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71.
Dacitic magma, a mixture of high-temperature (T) aphyric magma and low-T crystal-rich magma, was erupted during the 1991–1995 Mount Unzen eruptive cycle. Here, the crystallization processes of the low-T magma were examined on the basis of melt inclusion analysis and phase relationships. Variation in water content of the melt inclusions (5.1–7.2 wt% H2O) reflected the degassing history of the low-T magma ascending from deeper levels (250 MPa) to a shallow magma chamber (140 MPa). The ascent rate of the low-T magma decreased markedly towards the emplacement level as crystal content increased. Cooling of magma as well as degassing-induced undercooling drove crystallization. With the decreasing ascent rate, degassing-induced undercooling decreased in importance, and cooling became more instrumental in crystallization, causing local and rapid crystallization along the margin of the magma body. Some crystals contain scores of melt inclusions, whereas there are some crystals without any inclusions. This heterogeneous distribution suggests the variation in the crystallization rate within the magma body; it also suggests that cooling was dominant cause for melt entrapment. Numerical calculations of the cooling magma body suggest that cooling caused rapid crystal growth and enhanced melt entrapment once the magma became a crystal-rich mush with evolved interstitial melt. The rhyolitic composition of melt inclusions is consistent with this model.Editorial responsibility: H Shinohara  相似文献   
72.
Summary. Dynamical rupture process on the fault is investigated in a quasi-three-dimensional faulting model with non-uniform distributions of static frictions or the fracture strength under a finite shearing pre-stress. The displacement and stress time functions on the fault are obtained by solving numerically the equations of motion with a finite stress—fracture criterion, using the finite difference method.
If static frictions are homogeneous or weakly non-uniform, the rupture propagates nearly elliptically with a velocity close to that of P waves along the direction of pre-stress and with a nearly S wave velocity in the direction perpendicular to it. The rise time of the source function and the final displacements are larger around the centre of the fault. In the case when the static frictions are heavily non-uniform and depend on the location, the rupture propagation becomes quite irregular with appreciably decreased velocities, indicating remarkable stick-slip phenomena. In some cases, there remain unruptured regions where fault slip does not take place, and high stresses remain concentrated up to the final stage. These regions could be the source of aftershocks at a next stage.
The stick—slip faulting and irregular rupture propagation radiate high-frequency seismic waves, and the near-field spectral amplitudes tend to show an inversely linear frequency dependence over high frequencies for heavily non-uniform frictional faults.  相似文献   
73.
We determined the morphologies and dimensions of possible impact craters on the surface of Asteroid 25143 Itokawa from images taken by the Hayabusa spacecraft. Circular depressions, circular features with flat floors or convex floors, and circular features with smooth surfaces were identified as possible craters. The survey identified 38 candidates with widely varying morphologies including rough, smooth and saddle-shaped floors, a lack of raised rims and fresh material exposures. The average depth/diameter ratio was 0.08±0.03: these craters are very shallow relative to craters observed on other asteroids. These shallow craters are a result of (1) target curvature influencing the cratering process, (2) raised rim not being generated by this process, and (3) fines infilling the craters. As many of the crater candidates have an unusual appearance, we used a classification scheme that reflects the likelihood of an observed candidate's formation by a hypervelocity impact. We considered a variety of alternative interpretations while developing this scheme, including inherited features from a proto-Itokawa, spall scars created by the disruption of the proto-Itokawa, spall scars following the formation of a large crater on Itokawa itself, and apparent depressions due to random arrangements of boulders. The size-frequency distribution of the crater candidates was close to the empirical saturation line at the largest diameter, and then decline with decreasing diameter.  相似文献   
74.
