煤中As的赋存状态及其在燃烧过程中的转化   总被引：1，自引：0，他引：1  

鲁静  孙俊民  赵承美 《煤田地质与勘探》2003,31(5):6-9

对煤中砷的赋存状态进行了综述,总结了砷在燃煤过程中的迁移转化行为。从飞灰演化的角度探讨了飞灰对砷的富集机制,认为飞灰对砷的富集是伴随飞灰的演化过程进行的。飞灰对砷的富集主要有4种形式,即发生化学反应生成含砷稳定化合物,进入粘土矿物晶格内部,飞灰对砷及其化合物的吸附和冷凝   相似文献   

大同盆地砷、氟中毒地方病生态地球化学研究   总被引：17，自引：1，他引：16  

赵伦山  武胜  周继华  王敬华  王建武 《地学前缘》2007,14(2):225-235

山西大同盆地属干冷荒漠景观条件的半封闭型断陷盆地。区内有害元素的聚集导致氟中毒等多种地方病肆虐,20世纪90年代因开发和饮用深层地下水爆发了水砷中毒病。经地球化学调查发现:地下潜水高含F,超标1.3～12倍;深层承压地下水富As,砷含量超标2～20倍。砷中毒发病率与饮水中As3+/∑As比值呈正相关关系。盆地周边分布多层富含As和F的地层和火成岩体,处于富As、F的区域地球化学省内。由于大同盆地的不均匀沉降,在其边缘部分形成深凹陷带,含砷下渗地下水经有机碳质层的还原作用,使砷还原为三价,提高了地下水的毒性并滞留聚集。探讨了F、As富集和中毒的机理和生态地球化学危害评价,提出了治理和外围调查预测建议。  相似文献   

云南耿马孟定盆地高砷水成因及其危害   总被引：2，自引：0，他引：2  

李燕  王强  蒋成兴  李丽辉  李庆生 《云南地质》2009,28(4):367-373

孟定盆地出现水砷异常由三类因素共同作用引发：汇水区砷背景高,有色金属采选冶过程排放含砷重金属导致砷二次污染,盆地地球化学环境利于砷积累。形成环境具一定的代表性,区别于我国已发生的饮水型盆地砷病病区。  相似文献   

原生锡矿蒸馏碘量法测砷的问题及解决方法     

黑宗柳 《云南地质》2009,28(3):307-310

原生锡矿蒸馏量法测砷,在测定过程中多注意锑元素的干扰,蒸馏体积的控制等因素,可得到更准确、可靠的测定结果。  相似文献   

Salt tectonics and tear faulting in the central part of the Zagros Fold-Thrust Belt,Iran     

《Marine and Petroleum Geology》2017

The central part of the Zagros Fold-Thrust Belt is characterized by a series of right-lateral and left-lateral transverse tear fault systems, some of them being ornamented by salt diapirs of the Late Precambrian–Early Cambrian Hormuz evaporitic series. Many deep-seated extensional faults, mainly along N–S and few along NW–SE and NE–SW, were formed or reactivated during the Late Precambrian–Early Cambrian and generated horsts and grabens. The extensional faults controlled deposition, distribution and thickness of the Hormuz series. Salt walls and diapirs initiated by the Early Paleozoic especially along the extensional faults. Long-term halokinesis gave rise to thin sedimentary cover above the salt diapirs and aggregated considerable volume of salt into the salt stocks. They created weak zones in the sedimentary cover, located approximately above the former and inactive deep-seated extensional faults. The N–S to NNE–SSW direction of tectonic shortening during the Neogene Zagros folding was sub-parallel with the strikes of the salt walls and rows of diapirs. Variations in thickness of the Hormuz series prepared differences in the basal friction on both sides of the Precambrian–Cambrian extensional faults, which facilitated the Zagros deformation front to advance faster wherever the salt layer was thicker. Consequently, a series of tear fault systems developed along the rows of salt diapirs approximately above the Precambrian–Cambrian extensional faults. Therefore, the present surface expressions of the tear fault systems developed within the sedimentary cover during the Zagros orogeny. Although the direction of the Zagros shortening could also potentially reactivate the basement faults as strike-slip structures, subsurface data and majority of the moderate-large earthquakes do not support basement involvement. This suggests that the tear fault systems are detached on top of the Hormuz series from the deep-seated Precambrian–Cambrian extensional faults in the basement.  相似文献   

