Geochemical behavior of rare earth elements in hydrothermally altered rocks of the Kuroko mining area,Japan     

N. Shikazono  Y. Ogawa  M. Utada  D. Ishiyama  T. Mizuta  N. Ishikawa  Y. Kubota 《Journal of Geochemical Exploration》2008

In this study we analyzed the chemical composition of hydrothermally altered dacite and basalt from the Kuroko mining area, northeastern Honshu, Japan, by REE (rare earth element). Features of rare earth element analyses include: (1) altered footwall dacite exhibits a negative Eu anomaly compared with fresh dacite, suggesting preferential removal of Eu²⁺ from the altered dacite via hydrothermal solutions, (2) altered hangingwall dacite and basalt and dacite and basalt adjacent to ore deposits exhibit positive Eu anomalies compared with fresh dacite and basalt, suggesting addition of Eu²⁺ from hydrothermal solutions, (3) LREE ratio (∑LREE/∑REE) from altered dacite of chlorite–sericite zone and K-feldspar zone show a negative relationship with δ¹⁸O, and La/Sm ratios show a positive correlation with the K₂O index. These trends indicate the addition of light rare earth elements such as La to the altered dacite from hydrothermal solution and/or leaching of heavy rare earth elements such as Sm and Yb, (4) Principal component analysis (PCA) indicates that light rare earth elements enrichment is related to the formation of sericite zone near the Kuroko deposits but not to the formations of chlorite and K-feldspar zones, and (5) The correlations among REE features (LREE ratio, MREE ratio, HREE ratio, Eu/Eu?), δ¹⁸O and K₂O index are not found for montmorillonite zone, mixed layer clay mineral zone and mordenite zone. Therefore, it is inferred that sericite, chlorite and K-feldspar alterations are related to the Kuroko and vein-type mineralization, but montmorillonite and mordenite alterations are not related to the mineralizations, and probably they formed at the post-mineralization stage.  相似文献   

Seasonal variation in the upper layer thickness of the tropical Pacific ocean model     

Masahisa Kubota  James J. O'Brien 《Journal of Oceanography》1992,48(1):59-76

Seasonal variation in the tropical Pacific is studied by use of climatological monthly mean data of upper layer thickness of a linear reduced-gravity model with realistic basin geometry. Complex empirical orthogonal function (CEOF) analysis is applied to the data on a closed circuit which consists of the equator, eastern boundary, 7° latitude, and western boundary. The first and second CEOF represent the annual and semiannual variations, respectively. At the equator, absolute maximum anomalies associated with the first CEOF can be found near 160°W in spring and fall. Westward propagation of the annual variation is remarkable west of 130°W. However, similar westward propagation cannot be detected in either the eastern or western part of the equator. Maximum anomalies at 7° and the equator can be found in similar longitude and time. These maxima at both latitudes originate from the annual variation of Ekman pumping associated with the meridional movement of wind fields. We also decomposed the model results into Kelvin and Rossby modes. The Kelvin mode is characterized by seminnual variation, while first and third-mode Rossby waves have annual variations. In the present results, first and third-mode Rossby waves do not appear to be a trigger for Kelvin waves.  相似文献   

Sensitivity of CFCs and Anthropogenic CO2 Uptake in a North Pacific GCM to Mixing Parameterization and Surface Forcing     

Akio Ishida  Kisaburo Nakata  Shigeaki Aoki  Hiroshi Kutsukake  Michio J. Kishi  Masahisa Kubota 《Journal of Oceanography》2001,57(4):433-450

Distributions and characteristics of water mass and chlorofluorocarbons (CFCs) in the North Pacific are investigated by using a General Circulation Model (GCM). The anthropogenic CO₂ uptake by the ocean is estimated with velocity fields derived from the GCM experiments. The sensitivity of the uptake to different diffusion parameterizations and different surface forcing used in the GCM is investigated by conducting the three GCM experiments; the diffusive processes are parameterized by horizontal and vertical eddy diffusion which is used in many previous models (RUN1), parameterized by isopycnal diffusion (RUN2), and isopycnal diffusion and perpetual winter forcing for surface temperature and salinity (RUN3). Realistic features for water masses and CFCs can be simulated by the isopycnal diffusion models. The horizontal and vertical diffusion model fails to simulate the salinity minimum and realistic penetration of CFCs into the ocean. The depth of the salinity minimum layer is better simulated under the winter forcing. The results suggest that both isopycnal parameterization and winter forcing are crucial for the model water masses and CFCs simulations. The oceanic uptake of anthropogenic CO₂ in RUN3 is about 19.8 GtC in 1990, which is larger by about 10% than that in RUN1 with horizontal and vertical diffusive parameterization. RUN3 well simulates the realistic water mass structure of the intermediate layer considered as a candidate of oceanic sink for anthropogenic CO₂. The results suggest that the previous models with horizontal and vertical diffusive parameterization may give the oceanic uptake of anthropogenic CO₂ underestimated. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Effects of clear-cutting,meteorological, and physiological factors on evapotranspiration in the Kamabuchi experimental watershed in northern Japan     

