Usefulness of geological,mineralogical, chemical and chemometric analytical techniques in exploitation and profitability studies of iron mines and their associated elements     

M. Dolores Petit-Dominguez  M. Isabel Rucandio  Almudena Galan-Saulnier  Rosario Garcia-Gimenez 《Journal of Geochemical Exploration》2008

Due to the high number of variables involved in mine profitability studies, it is often very difficult to establish connections among them in order to provide a blend of market saleable quality products. In this sense, analytical chemistry together with chemometry are essential and indispensable disciplines to tackle these studies. The aim of this work was to demonstrate the utility of these disciplines to carry out optimization studies of iron mines. For this purpose, one of the most important iron mines of the Iberian Peninsula was chosen, sited in the mountain range of Sierra Menera, near the location of Ojos Negros (Teruel, Spain). Geological, mineralogical and chemical composition of 148 samples was analyzed, corresponding to different depths of three drill holes (named TE1, TE2 and TE3). In particular, aspects concerning to chemical composition are very important, since the mean contents of certain elements, such as phosphorus, sodium and potassium, should be restricted to the established limits to prevent that companies can drive back the raw material if they do not fulfil the necessary requirements. On the other hand, the large number of analysed samples drove us to use a statistical processing of the data. Among other aspects, it provides a way to find possible connections among a high number of variables and classify samples into compositional groups sharing similar composition, in order to limit the mineralised area and to obtain enough information about the amount of those chemical elements associated to iron ores. Data obtained from all these analytical techniques were in good agreement and provide a methodology that can be of wide interest applied to different geological studies.  相似文献   

Phosphorus transport in shallow groundwater in peri-urban Kampala, Uganda: results from field and laboratory measurements   总被引：1，自引：0，他引：1  

N. R. Kulabako  M. Nalubega  R. Thunvik 《Environmental Geology》2008,53(7):1535-1551

To understand Phosphorus (P) sources and transport processes in the subsurface in Bwaise III Parish, Kampala, P attenuation and adsorption capacities of soils were studied in situ and from laboratory measurements. Relationships between sorption parameters and soil matrix properties, rates and mechanism of the adsorption process and soil P fractions were also investigated. P was generally higher in the wet than the dry season, but for both seasons, the maximum was 5 mgP/l. P transport mechanisms appeared to be a combination of adsorption, precipitation, leaching from the soil media and by colloids with the latter two playing an important role in the wet season. The sorption process comprised two phases with the first stage rate constants being about fourfold those of the second stage. The Langmuir isotherm described the sorption data well (R ² ≥ 0.95) with the second soil layer exhibiting the highest sorption maximum (C _max) (average value 0.6 ± 0.17 mgP/gDW). The best prediction of C _max had organic carbon, Ca, available P and soil pH. Residual P consisting mostly of organics was the main fraction in all the layers followed by inorganic HCl-P and NaOH-P in the top and middle layers, respectively. Loosely bound P (NH₄Cl-P) was the least fraction (<0.4% of total P) in all layers indicating the high binding capacity of P by the soils. The study results suggest that P dynamics is related to Ca, Fe and organic carbon content of the soils.  相似文献   

The transformation and export of phosphorus from Wetlands     

Jim Gehrels  George Mulamoottil 《水文研究》1989,3(4):365-370

There is widespread acceptance of the phosphorus retention capability of wetlands even though research findings are often inconclusive and contradictory. The results of a one year phosphorus budget study indicate that internal wetland processes may transform sediment bound phosphorus to plant available orthophosphorus. While total phosphorus imports were nearly double the total phosphorus exports for the study wetland, orthophosphorus exports were 22 per cent greater than imports. This study supports the recent finding that wetlands have limited capability to retain orthophosphorus and indicates that wetlands may even increase the export of orthophosphorus. The generally accepted nutrient retention function of wetlands and their possible role in eutrophication is thus questionable.  相似文献   

Water-removed spectra increase the retrieval accuracy when estimating savanna grass nitrogen and phosphorus concentrations   总被引：2，自引：0，他引：2  

