应用改进的ICP算法检测工业封头表面变形     

王春林  郑德华  孟敏  谢波 《测绘与空间地理信息》2015,(1):209-211

由于工业封头变形使得采集到的两期点云重心不一致,受点云重心变化的干扰,传统ICP算法出现局部收敛的情况,本文提出了一种基于点对间欧氏距离计算点云加权重心的ICP改进算法。该方法通过给不同距离的点对赋予权值,变形区域的点对距离较大,赋予的权值相对小,有效地消除了变形区域的点云对重心位置的影响。实验结果表明,该方法大大提高了ICP算法的精准性,有效消除重心变化的影响,从而可以准确地检测出工业封头变形区域。  相似文献   

大巴山南部房县东河辉绿玢岩LA ICP MS 锆石U Pb测年及其构造意义     

曹亮  张权绪  胡尚军  段其发  周云  于玉帅  邹先武  甘金木 《地质学报》2015,89(12):2314-2322

大巴山构造带位于秦岭造山带和扬子板块的过渡部位,形成于印支-燕山期,定型于喜山期。前人对北大巴山地区基性岩年代学已有研究,但对大巴山南部地区基性岩却很少高精度年龄报道。本文对大巴山南部房县东河地区的辉绿玢岩脉进行LA-ICP-MS锆石U-Pb年龄测定,结果表明,东河辉绿玢岩形成于439.3Ma,相当于早志留世。与北大巴山镇坪地区辉绿岩,紫阳-岚皋地区基性岩及火山岩形成时代基本一致。结合前人的研究结果表明,大巴山南部地区在早志留世处于张裂状态,东河地区的基性岩为岩石圈处于拉张状态下大陆裂谷作用产物。此处439.3Ma的年龄值,也说明此时扬子板块北缘普遍处于拉张的构造环境,代表了在早志留世大巴山南部裂谷盆地的伸展裂陷幅度达到最大。本次研究所获得的年龄数据,确定了围岩竹山组形成不晚于早志留世,限定地层时代为寒武纪-奥陶纪。  相似文献   

赣南横市地区基性岩墙的LA-ICP-MS锆石U-Pb年龄、地球化学特征及其地质意义   总被引：1，自引：0，他引：1  

左祖发  罗春林  王会敏  刘邦秀  刘春根  徐喆 《地质论评》2015,61(6):1417-1428

本文对江西赣南横市地区基性岩墙进行了年代学、岩石学和地球化学研究,主量元素特征和微量元素分析结果显示,基性岩墙为拉斑玄武岩系列和钙碱性系列,属于富钠基性岩类;Ti O2含量较高,平均含量1%,属于钛较高的基性岩类;A/NCK均小于1,属于准铝质基性岩类,具幔源型岩浆特征。基性岩墙LA-ICP-MS锆石U-Pb定年法测年结果为422.8±1.8 Ma和421.7±2.2 Ma,时代属于晚志留世,表明该基性岩墙是加里东期褶皱造山运动期后拉张(伸展)作用的产物。该地区不仅出露了加里东期同造山期和后造山期两类酸性花岗岩岩体,而且在该地区还同时出现加里东期的酸性岩类及基性岩类,大致反映了该地区从挤压型酸性岩浆侵位逐渐转换为拉张环境的基性岩浆侵位构造过程。  相似文献   

Methodology and Application of Hafnium Isotopes in Ilmenite and Rutile by MC‐ICP‐MS     

Caroline‐Emmanuelle Morisset  James S. Scoates  Dominique Weis  André Rahier 《Geostandards and Geoanalytical Research》2014,38(2):159-176