Tayoko Kubota  Akira Kagawa  Toshio Abe  Ikuhiro Hosoda 《水文研究》2021,35(4):e14111

This study investigated the effects of clear-cutting and the meteorological and physiological factors on forest evapotranspiration (ET), by using the water-budget method in the Kamabuchi experimental watershed (KMB; 38° 56′ 21″ N, 140° 15′ 58″ E) in northern Japan. Meteorological and discharge data collected during no-snow periods (from June to October) from 1939 were used to compare ET in three sub-watersheds: No. 1, where the forest had been left undisturbed, and No. 2 and No. 3, where Cryptomeria japonica was planted after clear-cutting. Paired watershed experiments revealed that clear-cutting caused ET to decrease by approximately 100 mm yr⁻¹, and this reduction continued for more than 20 years, even after C. japonica was planted. ET fluctuated similarly across all watersheds, regardless of clear-cutting or planting. This fluctuation is mainly caused by solar radiation and temperature. Intrinsic water-use efficiency (iWUE) calculated using δ¹³C of tree-ring cellulose in C. japonica increased due to elevated atmospheric CO₂ concentration. We estimated annual carbon fixation in a single tree as the annual net photosynthesis (A). Subsequently, transpiration (E) was calculated from the relationship between iWUE and A. The results showed that A and E per tree increased as the tree grew older; however, the trees' responses to increasing c_a suppress the increase in ET. Moreover, the fluctuation of ET from the watershed was small compared to the fluctuation of P during the observation periods because the increase and decrease in E and interception loss complemented each other.  相似文献   

Radiometrically determined skin temperature and scalar roughness to estimate surface heat flux. Part I: Parameterization of radiometric scalar roughness     

Akihiro Kubota  Michiaki Sugita 《Boundary-Layer Meteorology》1994,69(4):397-416

A series of experiments carried out in a pasture field during a growing season, allowed a radiometric determination of the scalar roughness for sensible heatz _oh,r . The values ofz _oh,r are shown to vary over the range of 10^–1–10^–7m both diurnally and seasonally, and an existing theoretical model for the estimation of scalar roughness for sensible heat is found to be inappropriate for the precise estimation ofz _oh,r . To parameterizez _oh,r better, a multiple regression analysis was performed, with predictor candidates such as solar elevation, solar radiationR _s , leaf area index LAI, canopy height, the ratio of the solar radiation and the extraterrestrial radiationR _s /R _e , the ratio of the direct and the total solar radiationR _d /R _s , and the roughness Reynolds number among others. The best regression equation which usesR _s , LAI,R _s /R _e , andR _d /R _s is derived withr=0.75; with smaller numbers of predictors, values ofr tend to deteriorate gradually down tor=0.52 when only one predictor, LAI, was incorporated into the equation.  相似文献   

Evidence for magma in the Katmai volcanic range     

S. Kubota  E. Berg 《Bulletin of Volcanology》1967,31(1):175-214

Several independent observations during the summer of 1965 suggest the presence of magma in the volcanic range of Katmai. A high value of 0.3 for Poisson’s ratio and the screening of predominantly the vertical component of the elastic shear waves have been observed. Narrow negative Bouguer anomalies possibly indicate the presence of low density material at shallow depth. The location of magma reservoirs has been attempted, using the calculated wave path and the screening of the mainly vertically polarized shear wave. Of the possible ten chambers thus located, the ones of shallow depth (to 20 km) correspond to the location of active volcanoes. The ones between the 20 km level to the upper mantle seem to spread over a rather wide area and are not clearly related to the geographical position of a particular volcano. Theoretical considerations on the propagation of elastic waves substantiate the observed absence of vertically polarized shear waves.  相似文献   

About This Issue: Kuroko Deposits Revisited after the Discovery of Their Modern Analogues on Submarine Arc Volcanoes     

Tetsuro Urabe  Hiroshi Kubota 《Resource Geology》2004,54(4):385-386

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Trace Fossils and Sulfur Isotopes in Mudstones around the Kuroko Deposits in the Hokuroku Basin, Northeast Japan: An Attempt to Delineate the Depositional Environment     

Kosei Komuro    Hiroshi Kubota  Tokiyuki Sato    Yoshimichi Kajiwara  Shojiro Tanimura 《Resource Geology》2004,54(4):425-436

