Optical properties of low molecular weight and colloidal organic matter: Application of the ultrafiltration permeation model to DOM absorption and fluorescence   总被引：4，自引：1，他引：4  

Claude Belzile  Laodong Guo   《Marine Chemistry》2006,98(2-4):183-196

Cross-flow ultrafiltration (CFF) is often used to obtain separation and concentration of colloids from bulk natural water samples. Application of the ultrafiltration permeation model allows the quantitative determination of the low molecular weight material (LMW, < 1 kDa) and colloids in bulk dissolved organic matter (DOM) from measurements of time series permeate samples obtained from CFF. Detailed analysis of a Yukon River water sample shows that DOM absorption coefficient and fluorescence follow the permeation model and that the complex spectral optical properties of LMW DOM can be reconstructed from CFF data. A combination of measured and modeled data indicates that the LMW contribution to bulk DOM optical properties obtained from CFF can be grossly underestimated by the use of a low concentration factor (CF, the ratio of initial sample volume to retentate volume). Even at a relatively high CF of 19, optical properties of LMW DOM calculated from measurements of the retentate or integrated permeate would underestimate true values by 5–36%. In the Yukon River sample, LMW dissolved organic carbon represented 26% of the bulk concentration, but only 3–14% of the colored DOM was in the LMW fraction while 31–33% of bulk DOM florescence was due to LMW DOM. The contrasting optical properties of LMW and colloidal DOM support the concept that analysis of bulk DOM absorption and fluorescence properties reveals information about DOM molecular weight.  相似文献   

Experimental Study on Friction Coefficient Between Concrete and the Top Surface of Rubble Mound Foundation     

李炎保  蒋学炼  郭鸿仪 《中国海洋工程》2005,19(2):287-298

Experimental studies on the friction coefficient between concrete and the top surface of a rubble mound foundation in China are reviewed. Through comparison of different test results, the development of this research is comprehensively analyzed. An experiment is carried out in the condition similar to prototype. The process curve of friction coefficient with the test block sliding is analyzed and a standard for determination of the friction coetfficient is defined. The variation features of the friction coefficient are analyzed on the basis of the present experimental results and other studies in China. It is shown that the friction coettfficient between concrete and the top surface of a rubble mound foundation decreases with the increase of the foundation pressure, and the friction coettqcient for a very fine leveling bed is smaller than that for a fine leveling bed.  相似文献   

Damage Detection Methods for Offshore Platforms Based on Wavelet Packet Transform     

李东升张兆德  王德禹 《中国海洋工程》2005,19(4):701-710

1 .IntroductionInthe whole service period of the platforms ,some damage is unavoidable due to the corrosion,impact ,fatigue and so on.The damage whould cause the structures’ultimate capacity and safety de-crease .Presently,it is generally acceptedthat the detection of damage involes considerable statisticaluncertainties,thus lot of efforts is made for the damage probalility model ,for example Song and Lu(1996) usedthefuzzy-settheoryto estimatethe humanerrorsthroughthe definitionof inspection…  相似文献   

Non-Simultaneous Failure of Ice in Front of Multi-Leg Structures   总被引：4，自引：1，他引：4  

SHI  Qingzeng 《中国海洋工程》2002,16(2):183-192

Because the multi-leg jacket structure is the major type of offshore structures in the Bohai Sea, the study of non-si-multaneous failure of i鏴 on multi-leg structures is important. However, the non-simultaneous failure has not been consid-ered in engineering design until now, obviously resulting in costly design and notable waste. To resolve this problem, this paper, by means of analysis of experimental data, calculates the coefficient of the non-simultaneous failure for the double-pile structure, the square four-leg structure, the single-line multi-pile structure, and the conical structure, respectively, and provides some reference criteria for engineering design.  相似文献   

海面对风应力的非定常响应     

陈水明 《海洋与湖沼》1994,25(4):399-407

针对常垂直湍流系数和变垂直湍流系数两种情况，给出了开阔静止海面对风应力的非定常响应的解析表达式，并讨论了水深，风应力强弱对响应过程的影响，尽管没有考虑风场的非定常性，但本文的结果对理解海洋对风应力的非定常响应过程具有一定的帮助，对分析海面停风后的消衰过程也具有实际意义。通过与实测资料比较，认为垂直湍流系数模式要比常垂直湍流系数模式更为合理。  相似文献   