The high abundances of the high field‐strength elements in ilmenite and rutile make these minerals particularly suitable for hafnium isotopic investigations. We present a technique for separating Hf by ion exchange chemistry from high‐TiO₂ (> 40% m/m) minerals to achieve precise Hf isotopic composition analyses by MC (multiple collector)‐ICP‐MS. Following digestion and conversion to chlorides, the first elution column is used to separate iron and the rare earth elements, the second column is designed to separate most of the titanium from Hf, an evaporation step using HClO₄ is then performed to remove any trace of HF in preparation for the third column, which is needed to eliminate any remaining trace of titanium. The modified chemistry helped to improve the yields from < 10 to > 78% as well as the analytical precision of the processed samples (e.g., sample 2033‐A1, ¹⁷⁶Hf/¹⁷⁷Hf = 0.282251 ± 25 before vs. 0.282225 ± 6 after). The technique was tested on a case study in which the Hf isotopic ratios of ilmenite and rutile (analysed prior to the chemistry improvement) were determined and permitted to evaluate that the origin of rutile‐bearing ilmenite deposits is from the same or similar magma than their, respectively, associated Proterozoic anorthosite massifs (Saint‐Urbain and Lac Allard) of the Grenville Province in Québec, Canada.  相似文献   

Dating Micrometre‐Thin Rims Using a LA‐ICP‐MS Depth Profiling Technique on Zircon from an Archaean Metasediment: Comparison with the SIMS Depth Profiling Method     

Colter J. Kelly  Christopher R.M. McFarlane  David A. Schneider  Simon E. Jackson 《Geostandards and Geoanalytical Research》2014,38(4):389-407

Laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) was examined as a tool for measuring isotopic variation as a function of ablation depth in unpolished zircon from an Archaean metasediment specimen. This technique was able to identify micrometre‐thin (> 3 μm) isotopically distinct mineral domains characterised by ca. 100 Myr younger ²⁰⁷Pb/²⁰⁶Pb ages associated with 2s age uncertainties as low ~ 0.2%, as well as elevated U content relative to grain interiors (up to an order of magnitude). Our calculated drilling rate suggests that each laser pulse excavated depths of ~ 0.06 μm. Ages resolved through the LA‐ICP‐MS methods overlap the 2s uncertainties of ²⁰⁷Pb/²⁰⁶Pb ages measured using SIMS depth profiling on the same zircon population. The rims were further evinced by the detection of relative enrichment (> 3 orders of magnitude) in REE in the outermost micrometres of the same zircon, measured using a different and independent LA‐ICP‐MS depth profiling technique. We propose a LA‐ICP‐MS U–Pb technique capable of quickly identifying and quantifying rims, which are indication of late, yet geologically significant, fluid events that are otherwise undefined.  相似文献   

Apatite Chlorine Concentration Measurements by LA‐ICP‐MS     

David M. Chew  Ray A. Donelick  Margaret B. Donelick  Balz S. Kamber  Michael J. Stock 《Geostandards and Geoanalytical Research》2014,38(1):23-35

