Contamination by organochlorine compounds in sturgeons from Caspian Sea during 2001 and 2002   总被引：2，自引：0，他引：2  

Kajiwara N  Ueno D  Monirith I  Tanabe S  Pourkazemi M  Aubrey DG 《Marine pollution bulletin》2003,46(6):741-747

Organochlorine compounds (OCs) were determined in the five species of sturgeons collected from coastal waters of Caspian Sea in Kazakhstan, Azerbaijan, Turkmenistan and Iran during 2001 and 2002 to understand their status of contamination and accumulation features. Among OCs examined, concentrations of DDTs (DDT and its metabolites) were predominant in all the sturgeon samples with concentrations ranging from 73 to 31,000 ng/g on lipid weight basis, followed by PCBs, CHLs, HCHs, HCB, dieldrin, TCPMOH, and heptachlor epoxide in order. The concentrations of OCs in beluga (Huso huso) were the highest among all the five species. When comparing residue levels among same species, OC residues were highest in sturgeons from Azerbaijan and Kazakhstan and lowest in Turkmenistan. However, the concentrations of HCHs, dieldrin, and heptachlor epoxide in sturgeons showed less geographical variability.  相似文献   

Specific accumulation of persistent organochlorines in bluefin tuna collected from Japanese coastal waters     

Ueno D  Iwata H  Tanabe S  Ikeda K  Koyama J  Yamada H 《Marine pollution bulletin》2002,45(1-12):254-261

Concentrations of persistent organochlorines (OCs) such as PCBs, DDTs, chlordanes (CHLs), HCHs and HCB were determined in the liver of bluefin tuna (Thunnus thynnus) collected from Japanese coastal waters in order to elucidate accumulation profiles and to evaluate the suitability of this species as a biomonitor for pollution in the open sea ecosystem. Concentrations of PCBs, DDTs and CHLs in bluefin tuna increased significantly with body length (30–190 cm). HCHs and HCB residues were comparable among all the sampling regions, and the levels of these chemicals did not show correlation with body length. These results suggest significance of dietary uptake of PCBs, DDTs and CHLs compared to the intake via the gill. On the other hand, equilibrium partitioning with ambient water is a major determinant of the levels of HCHs and HCB in tuna. Body-length normalized values (BLNV) of PCBs, DDTs and CHLs concentrations in bluefin tuna were calculated using the linear regression equation obtained from the plot of concentrations and body length. BLNV of these chemicals on a lipid wt basis, which was adjusted for 100 cm body length, were indicative of the present state water pollution by PCBs, DDTs and CHLs. These results suggest that bluefin tuna is a suitable bioindicator for monitoring OCs contamination in the open sea ecosystem.  相似文献   

Dynamical structure and wind-driven upwelling in a summertime anticyclonic eddy within Funka Bay,Hokkaido, Japan     

Daisuke Takahashi  Kazuo Kido  Yoshinori Nishida  Naoto Kobayashi  Naoyuki Higaki  Hideo Miyake 《Continental Shelf Research》2007

We conducted hydrographic observations in 2002 to investigate the anticyclonic eddy that emerges every summer in Funka Bay, Hokkaido, Japan, and elucidate dynamical structure and wind-driven upwelling within the eddy. The anticyclonic eddy has a vertical scale of 32 m and is characterized by a strong baroclinic flow and a sharp pycnocline with a concave isopycnal structure. The sharp pycnocline occurs below a warm and relatively low-salinity water termed summer Funka Bay water (FS), which is formed by heating from solar radiation and dilution from river discharge in summertime Funka Bay. Flow of the anticyclonic eddy rotates as a rigid body at each layer, and the horizontal scale and rotation period of the eddy in the surface layer are about 15 km and 2.2 days, respectively. The dynamical balance of the anticyclonic eddy is well explained by the gradient flow balance. The contribution of centrifugal force to the gradient flow balance is about 27%. Therefore, the effect of the nonlinear term associated with centrifugal force cannot be neglected in considering the dynamics of the anticyclonic eddy in summertime Funka Bay. In addition, upwelling of subsurface water was observed in the surface layer of the central part of the eddy. The formation mechanism of this upwelling is consistent with interaction between horizontal uniform wind and the eddy. This upwelling is driven by upward Ekman pumping velocity related to the horizontal divergence of Ekman transport. In summertime Funka Bay, there are two wind effects that affect the anticyclonic eddy: a decay effect of the upwelling of subsurface water resulting from horizontal uniform wind (mainly northwesterly wind), and a maintenance or spin-up effect of horizontal non-uniform wind (mainly southerly–southeasterly seasonal wind) with negative wind stress curl.  相似文献   