Wave Reflection Caused by Wave Overtopping and Sloping Top of Spructure     

LI  Yanbao 《中国海洋工程》2002,16(2):211-218

In this paper, the theoretical analysis and experimental studies are employed to investigate the reflection characteris-tics of partial standing waves caused by wave overtopping and sloping top of structures. Based on the principle of conser-vation of wave energy flux, the third-order Stokes wave theory is used to formulate the reflection coefficient at wave overtopping; the calculation results are regressed into an applied expression. A series of experiments of wave reflection for a vertical-wall structure with chamfered and overhanging upper sections are carried out to investigate the influence of top slope on wave reflection. The regularity of variation of wave reflection in this case is analysed based on the experimental results.  相似文献   

台湾海峡1997年8月至1999年8月份海水光学衰减系数的分布特征   总被引：2，自引：0，他引：2  

张彩云  商少平  胡建宇  陈照章 《台湾海峡》2001,20(1):127-131

利用1997－1999年间8月份台湾海峡的实测资料，分析了海水光学衰减系数的垂直分布类型、水平分布特征。结果表明，台湾海峡海水光学衰减系数的垂直分布类型主要分为5种，大部分随深度而递增；光学衰减系数等值线基本与岸线平行，水平梯度自北向南、自近岸向外海递减，近岸等值线密集，而外海稀疏；影响台湾海峡光学衰减系数的主要因素是县浮物质（主要含浮游生物）和海流运动。  相似文献   

Hilbert Transferin Applied to Separation of Waves     

孙鹤泉  王永学  彭静萍 《中国海洋工程》2002,(2)

The analytical method (AM) for separation of composite waves is presented based on the Hilbert transform. It is ap-plicable to both regular and irregular trains of waves. The wave data series measured with two wave gauges in the experi-ments are separated into two series of incident and reflected waves. Then, the reflection coefficient can be easily ob-tained. The arrival of reflected waves can also be detected for improveraent of the accuracy of the reflection coefficient. The reflection performance of the physical model can be estimated exactly without calculation of wave height and phase difference. Numerical samples developed to test the method are proved to be accurate. Physical experiments are conduct-ed and compared with Goda s method and satisfactory results are obtained.  相似文献   

钝顶螺旋藻C-藻蓝蛋白和多管藻R-藻红蛋白的分离纯化及摩尔消光系数的测定   总被引：2，自引：1，他引：2  

王广策  周百成  曾呈奎 《海洋科学》1996,20(1):52-55

１９９３年１１月～１９９４年１月用简单的羟基磷灰石柱层析法从多管藻中分 离纯化了Ｒ－藻红蛋白和从钝顶螺旋藻中纯化了Ｃ－藻蓝蛋白，它们的纯度（指可见 光部分的最大吸收与 ２８０ｎｍ处吸收值之比）可分别达到 ６（Ｒ－藻红蛋白）和 ５． ５（Ｃ－ 藻蓝蛋白）。由于不同藻种的同种藻胆蛋白的摩尔消光系数不同，所以应用凯氏定 氮法并结合可见光的吸收值测定了上述两种藻胆蛋白的摩尔消光系数，钝顶螺旋 藻Ｃ－藻蓝蛋白为１．８５３ × １０６ｍｏｌ－１ｃｍ－１（６２０ｎｍ），多管藻Ｒ－藻红蛋白为１．７９６ × １０６ｍｏｌ－１ｃｍ－１（４９８ｎｍ），为藻胆蛋白的浓度测定提供了方便。  相似文献   

厦门湾有色溶解有机物的光吸收特性研究   总被引：3，自引：0，他引：3  

李猛  郭卫东  夏恩琴  韩宇超  胡明辉 《热带海洋学报》2006,25(1):9-14

研究了厦门湾九龙江河口区、西海域、同安湾及东侧水道海水中有色溶解有机物(CDOM)的光吸收特性,分析了CDOM的河口行为,并讨论了CDOM光吸收特性与其荧光性质之间的关系。结果表明,厦门湾表层海水CDOM光吸收系数a(355)的水平分布表现为河口区最高、东侧水道最低、西海域和同安湾介于两者之间,底层水a(355)的分布与表层基本相似,表明陆源河流输入是厦门湾CDOM的主要来源;a(355)的垂直分布为表层高于底层,主要受水文和生物因素控制。厦门湾表层水CDOM光谱斜率S的平均值介于0.014—0.018nm-1,但河口低盐度区S值较小,反映陆源腐殖质的影响。a(355)在河口混合中呈保守行为,表明CDOM具有良好的保守性质。CDOM的吸收系数a(355)与其荧光强度之间表现为较好的相关关系,指示可以用灵敏度更高的荧光方法来研究CDOM的分布和行为。  相似文献