Apatite incorporates variable and significant amounts of halogens (mainly F and Cl) in its crystal structure, which can be used to determine the initial F and Cl concentrations of magmas. The amount of chlorine in the apatite lattice also exerts an important compositional control on the degree of fission‐track annealing. Chlorine measurements in apatite have conventionally required electron probe microanalysis (EPMA). Laser ablation inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) is increasingly used in apatite fission‐track dating to determine U concentrations and also in simultaneous U‐Pb dating and trace element measurements of apatite. Apatite Cl measurements by ICP‐MS would remove the need for EPMA but the high (12.97 eV) first ionisation potential makes analysis challenging. Apatite Cl data were acquired using two analytical set‐ups: a Resonetics M‐50 193 nm ArF Excimer laser coupled to an Agilent 7700× quadrupole ICP‐MS (using a 26 μm spot with an 8 Hz repetition rate) and a Photon Machines Analyte Excite 193 nm ArF Excimer laser coupled to a Thermo Scientific iCAP Qc (using a 30 μm spot with a 4 Hz repetition rate). Chlorine concentrations were determined by LA‐ICP‐MS (1140 analyses in total) for nineteen apatite occurrences, and there is a comprehensive EPMA Cl and F data set for 13 of the apatite samples. The apatite sample suite includes different compositions representative of the range likely to be encountered in natural apatites, along with extreme variants including two end‐member chlorapatites. Between twenty‐six and thirty‐nine isotopes were determined in each apatite sample corresponding to a typical analytical protocol for integrated apatite fission track (U and Cl contents) and U‐Pb dating, along with REE and trace element measurements. ³⁵Cl backgrounds (present mainly in the argon gas) were ~ 45–65 kcps in the first set‐up and ~ 4 kcps in the second set‐up. ³⁵Cl background‐corrected signals ranged from ~ 0 cps in end‐member fluorapatite to up to ~ 90 kcps in end‐member chlorapatite. Use of a collision cell in both analytical set‐ups decreased the low mass sensitivity by approximately an order of magnitude without improving the ³⁵Cl signal‐to‐background ratio. A minor Ca isotope was used as the internal standard to correct for drift in instrument sensitivity and variations in ablation volume during sessions. The ³⁵Cl/⁴³Ca values for each apatite (10–20 analyses each) when plotted against the EPMA Cl concentrations yield excellently constrained calibration relationships, demonstrating the suitability of the analytical protocol and that routine apatite Cl measurements by ICP‐MS are achievable.  相似文献   

Measurement of the Isotopic Composition of Molybdenum in Geological Samples by MC‐ICP‐MS using a Novel Chromatographic Extraction Technique     

Jie Li  Xi‐Rong Liang  Li‐Feng Zhong  Xuan‐Ce Wang  Zhong‐Yuan Ren  Sheng‐Ling Sun  Zhao‐Feng Zhang  Ji‐Feng Xu 《Geostandards and Geoanalytical Research》2014,38(3):345-354

A novel preconcentration method is presented for the determination of Mo isotope ratios by multi‐collector inductively coupled plasma‐mass spectrometry (MC‐ICP‐MS) in geological samples. The method is based on the separation of Mo by extraction chromatography using N‐benzoyl‐N‐phenylhydroxylamine (BPHA) supported on a microporous acrylic ester polymeric resin (Amberlite CG‐71). By optimising the procedure, Mo could be simply and effectively separated from virtually all matrix elements with a single pass through a small volume of BPHA resin (0.5 ml). This technique for separation and enrichment of Mo is characterised by high selectivity, column efficiency and recovery (~ 100%), and low total procedural blank (~ 0.18 ng). A ¹⁰⁰Mo‐⁹⁷Mo double spike was mixed with samples before digestion and column separation, which enabled natural mass‐dependent isotopic fractionation to be determined with a measurement reproducibility of  < 0.09‰ (δ^98/95Mo, 2s) by MC‐ICP‐MS. The mean δ^98/95Mo_{SRM 3134} (NIST SRM 3134 Mo reference material; Lot No. 891307) composition of the IAPSO seawater reference material measured in this study was 2.00 ± 0.03‰ (2s, n = 3), which is consistent with previously published values. The described procedure facilitated efficient and rapid Mo isotopic determination in various types of geological samples.  相似文献   

Trace Element Geochemistry of Magnetite from the Fe(-Cu) Deposits in the Hami Region, Eastern Tianshan Orogenic Belt, NW China   总被引：5，自引：0，他引：5  