Comparison and interpretation of graphitization in contact and regional metamorphic rocks     

Daisuke  Nakamura 《Island Arc》1995,4(2):112-127

Abstract X-ray diffraction (XRD) analyses of carbonaceous materials were carried out in conjunction with petrological studies for selected metamorphic rocks in order to compare the structural state of carbonaceous materials between contact and regional metamorphic rocks. The most extensive study was done for the Daimonji contact aureole in the eastern part of Kyoto city, Japan. The Daimonji contact aureole can be divided into three mineral zones using mineral parageneses of pelitic rocks: chlorite, biotite and cordierite zones. The cordierite zone can be further subdivided into lower- and higher-grade subzones. Petrological considerations allow the two isograd reactions that define the lower- and higher-grade cordierite subzones to be determined and suggest these reactions occurred at 510–560°C and 560–590°C per 2.0-2.3 kbar, respectively. A combination of the petrological studies and the XRD data of carbonaceous materials suggest that fully ordered graphite (FG; defined by d(002) ≤ 3.360 Å following the convention used by many workers), appears around 560–590°C in the Daimonji contact aureole. This data and refinement of geothermometer for published data confirmed that the FG appears at 400–500°C in regional metamorphic rocks, but at higher than 530°C in contact aureoles. One possible explanation for such a temperature difference is the duration of heating. However, the width at half height (WH) of the graphite peak attains a similar value of 0.30° at around 500°C both in contact and regional metamorphic rocks, suggesting that WH value is a more reliable indicator of metamorphic grade than the change of d(002) value. Furthermore, the depressed d(002) data of graphite was observed locally in the higher grade part (≥ 500°C) of the Ryoke regional metamorphic belt, where granitic intrusions exist within a few km distance. These facts indicate that the duration of heating is not an important factor controlling the change of d(002) value. It is possible that interlayered impurities, such as chlorine, which was derived from igneous intrusions, may be an important factor in suppressing the reduction in d(002) at temperatures greater than 500°C.  相似文献   

Search for extinct Cl: Vigarano CAIs, the Pink Angel from Allende, and a Ningqiang chondrule     

Daisuke Nakashima  Ulrich Ott  Ahmed El Goresy 《Geochimica et cosmochimica acta》2008,72(24):6141-6153

We have searched for excesses of ³⁶S derived from the decay of extinct ³⁶Cl in sodalite, a secondary Cl-rich mineral, in Ca-Al-rich inclusions (CAIs) from the Vigarano and Allende CV3 chondrites and in a chondrule from the Ningqiang carbonaceous chondrite. The presence of sodalite in two CAIs from Vigarano and its absence from surrounding CAI fragments suggests sodalite formation after CAI fragmentation. As for sodalite in the Allende Pink Angel CAI, oxygen isotopic compositions have been interpreted as indicative of high temperature interactions, thus suggesting formation prior to accretion to the parent body, probably in a nebular setting. Sodalite in the Ningqiang chondrule is considered to have formed via alkali-Ca exchange, which is believed to have occurred before accretion to the parent body.Sodalites in the Vigarano CAIs and in the Ningqiang chondrule show no clear evidence for the presence of radiogenic ³⁶S. The inferred 2σ upper limits for ³⁶Cl/³⁵Cl at the time of sodalite formation are 1.6 × 10⁻⁶ (Vigarano CAIs) and 3.3 × 10⁻⁶ (Ningqiang chondrule), respectively. In the Pink Angel CAI sodalite exhibits small ³⁶S excesses which weakly correlate with ³⁵Cl/³⁴S ratios. The inferred ³⁶Cl/³⁵Cl ratio of (1.8 ± 2.2) × 10⁻⁶ (2σ error) is lower than that found by Hsu et al. [Hsu, W., Guan, Y., Leshin, L. A., Ushikubo, T. and Wasserburg, G. J. (2006) A late episode of irradiation in the early solar system: Evidence from extinct ³⁶Cl and ²⁶Al in meteorites. Astrophys. J. 640, 525-529], thus indicative of heterogeneous distribution of ³⁶Cl in this CAI. Spallation reactions induced by energetic particles from the young Sun are suggested for the origin of ³⁶Cl, similar to the case of ¹⁰Be. While ¹⁰Be appears to be present in roughly equal abundance in all studied CAIs, our study indicates the level of ³⁶Cl abundances to be variable so that there seems to be no simple relationship between ¹⁰Be and ³⁶Cl. This would be expected if trapped cosmic rays rather than Early Solar System spallation were the dominant source of ¹⁰Be in the Early Solar System, since their contribution to ³⁶Cl would have been tiny.If the variability of ³⁶Cl abundances is caused by temporal differences in the alteration that formed sodalite, sodalite in the Vigarano CAIs and in the Ningqiang chondrule may have formed ?0.5 and ?0.2 Ma after formation of the sodalite in the Ningqiang CAI analyzed by Lin et al. [Lin, Y., Guan, Y., Leshin, L. A., Ouyang, Z. and Wang, D. (2005) Short-lived chlorine-36 in a Ca- and Al-rich inclusion from the Ningqiang carbonaceous chondrite. Proc. Natl. Acad. Sci. USA 102, 1306-1311]. The Pink Angel sodalite that we analyzed may have formed ∼0.3 Ma after formation of the sodalite in the Pink Angel analyzed by Hsu et al. [Hsu, W., Guan, Y., Leshin, L. A., Ushikubo, T. and Wasserburg G. J. (2006) A late episode of irradiation in the early solar system: Evidence from extinct ³⁶Cl and ²⁶Al in meteorites. Astrophys. J. 640, 525-529]. The estimated temporal differences suggest that alteration extended over at least 0.5 Ma. If previous works showing very low initial ³⁶Cl/³⁵Cl in the Allende CAIs and a H3 chondrite CAI are also considered, then alteration processes may have been more than 1.7 Ma.  相似文献   