Abel Ramoelo  Andrew K. SkidmoreMartin Schlerf  Renaud MathieuIgnas M.A. Heitkönig 《ISPRS Journal of Photogrammetry and Remote Sensing》2011,66(4):408-417

Information about the distribution of grass foliar nitrogen (N) and phosphorus (P) is important for understanding rangeland vitality and for facilitating the effective management of wildlife and livestock. Water absorption effects in the near-infrared (NIR) and shortwave-infrared (SWIR) regions pose a challenge for nutrient estimation using remote sensing. The aim of this study was to test the utility of water-removed (WR) spectra in combination with partial least-squares regression (PLSR) and stepwise multiple linear regression (SMLR) to estimate foliar N and P, compared to spectral transformation techniques such as first derivative, continuum removal and log-transformed (Log(1/R)) spectra. The study was based on a greenhouse experiment with a savanna grass species (Digitaria eriantha). Spectral measurements were made using a spectrometer. The D. eriantha was cut, dried and chemically analyzed for foliar N and P concentrations. WR spectra were determined by calculating the residual from the modelled leaf water spectra using a nonlinear spectral matching technique and observed leaf spectra. Results indicated that the WR spectra yielded a higher N retrieval accuracy than a traditional first derivative transformation (R²=0.84, RMSE = 0.28) compared to R²=0.59, RMSE = 0.45 for PLSR. Similar trends were observed for SMLR. The highest P retrieval accuracy was derived from WR spectra using SMLR (R²=0.64, RMSE = 0.067), while the traditional first derivative and continuum removal resulted in lower accuracy. Only when using PLSR did the first derivative result in a higher P retrieval accuracy (R²=0.47, RMSE = 0.07) than the WR spectra (R²=0.43, RMSE = 0.070). It was concluded that the water removal technique is a promising technique to minimize the perturbing effect of foliar water content when estimating grass nutrient concentrations.  相似文献   

Organic carbon deposition and phosphorus accumulation during Oceanic Anoxic Event 2 in Tarfaya, Morocco     

Haydon P. Mort  Thierry Adatte  Gerta Keller  David Bartels  Karl B. Fllmi  Philipp Steinmann  Zsolt Berner  E.H. Chellai 《Cretaceous Research》2008,29(5-6):1008

With a multi-proxy approach, an attempt was made to constrain productivity and bottom-water redox conditions and their effects on the phosphorus accumulation rate at the Mohammed Plage section on the Tarfaya coast, Morocco, during the Cenomanian-Turonian Anoxic Event (OAE 2). A distinct δ¹³C_org isotope excursion of +2.5‰ occurs close to the top of the section. The unusually abrupt shift of the isotope excursion and disappearance of several planktonic foraminiferal species (e.g. Rotalipora cushmani and Rotalipora greenhornensis) in this level suggests a hiatus of between 40–60 kyrs at the excursion onset. Nevertheless, it was possible to determine both the long-term environmental history as well as the processes that took place immediately prior to and during OAE 2. TOC% values increase gradually from the base of the section to the top (from 2.5% to 10%). This is interpreted as the consequence of a long-term eustatic sea-level rise and subsidence causing the encroachment of less oxic waters into the Tarfaya Basin. Similarly a reduction in the mineralogically constructed ‘detrital index’ can be explained by the decrease in the continental flux of terrigenous material due to a relative sea-level rise. A speciation of phosphorus in the upper part of the section, which spans the start and mid-stages of OAE 2, shows overall higher abundances of P_reactive mass accumulation rates before the isotope excursion onset and lower values during the plateau. Due to the probable short hiatus, the onset of the decrease in phosphorus content relative to the isotope excursion is uncertain, although the excursion plateau already contains lower concentrations. The C_org/P_total and V/Al ratios suggest that this reduction was mostly likely caused by a decrease in the available bottom oxygen content (probably as a result of higher productivity) and a corresponding fall in the phosphorus retention ability of the sediment. Productivity appears to have remained high during the isotope plateau possibly due to a combination of ocean-surface fertilisation via increased aridity (increased K/Al and Ti/Al ratios) and/or higher dissolved inorganic phosphorus content in the water column as a result of the decrease in sediment P retention. The evidence for decreased P-burial has been observed in many other palaeoenvironments during OAE 2. Tarfaya's unique upwelling paleosituation provides strong evidence that the nutrient recycling was a global phenomenon and therefore a critical factor in starting and sustaining OAE 2.  相似文献   