We investigated the structure of uranyl sorption complexes on gibbsite (pH 5.6-9.7) by two independent methods, density functional theory (DFT) calculations and extended X-ray absorption fine structure (EXAFS) spectroscopy at the U-LIII edge. To model the gibbsite surface with DFT, we tested two Al (hydr)oxide clusters, a dimer and a hexamer. Based on polarization, structure, and relaxation energies during geometry optimization, the hexamer cluster was found to be the more appropriate model. An additional advantage of the hexamer model is that it represents both edges and basal faces of gibbsite. The DFT calculations of (monomeric) uranyl sorption complexes show an energetic preference for the corner-sharing versus the edge-sharing configuration on gibbsite edges. The energy difference is so small, however, that possibly both surface species may coexist. In contrast to the edge sites, sorption to basal sites was energetically not favorable. EXAFS spectroscopy revealed in all investigated samples the same interatomic distances of the uranyl coordination environment (RU-Oax ≈ 1.80 Å, RU-Oeq ≈ 2.40 Å), and towards the gibbsite surface (RU-O ≈ 2.87 Å, RU-Al ≈ 3.38 Å). In addition, two U-U distances were observed, 3.92 Å at pH 9.7 and 4.30 Å at pH 5.6, both with coordination numbers of ∼1. The short U-U distance is close to that of the aqueous uranyl hydroxo dimer, UO2(OH)2, reported as 3.875 Å in the literature, but significantly longer than that of aqueous trimers (3.81-3.82 Å), suggesting sorption of uranyl dimers at alkaline pH. The longer U-U distance (4.30 Å) at acidic pH, however, is not in line with known aqueous uranyl polymer complexes. Based on the EXAFS findings we further refined dimeric surface complexes with DFT. We propose two structural models: in the acidic region, the observed long U-U distance can be explained with a distortion of the uranyl dimer to form both a corner-sharing and an edge-sharing linkage to neighboring Al octahedra, leading to RU-U = 4.150 Å. In the alkaline region, a corner-sharing uranyl dimer complex is the most favorable. The U-O path at ∼2.87 Å in the EXAFS spectra arises from the oxygen atom linking two Al cations in corner-sharing arrangement. The adsorption structures obtained by DFT calculations are in good agreement with the structural parameters from EXAFS analysis: U-Al (3.394 Å), U-U (3.949 Å), and U-O (2.823 Å) for the alkaline pH model, and U-Al (3.279 Å), U-U (4.150 Å), and U-O (2.743 Å) for the acidic pH model. This work shows that by combining EXAFS and DFT, consistent structural models for uranyl sorption complexes can be obtained, which are relevant to predict the migration behavior of uranium at nuclear facilities.  相似文献   
75.
Japanese Venus Climate Orbiter, Akatsuki, is cruising to approach to Venus again although its first Venus orbital insertion (VOI) has been failed. At present, we focus on the next opportunity of VOI and the following scientific observations.We have constructed an automated cloud tracking system for processing data obtained by Akatsuki in the present study. In this system, correction of the pointing of the satellite is essentially important for improving accuracy of the cloud motion vectors derived using the cloud tracking. Attitude errors of the satellite are reduced by fitting an ellipse to limb of an imaged Venus disk. Next, longitude–latitude distributions of brightness (cloud patterns) are calculated to make it easy to derive the cloud motion vectors. The grid points are distributed at regular intervals in the longitude–latitude coordinate. After applying the solar zenith correction and a highpass filter to the derived longitude–latitude distributions of brightness, the cloud features are tracked using pairs of images. As a result, we obtain cloud motion vectors on longitude–latitude grid points equally spaced. These entire processes are pipelined and automated, and are applied to all data obtained by combinations of cameras and filters onboard Akatsuki. It is shown by several tests that the cloud motion vectors are determined with a sufficient accuracy. We expect that longitude–latitude data sets created by the automated cloud tracking system will contribute to the Venus meteorology.  相似文献   
76.
Tertiary volcanic rocks in northwestern Firoozeh, Iran (the Meshkan triangular structural unit), constitute vast outcrops (up to 250 km2) of high-Mg basaltic andesites to dacites that are associated with high-Nb hawaiites and mugearites. Whole-rock 40Ar/39Ar ages show a restricted range of 24.1 ± 0.4–22.9 ± 0.5 Ma for the volcanic rocks. The initial ratios of 87Sr/86Sr and 143Nd/144Nd vary from 0.703800 to 0.704256 and 0.512681 to 0.512877, respectively, in the high-Mg basaltic andesites–dacites. High-Th contents (up to 11 ppm) and Sr/Y values (27–100) and the isotopic composition of the subalkaline high-Mg basaltic andesites–dacites indicate derivation from a mantle modified by slab and sediment partial melts. Evidence such as reverse zoning and resorbed textures and high Ni and Cr contents in the evolved samples indicate that magma mixing with mafic melts and concurrent fractional crystallization lead to the compositional evolution of this series. The high-Nb hawaiites and mugearites, by contrast, have a sodic alkaline affinity and are silica undersaturated; they are also enriched in Nb (up to 47 ppm) and a wide range of incompatible trace elements, including LILE, LREE, and HFSE. Geochemistry and Sr–Nd isotopic compositions of the high-Nb hawaiites and mugearites suggest derivation from a mantle source affected by lower degrees of slab melts. Post-orogenic slab break-off is suggested to have prompted the asthenospheric upwelling that triggered partial melting in mantle metasomatized by slab-derived melts.  相似文献   
77.

