Clark  Catherine V. Spaggiari  R. Hugh Smithies  Noreen J. Evans  Brad J. McDonald 《Journal of Metamorphic Geology》2019,37(6):823-838

Titanite can be found in rocks of wide compositional range, is reactive, growing or regrowing during metamorphic and hydrothermal events, and is generally amenable to U–Pb geochronology. Experimental evidence suggest that titanite has a closure temperature for Pb ranging from 550 to 650°C, and thus titanite dates are commonly interpreted as cooling ages. However, this view has been challenged in recent years by evidence from natural titanite which suggests the closure temperature may be significantly higher (up to 800°C). Here, we investigate titanite in an enclave of migmatitic gneiss included within a granite intrusion. The titanite crystals exhibit textural features characteristic of fluid‐mediated mass transfer processes on length scales of <100 µm. These textural features are associated with variation in both Pb concentrations and distinct U–Pb isotopic compositions. Zr‐in‐titanite thermometry indicates that modification of the titanite occurred at temperatures in excess of 840°C, in the presence of a high‐T silicate melt. The Pb concentration gradients preserved in these titanite crystals are used to determine the diffusivity of Pb in titanite under high‐T conditions. We estimate diffusivities ranging from 2 × 10^?22 to 5 × 10^?25 m²/s. These results are significantly lower than experimental data predict yet are consistent with other empirical data on natural titanites, suggesting that Pb diffusivity is similar to that of Sr. Thus our data challenge the wide‐held assumption that U–Pb titanite dates only reflect cooling ages.  相似文献   

Petrogenesis of lunar impact melt rock meteorite Oued Awlitis 001     

Axel Wittmann  Randy L. Korotev  Bradley L. Jolliff  Kunihiko Nishiizumi  A. J. Timothy Jull  Marc W. Caffee  Michael Zanetti  Anthony J. Irving 《Meteoritics & planetary science》2019,54(10):2167-2188

Oued Awlitis 001 is a highly feldspathic, moderately equilibrated, clast‐rich, poikilitic impact melt rock lunar meteorite that was recovered in 2014. Its poikilitic texture formed due to moderately slow cooling, which judging from textures of rocks in melt sheets of terrestrial impact structures, is observed in impact melt volumes at least 100 m thick. Such coherent impact melt volumes occur in lunar craters larger than ~50 km in diameter. The composition of Oued Awlitis 001 points toward a crustal origin distant from incompatible‐element‐rich regions. Comparison of the bulk composition of Oued Awlitis 001 with Lunar Prospector 5° γ‐ray spectrometer data indicates a limited region of matches on the lunar farside. After its initial formation in an impact crater larger than ~50 km in diameter, Oued Awlitis 001 was excavated from a depth greater than ~50 m. The cosmogenic nuclide inventory of Oued Awlitis 001 records ejection from the Moon 0.3 Ma ago from a depth of at least 4 m and little mass loss due to ablation during its passage through Earth's atmosphere. The terrestrial residence time must have been very short, probably less than a few hundred years; its exact determination was precluded by a high concentration of solar cosmic ray‐produced ¹⁴C. If the impact that excavated Oued Awlitis 001 also launched it, this event likely produced an impact crater >10 km in diameter. Using petrologic constraints and Lunar Reconnaissance Orbiter Camera and Diviner data, we test Giordano Bruno and Pierazzo as possible launch craters for Oued Awlitis 001.  相似文献   

Influence of length effect on embankment slope reliability in 3D          下载免费PDF全文

Michael A. Hicks  Yajun Li 《国际地质力学数值与分析法杂志》2018,42(7):891-915

Embankment slopes composed of spatially variable soils have a variety of different failure modes that are affected by the correlation distances of the material properties and the geometry and total length of the slope. This paper examines the reliability of soil slopes for embankments of different length and uses parallel computing to analyse very long embankments (up to 100 times the embankment height) for a clay soil characterised by a spatially varying undrained shear strength. Based on a series of analyses using the 3D random finite element method (RFEM), it is first shown that the reliability of slopes of various length can be efficiently computed by combining simple probability theory with a detailed 3D RFEM analysis of a representative shorter slope of length 10 times the slope height. RFEM predictions of reliability indices for longer slopes are then compared with results obtained using Vanmarcke's (1977a) simplified 3D method and Calle's (1985) extended 2D approach. It is shown that these methods can give significantly different results, depending on the horizontal scale of fluctuation relative to the slope length, with RFEM predicting a lower slope reliability than the Vanmarcke and Calle solutions in all cases. The differences in the solutions are evaluated and attributed to differences in the assumed and computed failure surface geometries.  相似文献   

