Oxygen isotopic and chemical compositions of cosmic spherules collected from the Antarctic ice sheet: Implications for their precursor materials     

Toru Yada  Tomoki Nakamura  Noriko Matsumoto  Hajime Hiyagon  Naoji Sugiura  Nobuo Takaoka 《Geochimica et cosmochimica acta》2005,69(24):5789-5804

Bulk chemical compositions and oxygen isotopic compositions were analyzed for 48 stony cosmic spherules (melted micrometeorites) collected from the Antarctic ice sheet using electron- and ion-microprobes. No clear correlation was found between their isotopic compositions and textures. The oxygen isotopic compositions showed an extremely wide range from −28‰ to +93‰ in δ¹⁸O and from −21‰ to +13‰ in Δ¹⁷O. In δ¹⁸O-δ¹⁷O space, most samples (38 out of 48) plot close to the terrestrial fractionation line, but 7 samples plot along the carbonaceous chondrite anhydrous mineral (CCAM) line. Three samples plot well above the terrestrial fractionation line. One of these has a Δ¹⁷O of +13‰, the largest value ever found in solar system materials. One possible precursor for this spherule could be ¹⁶O-poor planetary material that is still unknown as a meteorite. The majority of the remaining spherules are thought to be related to carbonaceous chondrites.  相似文献   

Improvement of short-term sea ice forecast in the southern Okhotsk Sea     

Ayumi Fujisaki  Hajime Yamaguchi  Fengjun Duan  Genki Sagawa 《Journal of Oceanography》2007,63(5):775-790

In this study, a numerical model of 7-day forecast of sea ice produced by the Japan Meteorological Agency was improved by the following approaches. First, a new ice dynamic model was introduced: the distributed mass/discrete floe model. The model takes account of discrete characteristics of ice floes and well simulates the ice edge location at low computational cost. Secondly, the grid size was reduced to 5 × 5 km for the future high resolution forecasts. Next, the sea surface current data was examined because it significantly influences sea ice movement. We applied two new datasets of HINO and Okhotsk Ocean General Circulation Model (Okhotsk OGCM), which are estimated by numerical simulations, for the 7-day forecast of sea ice. Ice southward speed in January and the whorl formations in February and March were well reproduced with Okhotsk OGCM datasets. Finally, the ocean heat flux at the ice-ocean interface was refined. As a result, we achieved an ice edge error reduction from 30.8 km to 23.5 km.  相似文献   

A new method of evaluating the mineralization of particulate and dissolved photoassimilated organic matter     

Masanobu Ishikawa  Hajime Nishimura 《Journal of Oceanography》1983,39(2):29-42

A new method of evaluating the rate of mineralization of photoassimilated organic matter is described. This method enables us to compare the rate of direct mineralization of particulate organic carbon (POC) to CO₂ with the rate of solubilization of photoassimilated organic carbon followed by the mineralization of the resultant dissolved organic carbon (DOC) under the same conditions. The direct mineralization of photoassimilated carbon from POC to CO₂ is a more significant process compared with the mineralization of extracellular released organic carbon. The first-order rate coefficients range from 0.132 to 0.434 day^–1 for direct mineralization and 0.034 to 0.189 day^–1 for solubilization.  相似文献   

Some regular patterns in the distribution of sediment contamination in the coastal waters along Japan     

Yasushi Hiraizumi  Takehiko Manabe  Hajime Nishimura 《Journal of Oceanography》1978,34(5):222-232

Observations of sediment contamination along the coast of Japan were analyzed. When the pollutant concentration is divided by the fine particle fraction in the sediment, a regular pattern is observed in the quantitative relationship among the degree and the area of contamination and the discharge rate of pollutant released continuously into the water along the coast. This regularity was observed with respect to COD,n-hexane soluble substances and heavy metals, and could be expressed by a formula.Polluted particles were supposed to disperse through suspension in the bottom water layer, and thus their distribution in the surface sediment is expected to become similar to effluent dispersion in the surface water.  相似文献   

Spatial variations of rare earth elements in north pacific surface water     

Yayoi Hongo  Hajime Obata  Dia Sotto Alibo  Yoshiyuki Nozaki 《Journal of Oceanography》2006,62(4):441-455