The temperature distribution at depth is a key variable when assessing the potential of a supercritical geothermal resource as well as a conventional geothermal resource. Data-driven estimation by a machine-learning approach is a promising way to estimate temperature distributions at depth in geothermal fields. In this study, we developed two methodologies—one based on Bayesian estimation and the other on neural networks—to estimate temperature distributions in geothermal fields. These methodologies can be used to supplement existing temperature logs, by estimating temperature distributions in unexplored regions of the subsurface, based on electrical resistivity data, observed geological/mineralogical boundaries, and microseismic observations. We evaluated the accuracy and characteristics of these methodologies using a numerical model of the Kakkonda geothermal field, Japan, where a temperature above 500 °C was observed below a depth of about 3.7 km. When using geological and geophysical knowledge as prior information for the machine learning methods, the results demonstrate that the approaches can provide subsurface temperature estimates that are consistent with the temperature distribution given by the numerical model. Using a numerical model as a benchmark helps to understand the characteristics of the machine learning approaches and may help to identify ways of improving these methods.

  相似文献   
78.
This article shows the potential impact on global GHG emissions in 2030, if all countries were to implement sectoral climate policies similar to successful examples already implemented elsewhere. This assessment was represented in the IMAGE and GLOBIOM/G4M models by replicating the impact of successful national policies at the sector level in all world regions. The first step was to select successful policies in nine policy areas. In the second step, the impact on the energy and land-use systems or GHG emissions was identified and translated into model parameters, assuming that it would be possible to translate the impacts of the policies to other countries. As a result, projected annual GHG emission levels would be about 50 GtCO2e by 2030 (2% above 2010 levels), compared to the 60 GtCO2e in the ‘current policies’ scenario. Most reductions are achieved in the electricity sector through expanding renewable energy, followed by the reduction of fluorinated gases, reducing venting and flaring in oil and gas production, and improving industry efficiency. Materializing the calculated mitigation potential might not be as straightforward given different country priorities, policy preferences and circumstances.

Key policy insights

  • Considerable emissions reductions globally would be possible, if a selection of successful policies were replicated and implemented in all countries worldwide.

  • This would significantly reduce, but not close, the emissions gap with a 2°C pathway.

  • From the selection of successful policies evaluated in this study, those implemented in the sector ‘electricity supply’ have the highest impact on global emissions compared to the ‘current policies’ scenario.

  • Replicating the impact of these policies worldwide could lead to emission and energy trends in the renewable electricity, passenger transport, industry (including fluorinated gases) and buildings sector, that are close to those in a 2°C scenario.

  • Using successful policies and translating these to policy impact per sector is a more reality-based alternative to most mitigation pathways, which need to make theoretical assumptions on policy cost-effectiveness.

  相似文献   
79.
A new, automatic hydrothermal fluid sampler using a shape-memory alloy   总被引:2,自引:0,他引:2  
A new hydrothermal fluid sampler has been developed to provide more maneuverability in underwater operation. The sampler characteristically employs a shape-memory alloy, which senses high temperature and actuates the suction mechanism. A shape-memory alloy is also used to switch the intake valve of the sampler, the intention being to avoid missampling when the inlet is in low temperature water. Prototype samplers were designed to collect the fluids hotter than 80°C. Test sampling was performed at hydrothermal vents (1372–1374 m deep) in the submarine volcano, Suiyo Seamount, Izu-Bonin Arc, northwestern Pacific. Observed fluid temperature was between 138 and 298°C, while the ambient seawater temperature was 3.1°C. Each prototype collected about 100 ml fluid as designed. The magnesium concentration in the samples indicated a seawater content of 47.5–90.8%, which indicates the entrainment of ambient seawater. Microscopic observatinn revealed the occurrence of microorganisms in the sample fluids at a population density of 105 to 106 cells ml−1, which is 2–3 orders of magnitude higher than those in seawater at that depth. The use of the newly developed fluid sampler will greatly facilitate the collection of vent-associated microorganisms, which are of potential biological and biotechnological interest.  相似文献   
80.
In order to examine the applicability of remotely-sensed ocean color for the estimation of phytoplankton biomass and primary production in the Oyashio region, the western subarctic Pacific, vertical distributions of chlorophylla concentration and primary production were observed in April and May 1997. Spring bloom was observed in both April and May, and the surface concentration of chlorophylla exceeded 40 mg m−3. The relationship between the standing stocks of chlorophylla within the layer from the sea surface to one optical depth (0–1/k layer) and the surface chlorophylla concentration is expressed as a Michaelis-Menten equation. The mean ratio of the standing stock of chlorophylla in the euphotic layer to that in the 0–1/k layer was 4.41, this ratio did not significantly differ from 4.61 which was obtained at homogeneous distribution of chlorophylla within the euphotic layer. These facts suggest that the distribution of chlorophylla could be assumed to be homogeneous in the euphotic layer during the spring bloom. Results of primary production measurements by simulatedin situ method were compared with those by an algorithm with two variables; chlorphylla and non-spectral PAR. Daily primary production in the euphotic layer estimated by the algorithm varied in a range of 38–274% of that estimated by incubation, although the primary productions by the algorithm agreed with those by the incubation at a half of stations. Primary production within the euphotic layer calculated using simply the surface data was the same as that estimated using vertical distribution of chlorophylla. These results show that the primary production in the euphotic layer may be estimated from the remote sensed measurements during the spring bloom in the Oyashio region.  相似文献   
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