Abstract. A comprehensive investigation was carried out on the distribution of both trace fossils and sulfur isotopes in mud-stones in the Hokuroku district, northeast Japan, in the hope of delineating the depositional environment of the mudstones in which the Kuroko deposits are embedded. The mudstones are generally massive in structure and usually contain large trace fossils, being indicative of an aerobic biofacies. On the other hand, some mudstones in and above the Kuroko ore horizon are partly laminated and usually contain smaller trace fossils, being assignable to an anaerobic or dysaerobic biofacies. The δ³⁴S values of sulfides in the mudstones above and below the ore horizon range from -40 to -12 %o, indicating mostly oxic depositional conditions in equilibrium with the inferred aerobic biofacies. In the mudstones in the ore horizon, the δ³⁴S values exhibit regionally discriminated variations: -44 to -12 %o in areas far (>1 km) from the known Kuroko deposits and -24 to +6 %o in areas closer to them. The latter high δ³⁴S group implies the temporal occurrence of local anoxic basins in the vicinity of the known Kuroko deposits. At the time of late Nishikurosawa Stage (i.e. the currently assumed Kuroko metallogenic epoch), an intense oceanic stagnation is suggested to have taken place to form the local anoxic basins responsible for the formation and preservation of Kuroko deposits. This oceanic environmental event is considered to be most likely due to increasing biological productivity primarily triggered and enhanced by upwelling of NADW in the paleo-Sea of Japan at that time.  相似文献   

Radiometrically determined skin temperature and scalar roughness to estimate surface heat flux part II: Performance of parameterized scalar roughness for the determination of sensible heat     

Michiaki Sugita  Akihiro Kubota 《Boundary-Layer Meteorology》1994,70(1-2):1-12

Several formulations and proposals to determine the value of the radiometric scalar roughness for sensible heatz _0h,r are tested with respect to their performance in the estimation of the sensible heat flux by means of the profile equations derived from Monin-Obukhov similarity theory. The equations are applied to the data set of spatially averaged surface skin temperature and profiles of wind speed and temperature observed in a pasture field during a growing season. The use of a physical model developed for a dense canopy to estimate scalar roughness for sensible heatz _0h,r produced sensible heat fluxH with a correlation coefficientr=0.884, the ratio of means being H _s /H=1.19 in a comparison with reference values ofH _s . In comparison, a proposal for a fixed value ofz _0h yieldedr=0.887, H _s /H=0.879. In both cases, the validity ofz _0h =z _0h,r was assumed. All expressions derived to estimatez _0h,r from a multiple linear regression with such predictors as leaf area index, solar radiation and the ratio of solar radiation to extraterrestrial radiation, were found to produce a better result, withr better than 0.90 and H _s /H around 1.0. However, when the constantsc andf of a linear regression equationHs=cH+f are used to evaluate the equations, a marked difference in performance of each formulation appeared. In general, equations with smaller numbers of predictors tend to produce a biased result, i.e., an overestimation ofH at largeH _s . These values ofH are used in conjunction with the energy balance equation to derive values of the latent heat fluxLE, which are shown to be in good agreement with the reference valuesLE _s , withr greater than 0.97.  相似文献   

Development of a Neural Network Algorithm for Retrieving Concentrations of Chlorophyll, Suspended Matter and Yellow Substance from Radiance Data of the Ocean Color and Temperature Scanner   总被引：1，自引：4，他引：1  

Akihiko Tanaka  Motoaki Kishino  Roland Doerffer  Helmut Schiller  Tomohiko Oishi  Tadashi Kubota 《Journal of Oceanography》2004,60(3):519-530

An algorithm is presented to retrieve the concentrations of chlorophyll a, suspended pariclulate matter and yellow substance from normalized water-leaving radiances of the Ocean Color and Temperature Sensor (OCTS) of the Advanced Earth Observing Satellite (ADEOS). It is based on a neural network (NN) algorithm, which is used for the rapid inversion of a radiative transfer procedure with the goal of retrieving not only the concentrations of chlorophyll a but also the two other components that determine the water-leaving radiance spectrum. The NN algorithm was tested using the NASA's SeaBAM (SeaWiFS Bio-Optical Mini-Workshop) test data set and applied to ADEOS/OCTS data of the Northwest Pacific in the region off Sanriku, Japan. The root-mean-square error between chlorophyll a concentrations derived from the SeaBAM reflectance data and the chlorophyll a measurements is 0.62. The retrieved chlorophyll a concentrations of the OCTS data were compared with the corresponding distribution obtained by the standard OCTS algorithm. The concentrations and distribution patterns from both algorithms match for open ocean areas. Since there are no standard OCTS products available for yellow substance and suspended matter and no in situ measurements available for validation, the result of the retrieval by the NN for these two variables could only be assessed by a general knowledge of their concentrations and distribution patterns. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献