Characterization of serpentinization in olivine-orthopyroxene-H2O system revealed by thermogravimetric and multivariate statistical analyses     

Atsushi Okamoto  Shuhei Tanaka  Masaoki Uno  Otgonbayar Dandar  Kazuki Yoshida 《Island Arc》2024,33(1):e12519

Thermogravimetric (TG) analyses were used to characterize the products and quantify the extent of serpentinization as a stepwise weight loss during heating (TG loss) or its derivative (DTG). Multivariate analyses are powerful tools for extracting information from complicated spectrum data; however, no studies have applied them to characterize serpentinites. In this study, hydrothermal experiments of olivine-H₂O, olivine–orthopyroxene-H₂O and orthopyroxene-H₂O were conducted at 250–400°C and under vapor-saturated pressure. The product minerals observed were serpentine+brucite+magnetite in the olivine-H₂O experiments and serpentine±talc in the orthoyroxene-H₂O and olivine-orthopyroxene-H₂O experiments. These results are consistent with those of previous studies; however, the positions and width of DTG peaks for individual minerals were varied depending on the experimental conditions. To extract systematics from the TG spectra, non-negative matrix factorization (NMF), an unsupervised machine learning technique, was applied to the DTG spectra of the experimental products. NMF revealed that the DTG profiles were explained by a linear combination of six basis spectra, which corresponded to the characteristic products, including three types of serpentine minerals (low-, medium-, and high-T), two types of brucite (low-and high-T), two type of talc (talc+serpentine mixture, well-crystallized talc) with different crystallinity, and noise during the TG measurement. Systematic changes in the factor loading revealed that, in the olivine-H₂O systems, the products changed from medium-T serpentine+low-T brucite to high-T serpentine+high-T brucite as serpentinization progressed. In the olivine-orthopyroxene system, low-T serpentine or poorly crystallized talc+serpentine mixture was initially formed, followed by the formation of well-crystallized talc, resulting in dehydration. Applying NMF to DTG showed the mineralogical differences between olivine and orthopyroxene systems and increases of the crystallinity during the progress of serpentinization, suggesting its potential for characterizing various serpentinites within oceanic lithospheres that suffer from several stages of alteration and weathering at different temperatures.  相似文献   

Provenance diversification within an arc‐trench system induced by batholith development: the Cretaceous Japan case     

Kazumasa Aoki  Yukio Isozaki  Daisuke Kofukuda  Tomohiko Sato  Atsushi Yamamoto  Kenshi Maki  Shuhei Sakata  Takafumi Hirata 《地学学报》2014,26(2):139-149

By comparing detrital zircon U–Pb age spectra of coeval fore‐arc and back‐/intra‐arc basin sandstones, we identified the overall distributary pattern of terrigenous clastic material within the Cretaceous arc system of SW Japan. Abundant Proterozoic (c. 1500–2500 Ma) detrital grains from the interior of East Asia are present in the Cretaceous intra‐arc basin. However, after a barrier mountain range formed during batholith emplacement, Proterozoic clastics were rarely transported into the fore‐arc domain. Episodic batholith formation in Pacific‐type orogens likely played a major role in controlling terrigenous supply routes between coeval back‐arc and fore‐arc domains. The Cretaceous orogen in Japan thus provides a good template for analysing the tectono‐sedimentary development of other arc‐related basins.  相似文献   

Effect of electron donors on the fractionation of sulfur isotopes by a marine Desulfovibrio sp.     

Min Sub Sim  Shuhei Ono  Stefanie P. Templer 《Geochimica et cosmochimica acta》2011,75(15):4244-77

Sulfur isotope effects produced by microbial dissimilatory sulfate reduction are used to reconstruct the coupled cycling of carbon and sulfur through geologic time, to constrain the evolution of sulfur-based metabolisms, and to track the oxygenation of Earth’s surface. In this study, we investigate how the coupling of carbon and sulfur metabolisms in batch and continuous cultures of a recently isolated marine sulfate reducing bacterium DMSS-1, a Desulfovibrio sp., influences the fractionation of sulfur isotopes.DMSS-1 grown in batch culture on seven different electron donors (ethanol, glycerol, fructose, glucose, lactate, malate and pyruvate) fractionates ³⁴S/³²S ratio from 6‰ to 44‰, demonstrating that the fractionations by an actively growing culture of a single incomplete oxidizing sulfate reducing microbe can span almost the entire range of previously reported values in defined cultures. The magnitude of isotope effect correlates well with cell specific sulfate reduction rates (from 0.7 to 26.1 fmol/cell/day). DMSS-1 grown on lactate in continuous culture produces a larger isotope effect (21-37‰) than the lactate-grown batch culture (6‰), indicating that the isotope effect also depends on the supply rate of the electron donor and microbial growth rate. The largest isotope effect in continuous culture is accompanied by measurable changes in cell length and cellular yield that suggest starvation. The use of multiple sulfur isotopes in the model of metabolic fluxes of sulfur shows that the loss of sulfate from the cell and the intracellular reoxidation of reduced sulfur species contribute to the increase in isotope effects in a correlated manner. Isotope fractionations produced during sulfate reduction in the pure culture of DMSS-1 expand the previously reported range of triple sulfur isotope effects (³²S, ³³S, and ³⁴S) by marine sulfate reducing bacteria, implying that microbial sulfur disproportionation may have a smaller ³³S isotopic fingerprint than previously thought.  相似文献   