Fate of carbonates within oceanic plates subducted to the lower mantle, and a possible mechanism of diamond formation     

Yusuke Seto  Daisuke Hamane  Takaya Nagai  Kiyoshi Fujino 《Physics and Chemistry of Minerals》2008,35(4):223-229

We report on high-pressure and high-temperature experiments involving carbonates and silicates at 30–80 GPa and 1,600–3,200 K, corresponding to depths within the Earth of approximately 800–2,200 km. The experiments are intended to represent the decomposition process of carbonates contained within oceanic plates subducted into the lower mantle. In basaltic composition, CaCO₃ (calcite and aragonite), the major carbonate phase in marine sediments, is altered into MgCO₃ (magnesite) via reactions with Mg-bearing silicates under conditions that are 200–300°C colder than the mantle geotherm. With increasing temperature and pressure, the magnesite decomposes into an assemblage of CO₂ + perovskite via reactions with SiO₂. Magnesite is not the only host phase for subducted carbon—solid CO₂ also carries carbon in the lower mantle. Furthermore, CO₂ itself breaks down to diamond and oxygen under geotherm conditions over 70 GPa, which might imply a possible mechanism for diamond formation in the lower mantle.  相似文献   

Interannual-decadal variability of wintertime mixed layer depths in the North Pacific detected by an ensemble of ocean syntheses     

Toyoda  Takahiro  Fujii  Yosuke  Kuragano  Tsurane  Kosugi  Naohiro  Sasano  Daisuke  Kamachi  Masafumi  Ishikawa  Yoichi  Masuda  Shuhei  Sato  Kanako  Awaji  Toshiyuki  Hernandez  Fabrice  Ferry  Nicolas  Guinehut  Stéphanie  Martin  Matthew  Andrew Peterson  K.  Good  Simon A.  Valdivieso  Maria  Haines  Keith  Storto  Andrea  Masina  Simona  Köhl  Armin  Yin  Yonghong  Shi  Li  Alves  Oscar  Smith  Gregory  Chang  You-Soon  Vernieres  Guillaume  Wang  Xiaochun  Forget  Gael  Heimbach  Patrick  Wang  Ou  Fukumori  Ichiro  Lee  Tong  Zuo  Hao  Balmaseda  Magdalena 《Climate Dynamics》2017,49(3):891-907

Climate Dynamics - The interannual-decadal variability of the wintertime mixed layer depths (MLDs) over the North Pacific is investigated from an empirical orthogonal function (EOF) analysis of an...  相似文献   

Oscillatory orbits in the planar three‐body problem with equal masses     

Kiyotaka Tanikawa  Hiroaki Umehara 《Celestial Mechanics and Dynamical Astronomy》1998,70(3):167-180