Neogene upper‐crustal cooling of the Olympus range (northern Aegean): major role of Hellenic back‐arc extension over propagation of the North Anatolia Fault Zone     

Isabelle Coutand  Michael Walsh  Bertha Louis  Frank Chanier  Jacky Ferrière  Jean‐Yves Reynaud 《地学学报》2014,26(4):287-297

The North Anatolian Fault Zone (NAFZ) is one of the most hazardous active faults on Earth, yet its Pliocene space‐time propagation across the north Aegean domain remains poorly constrained. We use low‐temperature multi‐thermochronology and inverse thermal modelling to quantify the cooling history of the upper crust across the Olympus range. This range is located in the footwall of a system of normal faults traditionally interpreted as resulting from superposed Middle–Late Miocene N–S stretching, related to the back‐arc extension of the Hellenic subduction zone, and a Pliocene‐Quaternary transtensional field, attributed to the south‐westward propagation of the NAFZ. We find that accelerated exhumational cooling occurred between 12 and 6 Ma at rates of 15–35 °C Ma^?1 and decreased to <3 °C Ma^?1 by 8–6 Ma. The absence of significant Plio‐Pleistocene cooling across Olympus suggests that crustal exhumation there is driven by late Miocene back‐arc extension, while the impact of the NAFZ remains limited.  相似文献   

Stratigraphic architecture of Solander Basin records Southern Ocean currents and subduction initiation beneath southwest New Zealand     

Jiten Patel  Rupert Sutherland  Michael Gurnis  Harm Van Avendonk  Sean P. S. Gulick  Brandon Shuck  Joann Stock  Erin Hightower 《Basin Research》2021,33(1):403-426

Solander Basin is characterized by subduction initiation at the Pacific‐Australia plate boundary, where high biological productivity is found at the northern edge of the Antarctic Circumpolar Current. Sedimentary architecture results from tectonic influences on accommodation space, sediment supply and ocean currents (via physiography); and climate influence on ocean currents and biological productivity. We present the first seismic‐stratigraphic analysis of Solander Basin based on high‐fold seismic‐reflection data (voyage MGL1803, SISIE). Solander Trough physiography formed by Eocene rifting, but basinal strata are mostly younger than ca. 17 Ma, when we infer Puysegur Ridge formed and sheltered Solander Basin from bottom currents, and mountain growth onshore increased sediment supply. Initial inversion on the Tauru Fault started at ca. 15 Ma, but reverse faulting from 12 to ca. 8 Ma on both the Tauru and Parara Faults was likely associated with reorganization and formation of the subduction thrust. The new seabed topography forced sediment pathways to become channelized at low points or antecedent gorges. Since 5 Ma, southern Puysegur Ridge and Fiordland mountains spread out towards the east and Solander Anticline grew in response to ongoing subduction and growth of a slab. Solander Basin had high sedimentation rates because (1) it is sheltered from bottom currents by Puysegur Ridge; and (2) it has a mountainous land area that supplies sediment to its northern end. Sedimentary architecture is asymmetric due to the Subtropical Front, which moves pelagic and hemi‐pelagic sediment, including dilute parts of gravity flows, eastward and accretes contourites to the shelf south of Stewart Island. Levees, scours, drifts and ridges of folded sediment characterize western Solander Basin, whereas hemi‐pelagic drape and secondary gravity flows are found east of the meandering axial Solander Channel. The high‐resolution record of climate and tectonics that Solander Basin contains may yield excellent sites for future scientific ocean drilling.  相似文献