The research of phosphorus of Xiangxi River nearby the Three Gorges, China     

Chang-Ying Fu  Tao Fang  Nan Sheng Deng 《Environmental Geology》2006,49(6):923-928

The Xiangxi River is the first middling tributary of the Changjiang River near the Three Gorges Dam. The River is subject to phosphorus pollution mainly from industrial wastewater. As the water quality of the Xiangxi River could directly influence the water quality of the Three Gorges Reservoir, the research on phosphorus levels and its change in the sediment profile of the Xiangxi River could provide useful information in the dynamic changes in the system, thereby offering options for mitigative measures. Water and sediment samples from lower reaches of Xiangxi River were collected and the different forms of phosphorus in sediments of the Xiangxi River were studied. The concentrations of total phosphorus in sediment ranged from 757.67 to 1438.54 mg/kg. Inorganic phosphorus concentrations ranged from 684.63 to 1055.58 mg/kg. Phosphorus contamination was serious in some parts of the Xiangxi River. With an average concentration of 635.17 mg/kg, calcium-bound phosphorus is the main form among different inorganic phosphorus forms. Labile phosphorus and iron/aluminum-bound phosphorus measured 3.40, 0.05and 35.28 mg/kg, respectively. The mobilization potential of phosphorus of sediments was studied through adsorption and release experiments. The equilibrium concentration of phosphorus adsorption and release was around 0.1 mg/L. The initial concentrations of phosphorus in the overlying water and the sediments have obvious effect on phosphorus mobilization potential. In addition, the release rate of phosphorus in sediment increased with water depth.  相似文献   

Nutrient dynamics in Mediterranean temporary streams: A case study in Pardiela catchment (Degebe River, Portugal)   总被引：1，自引：0，他引：1  

Ana Isabel Lilleb  Manuela Morais  Pedro Guilherme  Rita Fonseca  Antnio Serafim  Ramiro Neves 《Limnologica》2007,37(4):337-348

Most of the streams in the Mediterranean region are temporary, following predictable seasonal of flooding and drying, with a transition from lotic conditions to shallow lentic conditions. The goal of our study was to assess the nitrogen and phosphorus dynamics in channel-bed processes of temporary streams between floods. Results show that, during winter, temperatures ranged between 9.5 and 11.2 °C and oxygen concentration ranged from 8.0 to 9.5 mg L⁻¹, whereas, during summer, temperatures varied between 21.2 and 26.8 °C and oxygen between 1.2 and 5.3 mg L⁻¹, with oxygen depletion in the pools during the night. The nitrate concentrations were far more abundant during winter (February), while ammonium concentration increased after stream fragmentation into pools (especially in July when oxygen depletion conditions favoured ammonification). Results on sediment profiles showed that the most active sediment layers for NH₄-N are the top 2–3 cm, corresponding to the sediment depositional sites of the stream. Phosphate concentrations had larger variability, yet concentrations decreased from winter to spring and increased again in summer, when the shallow water pools were formed. Sediment profiles at the sediment depositional sites showed that PO₄-P was more dynamic in the first 6 cm.

In Mediterranean temporary streams, nutrient dynamics vary seasonally, as the system transits from lotic conditions to shallow lentic conditions, evidencing the regeneration of nutrients from organic and inorganic matter during the flow cessation period.  相似文献   

Vertical distribution and water solubility of phosphorus and heavy metals in sediments of the St. Lucie Estuary, South Florida, USA   总被引：2，自引：0，他引：2  