In the free‐fall three‐body problem, distributions of escape, binary, and triple collision orbits are obtained. Interpretation of the results leads us to the existence of oscillatory orbits in the planar three‐body problem with equal masses. A scenario to prove their existence is described. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Narratives in REDD+ benefit sharing: examining evidence within and beyond the forest sector     

Grace Yee Wong  Cecilia Luttrell  Lasse Loft  Anastasia Yang  Thuy Thu Pham  Daisuke Naito 《Climate Policy》2019,19(8):1038-1051

REDD+ was designed globally as a results-based instrument to incentivize emissions reduction from deforestation and forest degradation. Over 50 countries have developed strategies for REDD+, implemented pilot activities and/or set up forest monitoring and reporting structures, safeguard systems and benefit sharing mechanisms (BSMs), offering lessons on how particular ideas guide policy design. The implementation of REDD+ at national, sub-national and local levels required payments to filter through multiple governance structures and priorities. REDD+ was variously interpreted by different actors in different contexts to create legitimacy for certain policy agendas. Using an adapted 3E (effectiveness, efficiency, equity and legitimacy) lens, we examine four common narratives underlying REDD+ BSMs: (1) that results-based payment (RBP) is an effective and transparent approach to reducing deforestation and forest degradation; (2) that emphasis on co-benefits risks diluting carbon outcomes; (3) that directing REDD+ benefits predominantly to poor smallholders, forest communities and marginalized groups helps address equity; and (4) that social equity and gender concerns can be addressed by well-designed safeguards. This paper presents a structured examination of eleven BSMs from within and beyond the forest sector and analyses the evidence to variably support and challenge these narratives and their underlying assumptions to provide lessons for REDD+ BSM design. Our findings suggest that contextualizing the design of BSMs, and a reflexive approach to examining the underlying narratives justifying particular design features, is critical for achieving effectiveness, equity and legitimacy.

Key policy insights

• A results-based payment approach does not guarantee an effective REDD+; the contexts in which results are defined and agreed, along with conditions enabling social and political acceptance, are critical.

• A flexible and reflexive approach to designing a benefit-sharing mechanism that delivers emissions reductions at the same time as co-benefits can increase perceptions of equity and participation.

• Targeting REDD+ to smallholder communities is not by default equitable, if wider rights and responsibilities are not taken into account

• Safeguards cannot protect communities or society without addressing underlying power and gendered relations.

• The narratives and their underlying generic assumptions, if not critically examined, can lead to repeated failure of REDD+ policies and practices.

  相似文献   

Compositional variations,chemical weathering,and provenance of sands from the Cox’s Bazar and Kuakata beach areas,Bangladesh     

H. M. Zakir Hossain  Quazi Hasna Hossain  Atsushi Kamei  Daisuke Araoka 《Arabian Journal of Geosciences》2018,11(23):749

The modal and chemical composition of sands from Cox’s Bazar beach (CBB) and Kuakata beach (KB) areas of Bangladesh has been investigated to infer their maturity, chemical weathering, and provenance signatures. The CBB and KB sands are typically high quartz, low feldspar, and lithic fragments, representing a recycled orogen source. Major element compositions of CBB sands are characterized by high SiO₂ (83.52–89.84 wt%) and low Al₂O₃ (4.39–6.39 wt%), whereas KB sands contained relatively low SiO₂ (63.28–79.14 wt%) and high Al₂O₃ (9.00–11.33 wt%) contents. The major, trace and rare earth element (REE) compositions of beach sands display comparable distribution patterns with enriched Th and SiO₂ for both sands relative to upper continental crust (UCC). Pb, Rb, Y, and Fe for KB sands are little higher than UCC and the rest of the elements are marked depleted for both suites reflecting destruction of plagioclase and K-feldspar during fluvial transportation. The CBB and KB sands are compositionally low mature to immature in nature subsequently classified as subarkose and litharenite, respectively. Chondrite-normalized REE patterns for CBB and KB sands show LREE enrichment and nearly flat HREE (La_N/Yb_N, 7.64–9.38 and 5.48–8.82, respectively) coupled with prominent Eu anomalies (Eu/Eu*, 0.51–0.72 and 0.52–0.76, respectively), suggesting felsic source provenance. The provenance discrimination diagrams, immobile trace element ratios (Th/Sc, Zr/Sc, Ce/Sc, and Ti/Zr), and REE (∑LREE/HREE, Eu/Eu* and Gd_N/Yb_N) parameters indicate that CBB and KB sands were largely derived from felsic source rocks, with compositions close to average rhyolite, granodiorite, granite, and UCC.  相似文献