3D Structure of Arcade-Type Flares Derived from the Homologous Flare Series of 21, 24, and 27 February 1992     

Morita  Satoshi  Uchida  Yutaka  Hirose  Shigenobu  Uemura  Shuhei  Yamaguchi  Tomotaka 《Solar physics》2001,200(1-2):137-156

In February 1992, three flares, which we consider constitute a homologous flare series (flares having basically the same configuration repeating in the same situation), occurred in the active region NOAA 7070 and were observed by Yohkoh SXT. In the present paper, we first discuss the homology of these three flares, and derive the 3D structure by making use of the information obtained from the three different lines of sight at common phases. The result of this analysis made clear for the first time that the so-called `cusped arcade' at the maximum phase in the well-known 21 February 1992 flare is, contrary to the general belief, an `elongated arch' created at the beginning of the flare, seen with a shallow oblique angle. It is not the `flare arcade' seen on axis as widely conceived. This elongated arch roughly coincides with a diagonal of the main body of the soft X-ray arcade that came up later. The magnetic structure responsible for the flare as a whole turned out to be a structure with quadruple magnetic sources – with the third and fourth sources also playing essential roles. The observationally derived information in our paper provides strong restrictions to the theoretical models of the process occurring in arcade flares.  相似文献   

An acoustic positioning system using demodulated signals of an FM ultrasonic wave     

Mitome  H. Koda  T. Shibata  S. 《Oceanic Engineering, IEEE Journal of》1985,10(3):316-323

An acoustic positioning system using a continuous frequency-modulated (FM) ultrasonic wave transmitted from a sound source source located on the sea bottom is described in this paper. This system consists of a direction detecting system and a distance-change detecting system. The accuracy of the direction detection of the tested system was2degand the accuracy of the distance-change detection was within 0.10 m for a displacement of 50 m. Combining these two systems, it is possible to detect the change of position of the vessel sensitively. Since information from the phases of demodulated signals of the received FM ultrasonic wave is used exclusively, this system is excellent in signal-to-noise ratio (S/N) in spite of the simplicity of the electronic circuit. It was confirmed in experiments in the sea that both the direction detecting system and the distance-change detecting system worked well simultaneously, and that the combined systems would be suitable as an acoustic positioning system.  相似文献   

S-33 constraints on the seawater sulfate contribution in modern seafloor hydrothermal vent sulfides     

Shuhei Ono  Wayne C. Shanks III  Douglas Rumble 《Geochimica et cosmochimica acta》2007,71(5):1170-1182

Sulfide sulfur in mid-oceanic ridge hydrothermal vents is derived from leaching of basaltic-sulfide and seawater-derived sulfate that is reduced during high temperature water rock interaction. Conventional sulfur isotope studies, however, are inconclusive about the mass-balance between the two sources because ³⁴S/³²S ratios of vent fluid H₂S and chimney sulfide minerals may reflect not only the mixing ratio but also isotope exchange between sulfate and sulfide. Here, we show that high-precision analysis of S-33 can provide a unique constraint because isotope mixing and isotope exchange result in different Δ³³S (≡δ³³S-0.515 δ³⁴S) values of up to 0.04‰ even if δ³⁴S values are identical. Detection of such small Δ³³S differences is technically feasible by using the SF₆ dual-inlet mass-spectrometry protocol that has been improved to achieve a precision as good as 0.006‰ (2σ).Sulfide minerals (marcasite, pyrite, chalcopyrite, and sphalerite) and vent H₂S collected from four active seafloor hydrothermal vent sites, East Pacific Rise (EPR) 9-10°N, 13°N, and 21°S and Mid-Atlantic Ridge (MAR) 37°N yield Δ³³S values ranging from −0.002 to 0.033 and δ³⁴S from −0.5‰ to 5.3‰. The combined δ³⁴S and Δ³³S systematics reveal that 73 to 89% of vent sulfides are derived from leaching from basaltic sulfide and only 11 to 27% from seawater-derived sulfate. Pyrite from EPR 13°N and marcasite from MAR 37°N are in isotope disequilibrium not only in δ³⁴S but also in Δ³³S with respect to associated sphalerite and chalcopyrite, suggesting non-equilibrium sulfur isotope exchange between seawater sulfate and sulfide during pyrite precipitation. Seafloor hydrothermal vent sulfides are characterized by low Δ³³S values compared with biogenic sulfides, suggesting little or no contribution of sulfide from microbial sulfate reduction into hydrothermal sulfides at sediment-free mid-oceanic ridge systems. We conclude that ³³S is an effective new tracer for interplay among seawater, oceanic crust and microbes in subseafloor hydrothermal sulfur cycles.  相似文献   