The concentration of dissolved rare earth elements (REE) were determined at 47 stations in the North Pacific surface waters. Combining with other previous data, we present the surface REE distribution in the North Pacific and discuss the controlling factors. The surface concentrations increase toward the high latitude and continental margin (e.g. [Nd] > 10 pmol kg⁻¹) from the central North Pacific (e.g. [Nd] < 5 pmol kg⁻¹). The North Pacific Deep Water-normalized REE patterns are varied, indicating that two or more factors contribute to the REE distribution. We examined four factors making the regional variation of surface REE concentrations mainly; a) particle scavenging, b) atmospheric dust input, c) vertical mixing and d) lateral transport from the coastal region. Flux calculations for Nd showed that the influence of atmospheric dust was less significant than the vertical input even in the western upwelling zone. Moreover, the longitudinal and latitudinal transitions of surface REE seem to reflect the lateral supply from the coastal areas. We constructed the diagram of surface Er/Lu and Er/Yb molar ratios in order to assess the origin and the input processes of the surface REE. Both molar ratios showed increasing trend toward PEW (Er/Lu (>10.5) and Er/Yb (>1.4)) from PSUW (Er/Lu (>7) and Er/Yb (>1.2)). The high Er/Lu and Er/Yb ratios in PEW indicate that the lateral supply of terrestrial materials from the coastal area is possibly the important factor in PEW, because only weathering and dissolution of rocks can explain such high Er/Lu and Er/Yb ratios to our knowledge.  相似文献   

Validation of ADEOS-II GLI ocean color products using in-situ observations     

Hiroshi Murakami  Kosei Sasaoka  Kohtaro Hosoda  Hajime Fukushima  Mitsuhiro Toratani  Robert Frouin  B. Greg Mitchell  Mati Kahru  Pierre-Yves Deschamps  Dennis Clark  Stephanie Flora  Motoaki Kishino  Sei-Ichi Saitoh  Ichio Asanuma  Akihiko Tanaka  Hiroaki Sasaki  Katsumi Yokouchi  Yoko Kiyomoto  Hiroaki Saito  Cécile Dupouy  Absornsuda Siripong  Satsuki Matsumura  Joji Ishizaka 《Journal of Oceanography》2006,62(3):373-393

The Global Imager (GLI) aboard the Advanced Earth Observing Satellite-II (ADEOS-II) made global observations from 2 April 2003 to 24 October 2003. In cooperation with several institutes and scientists, we obtained quality controlled match-ups between GLI products and in-situ data, 116 for chlorophyll-a concentration (CHLA), 249 for normalized water-leaving radiance (nLw) at 443 nm, and 201 for aerosol optical thickness at 865 nm (Tau_865) and Angstrom exponent between 520 and 865 nm (Angstrom). We evaluated the GLI ocean color products and investigated the causes of errors using the match-ups. The median absolute percentage differences (MedPD) between GLI and in-situ data were 14.1–35.7% for nLws at 380–565 nm, 52.5–74.8% nLws at 625–680 nm, 47.6% for Tau_865, 46.2% for Angstrom, and 46.6% for CHLA, values that are comparable to the ocean-color products of other sensors. We found that some errors in GLI products are correlated with observational conditions; nLw values were underestimated when nLw at 680 nm was high, CHLA was underestimated in absorptive aerosol conditions, and Tau_865 was overestimated in sunglint regions. The error correlations indicate that we need to improve the retrievals of the optical properties of absorptive aerosols and seawater and sea surface reflection for further applications, including coastal monitoring and the combined use of products from multiple sensors.  相似文献   

Benzo(a)pyrene in the sediment of Osaka Bay and Keihin Canal and its estimated sources     

Yasushi Kawakami  Hajime Nishimura 《Journal of Oceanography》1976,32(4):175-181

Benzo(a)pyrene (BP) in the sediment of Osaka Bay were determined. High concentration was found at two stations near the mouth of Shin-Yodo and off Kobe respectively (0.98g g^–1 dry mud basis, 1.1g g^–1). The concentration decreases regularly from the mouth of the river further into the bay. The other supplemental determination was carried on the sediment and the seawater of Keihin Canal. Notable BP concentration of 89g g^–1 was observed in the sediment beneath the effluent outlet of a gasworks. The BP in the sediment near the ironworks was also considerable, while the BP was relatively less in the sediment beneath the effluent outlet of refineries. These data suggest that coke plants working in gasworks or ironworks may be the larger sources of BP than refineries. The results of Osaka Bay coincide with this hypothesis.Cadmium, lead, copper, zinc, nickel, ignition loss and fine sand content were measured from the same sediment samples of Osaka Bay. Cd, Pb, Cu and ignition loss showed the regular distributions which resemble to BP and accordingly, good correlations with BP. No significant correlations were found between BP and Ni, Zn and fine sand content which showed no regular distributions.  相似文献   

Biological organic carbon export estimated from the annual carbon budget observed in the surface waters of the western subarctic and subtropical North Pacific Ocean from 2004 to 2013     

Masahide Wakita  Makio C. Honda  Kazuhiko Matsumoto  Tetsuichi Fujiki  Hajime Kawakami  Sayaka Yasunaka  Yoshikazu Sasai  Chiho Sukigara  Mario Uchimiya  Minoru Kitamura  Toru Kobari  Yoshihisa Mino  Akira Nagano  Shuichi Watanabe  Toshiro Saino 《Journal of Oceanography》2016,72(5):665-685