HUANG Xiaowen  QI Liang  MENG Yumiao 《《地质学报》英文版》2014,88(1):176-195

Laser ablation–inductively coupled plasma–mass spectrometry(LA–ICP–MS) was used to determine the trace element concentrations of magnetite from the Heifengshan, Shuangfengshan, and Shaquanzi Fe(–Cu) deposits in the Eastern Tianshan Orogenic Belt. The magnetite from these deposits typically contains detectable Mg, Al, Ti, V, Cr, Mn, Co, Ni, Zn and Ga. The trace element contents in magnetite generally vary less than one order of magnitude. The subtle variations of trace element concentrations within a magnetite grain and between the magnetite grains in the same sample probably indicate local inhomogeneity of ore–forming fluids. The variations of Co in magnetite between samples are probably due to the mineral proportion of magnetite and pyrite. Factor analysis has discriminated three types of magnetite: Ni–Mn–V–Ti(Factor 1), Mg–Al–Zn(Factor 2), and Ga– Co(Factor 3) magnetite. Magnetite from the Heifengshan and Shuangfengshan Fe deposits has similar normalized trace element spider patterns and cannot be discriminated according to these factors. However, magnetite from the Shaquanzi Fe–Cu deposit has affinity to Factor 2 with lower Mg and Al but higher Zn concentrations, indicating that the ore–forming fluids responsible for the Fe–Cu deposit are different from those for Fe deposits. Chemical composition of magnetite indicates that magnetite from these Fe(–Cu) deposits was formed by hydrothermal processes rather than magmatic differentiation. The formation of these Fe(–Cu) deposits may be related to felsic magmatism.  相似文献   

基于U Pb定年和单颗粒锆石粒径分析示踪 中国黄土高原黄土和红粘土物源   总被引：3，自引：0，他引：3  

李云  宋友桂  聂军胜  孙博亚 《地质论评》2014,60(2):380-388

中国黄土高原的风成沉积蕴含着丰富的大陆古气候和大气环流变化信息,但关于黄土和红粘土物源是否有变化目前仍存在着争论。近些年,锆石的LA-ICP-MS定年被广泛用于追踪沉积物来源,本文把碎屑锆石的UPb定年运用到红粘土中,并结合前人的数据和碎屑锆石粒径分析对黄土和红粘土物源进行了重新的讨论,认为黄土高原黄土碎屑锆石主要来源于黄土高原北部戈壁沙漠和附近的沙漠,极少量锆石来源于青藏高原北部,而不是主要来源于青藏高原北部和柴达木盆地,红粘土的锆石物源受近缘的基岩影响较大,朝那6.2~3.6Ma红粘土锆石碎屑部分来源于附近的六盘山。而且在0.12 Ma、0.86 Ma、1.25 Ma之间,黄土碎屑锆石物源较稳定,存在少量变化,在2.6 Ma和3.6 Ma前后,黄土、红粘土碎屑锆石物源存在明显变化,这可能和全球变冷导致近地面冬季风增强有关。  相似文献   

Determination of Rare Earth Elements and Thorium at Nanogram Levels in Ultramafic Samples by Inductively Coupled Plasma‐Mass Spectrometry Combined with Chemical Separation and Pre‐concentration     

Yali Sun  Shengling Sun  Christina Yan Wang  Peng Xu 《Geostandards and Geoanalytical Research》2013,37(1):65-76

A method was developed for the determination of low‐level rare earth elements (REEs) and thorium in ultramafic samples by inductively coupled plasma‐mass spectrometry. The conventional method for the digestion of ultramafic rocks using HNO₃ and HF results in considerable amounts of insoluble fluorides because of the high contents of Mg (generally up to 24% m/m) in these rocks. In this study, we used H₃BO₃ as a complexing agent to break down the insoluble fluorides, and then separated the REEs from Fe and Mg major and Ba, Ca, Cr minor matrices by anion exchange and co‐precipitation, respectively. The whole procedural blanks estimated from sample‐free analyses ranged from 0.232 ng for Ce to 0.006 ng for Tm and Lu. Limits of detection for this method, defined as three times the standard deviation of these blank analyses, varied from 0.51 ng g^?1 for Ce to 0.03 ng g^?1 for Lu. The recovery of REEs using this technique, as determined using the standard addition method, ranged from 92.9% for Y to 102.0% for Er with 3% (RSD) variation. The method was validated using GAS (GeoPT‐12), JP‐1 and PCC‐1, and the results were comparable to literature values, elucidating the applicability to the determination of ultra trace REEs in ultramafic rocks.  相似文献