Interannual-decadal variability of wintertime mixed layer depths in the North Pacific detected by an ensemble of ocean syntheses     

Toyoda  Takahiro  Fujii  Yosuke  Kuragano  Tsurane  Kosugi  Naohiro  Sasano  Daisuke  Kamachi  Masafumi  Ishikawa  Yoichi  Masuda  Shuhei  Sato  Kanako  Awaji  Toshiyuki  Hernandez  Fabrice  Ferry  Nicolas  Guinehut  Stéphanie  Martin  Matthew  Andrew Peterson  K.  Good  Simon A.  Valdivieso  Maria  Haines  Keith  Storto  Andrea  Masina  Simona  Köhl  Armin  Yin  Yonghong  Shi  Li  Alves  Oscar  Smith  Gregory  Chang  You-Soon  Vernieres  Guillaume  Wang  Xiaochun  Forget  Gael  Heimbach  Patrick  Wang  Ou  Fukumori  Ichiro  Lee  Tong  Zuo  Hao  Balmaseda  Magdalena 《Climate Dynamics》2017,49(3):891-907

Climate Dynamics - The interannual-decadal variability of the wintertime mixed layer depths (MLDs) over the North Pacific is investigated from an empirical orthogonal function (EOF) analysis of an...  相似文献   

Partial derivative of love numbers     

Shuhei Okubo  Masanori Saito 《Journal of Geodesy》1983,57(1-4):167-179

We present a simple formula for the partial derivatives of Love numbers with respect to density, bulk modulus and rigidity without urging the Adams-Williamson condition in the liquid core. Partials of the second degree Love numbers are computed for model 1066 A. Love numbers prove to be either completely or virtually independent of the elastic profile within the whole core. Delta-function-like changes occur in Love numbers when we perturb the density of the top and bottom layers of the outer core.  相似文献   

Surface potential and gravity changes due to internal dislocations in a spherical earth—I. Theory for a point dislocation     

Wenke Sun  Shuhei Okubo 《Geophysical Journal International》1993,114(3):569-592

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Gravity change observed in a local gravity network and its implication to seasonal precipitation in Dali county,Yunnan province,China          下载免费PDF全文

Xin Zhou  Wenke Sun  Hui Li  Shuhei Okubo  Shaoan Sun  Lelin Xing  Dongzhi Liu  Chongyang Shen 《地震科学（英文版）》2014,27(1):79-88

This study investigates data-processing methods and examines the precipitation effect on gravity measurements at the Dali gravity network, established in 2005. High-quality gravity data were collected during four measurement campaigns. To use the gravity data validly, some geophysical corrections must be considered carefully. We first discuss data-processing methods using weighted least-squares adjustment with the constraint of the absolute gravity datum. Results indicate that the gravity precision can be improved if all absolute gravity data are used as constraints and if calibration functions of relative gravimeters are modeled within the observation function. Using this data-processing scheme, the mean point gravity precision is better than 12 μgal. After determining the best data-processing scheme, we then process the gravity data obtained in the four measurement campaigns, and obtain gravity changes in three time periods. Results show that the gravity has a remarkable change of more than 50 μgal in the first time period from Apr–May of 2005 to Aug–Sept of 2007. To interpret the large gravity change, a mean water mass change (0.6 m in height) is assumed in the ETOPO1 topographic model. Calculations of the precipitation effect on gravity show that it can reach the same order of the observed gravity change. It is regarded as a main source of the remarkable gravity change in the Dali gravity network, suggesting that the precipitation effect on gravity measurements must be considered carefully.  相似文献