The annual flux of biologically produced organic carbon from surface waters is equivalent to annual net community production (NCP) at a steady state and equals the export of particulate and dissolved organic carbon (POC and DOC, respectively) to the ocean interior. NCP was estimated from carbon budgets of salinity-normalized dissolved inorganic carbon (nDIC) inventories at two time-series stations in the western subarctic (K2) and subtropical (S1) North Pacific Ocean. By using quasi-monthly biogeochemical observations from 2004 to 2013, monthly mean nDIC inventories were integrated from the surface to the annual maximum mixed layer depth and corrected for changes due to net air–sea CO₂ exchange, net CaCO₃ production, vertical diffusion from the upper thermocline, and horizontal advection. The annual organic carbon flux at K2 (1.49 ± 0.42 mol m^?2 year^?1) was lower than S1 (2.81 ± 0.53 mol m^?2 year^?1) (p < 0.001 based on t test). These fluxes consist of three components: vertically exported POC fluxes (K2: 1.43 mol m^?2 year^?1; S1: 2.49 mol m^?2 year^?1), vertical diffusive DOC fluxes (K2: 0.03 mol m^?2 year^?1; S1: 0.25 mol m^?2 year^?1), and suspended POC fluxes (K2: 0.03 mol m^?2 year^?1; S1: 0.07 mol m^?2 year^?1). The estimated POC export flux at K2 was comparable to the sum of the POC flux observed with drifting sediment traps and active carbon flux exported by migrating zooplankton. The export fluxes at both stations were higher than those reported at other time-series sites (ALOHA, the Bermuda Atlantic Time-series Study, and Ocean Station Papa).  相似文献   

Comparison of sinking particles in the upper 200 m between subarctic station K2 and subtropical station S1 based on drifting sediment trap experiments     

Makio C. Honda  Hajime Kawakami  Kazuhiko Matsumoto  Masahide Wakita  Tetsuichi Fujiki  Yoshihisa Mino  Chiho Sukigara  Toru Kobari  Mario Uchimiya  Ryo Kaneko  Toshiro Saino 《Journal of Oceanography》2016,72(3):373-386

Drifting sediment trap experiments were conducted during various seasons to elucidate the characteristics of particles sinking through the upper 200 m of the water column in the western Pacific at subarctic station K2 and subtropical station S1. The sinking particle flux increased when primary productivity was high at each station, during June–July at K2 and during February at S1. Biogenic opal (Opal) and CaCO₃ were the major components of the fluxes at K2 and S1, respectively. Contrary to the expectation of a high flux at the eutrophic station K2 and low flux at the oligotrophic station S1, the annual average organic carbon fluxes at 100 m were comparable at both stations: 62.7 mg C m^?2 day^?1 at K2 and 56.1 mg C m^?2 day^?1 at S1. The similarity of the fluxes was perhaps a reflection of the unexpectedly high primary production at S1. At K2, the organic carbon export ratio (organic carbon flux/primary productivity) was significantly and negatively correlated with primary production and tended to decrease with depth. The magnitude of the rate of attenuation of the organic carbon flux with depth was larger at S1 than at K2. This rate of attenuation tended to decrease and increase with primary production at K2 and S1, respectively. The explanation for these patterns may be that the flux of labile organic carbon at relatively shallow depths decreased with increasing primary production at K2, and zooplankton grazing pressure increased with increasing primary productivity at S1.  相似文献   

A Three-Dimensional Simulation of HO x Concentrations Over East Asia During TRACE-P     

Meigen Zhang  Hajime Akimoto  Itsushi Uno 《Journal of Atmospheric Chemistry》2006,54(3):233-254

The Models-3 Community Multi-scale Air Quality modeling system (CMAQ) coupled with the Regional Atmospheric Modeling System (RAMS) is used to simulate three-dimensional concentration distributions of hydroxyl (OH) and hydroperoxyl (HO₂) radicals over the western Pacific Ocean during the NASA Transport and Chemical Evolution over the Pacific (TRACE-P) field campaign. Modeled values of OH and HO₂ and their closely related chemical species and photolysis rates are compared with observational data collected onboard the DC-8 aircraft. Comparison shows that the model reasonably reproduced these observed values over a broad range of conditions with an overall tendency to overestimate the measured OH and HO₂ by a factor of 1.56 and 1.24, respectively. A case study of OH, HO₂ and their closely related chemical species and photolysis rates along the DC-8 flights 11 and 12 conducted on 17–18 March 2001 shows that the model reproduces the temporal and spatial variations reasonable well, and produces more reliable OH and HO₂ concentrations in the polluted environment than in the clean marine boundary layer.  相似文献