Z. L. He  M. Zhang  P. J. Stoffella  X. E. Yang 《Environmental Geology》2006,50(2):250-260

Accumulation and distribution of heavy metals and phosphorus in sediments impact water quality. There has been an increasing concern regarding fish health in the St. Lucie Estuary, which is related to increased inputs of nutrients and metals in recent decades. To investigate vertical changes of contaminants (P, Cd, Cr, Co, Cu, Ni, Pb, Zn, and Mn) in sediments of the St. Lucie Estuary in South Florida, 117 layer samples from six of the 210 to 420 cm depth cores were analyzed for their total and water-soluble P and heavy metals, clay, total Fe, Al, K, Ca, Mg, Na, and pH. Principal component analysis (PCA) was used in two sets of analytical data (total and water-soluble contaminant concentrations) to document changes of contaminants in each core of sediments. The PCA of total contaminants and minerals resulted in two factors (principal components). The first and second factors accounted for 61.7 and 17.2 % of the total variation in all variables, and contrast indicators associated with contaminants of P, Cd, Co, Cr, Ni, Pb, Zn, and Mn and accumulation of Fe and Al oxides, respectively. The first factor could be used for overall assessment of P and heavy metal contamination, and was higher in the upper 45–90 cm than the lower depths of each core. The concentrations of P and heavy metals in the surface layers of sediments significantly increased, as compared with those in the sediments deeper than 45–90 cm. The PCA of water-soluble contaminants developed two factors. The second factor (Cu–P) was higher in the upper than the lower depths of the sediment, whereas the highest score of the first factor (Cd–Co–Cr–Ni–Pb–Zn–Mn) occurred below 100 cm. The water-soluble Cu and P concentrations were mainly dependent on their total concentrations in the sediments, whereas the water-soluble Cd, Co, Cr, Ni, Pb, Zn, and Mn concentrations were mainly controlled by pH.  相似文献   

The Application of a Diatom-based Transfer Function to Evaluate Regional Water-Quality Trends in Minnessota Since 1970     

J.M. Ramstack  S.C. Fritz  D.R. Engstrom  S.A. Heiskary 《Journal of Paleolimnology》2003,29(1):79-94

Significant population growth over the last three decades, as well as efforts to improve surface-water quality mandated by the Clean Water Act, potentially have had opposing influences on aquatic ecosystems in the U.S. Because historical data on water-quality trends are limited over this time period, we developed a diatom-based transfer function to reconstruct chloride, color, acid neutralizing capacity (ANC), total phosphorus (TP), and pH in 55 Minnesota lakes. The lakes span three different ecoregions, as well as the Twin Cities metropolitan area, and differ in their history of settlement and land use, and in surficial geology, climate, and vegetation. Lakes in the Northern Lakes and Forest ecoregion are nearly pristine, whereas those in the other regions likely are strongly affected by urban or agricultural pollutants. Reconstructions of water-chemistry trends since 1970 suggest that recent human activities have had substantial impacts in both urban and rural areas. Chloride concentrations have increased in many Metro lakes, which may be due to road salts, and phosphorus levels have been steady or rising in agricultural regions. The majority of Metro lakes show some decline in TP, although many of the changes are not statistically significant based on our reconstruction techniques. There is no evidence that atmospheric deposition of sulfate or nitrate has caused acidification or changes in trophic state for remote lakes in the northeastern part of the state.  相似文献   

上海旱地农田氮磷随地表径流流失研究   总被引：14，自引：0，他引：14  

黄宗楚  郑祥民  姚春霞 《云南地理环境研究》2007,19(1):6-10

选择上海宝山罗店镇具有代表性的旱地蔬菜农田生态系统，从2004年3月到8月的近半年时间里，通过对径流及径流中侵蚀泥沙的氮磷流失情况的连续监测，研究了旱地农田施肥与氮磷流失污染之间的关系，探讨了农田氮磷的迁移特征及环境效应，主要结果表明：当季施用化肥的地表径流总流失量，总氮为32．77kg/hm^2，总磷为8．1kg／hm^2，随径流排出农田的氮素中有37．7％是当季施用的氮素化肥，磷素中有26．9％是当季施用的磷素化肥；从过量施肥与环境污染之间的“因”与“果”来看，减量15％施肥区相比常规施肥区的茄子的产量减少2．7％，但是其污染负荷却减少了13．4％，表明在化肥利用的有效性上或增施化肥与控制环境污染之间，应该寻找一个最佳的平衡点。  相似文献