索氏提取-原子荧光光谱法测定含油岩心中的汞和砷   总被引：1，自引：1，他引：0  

乔宁强  薛志伟  王刚峰  罗丹 《岩矿测试》2019,38(4):461-467

原油对测定含油岩心中的汞和砷有很大影响,目前去除原油等有机物的方法主要有高温烧制、强酸高温氧化等,要求反应温度较高,会造成汞和砷的损失而使测定结果偏低。本文采用索氏提取法,以氯仿作为提取剂在75℃下低温提取分离岩心中的原油,再用50%的王水溶解剩余样品,原子荧光光谱法测定汞和砷的含量。该方法对汞和砷的检出限分别为0. 003mg/kg和0. 10mg/kg,相对标准偏差分别为7. 3%和5. 1%,加标回收率均大于92. 5%。与传统方法相比较,该方法避免了由于原油的疏水性造成样品与王水接触不充分、样品分解不完全和反应温度过高导致汞元素损失的问题,测定汞的相对标准偏差由33. 0%降低至7. 3%,测定砷的相对标准偏差由25. 0%提高至5. 1%,为含油岩心中其他元素的检测提供了借鉴。  相似文献   

我国热液金矿中黄铁矿的载金性研究     

刘一浩  薛春纪  赵云  赵晓波  褚海霞  刘城先  余亮  王璐  吴得海 《现代地质》2020,34(1):1-12

黄铁矿是热液金矿主要的载金矿物。单个金矿中黄铁矿的载金已有不少研究,并积累了相关经验,但综合研究和相对定量的分析鲜见,对热液金矿中黄铁矿含金性的普遍认识非常重要。以我国数十个重要的卡林/类卡林型、造山型、岩浆热液型以及浅成低温热液型金矿中载金黄铁矿的矿物学及元素组成为基础,相对全面和定量地开展了黄铁矿粒径、自形程度和As含量与其载金性之间相关性的研究。结果表明:黄铁矿的载金性与其粒径大小多呈负相关(相关系数为-0.049~-0.783),与其自形程度多呈负相关(相关系数为-0.049~-0.989),与其As含量多呈正相关(相关系数为0.189~0.998),即细晶、它形、高As黄铁矿载金性优于粗晶、自形、低As的黄铁矿。相较于粗晶自形的黄铁矿,中细晶它形黄铁矿晶体,由于非理想的生长条件,使其内部晶格缺陷常见,从而更易包裹自然金;As以类质同象的形式置换S进入黄铁矿,由于As与S的晶体化学性质差异,导致高As黄铁矿内部出现更多晶格缺陷而捕获金。这些可能都是导致细晶、它形、高As黄铁矿载金性优于粗粒、自形、低As黄铁矿的原因。热液金矿成矿早阶段形成黄铁矿中的不可见金,很可能在热液系统中通过溶解、迁移、再沉淀等过程,而转变为可见金。  相似文献   

Solid-solution partitioning of arsenic （As） in the paddy soil profiles in Chengdu Plain, Southwest China     

Xiaoyan Yang  Qingye Hou  Zhongfang Yang  Xin Zhang  Yijun Hou 《地学前缘(英文版)》2012,3(6):901-909

To predict the long-term behavior of arsenic(As) in soil profiles,the solid-solution partitioning of As was studied in four paddy soil profiles obtained from agricultural areas in Chengdu Plain,Southwest China.Paddy soil profile samples were collected and soil solution samples were extracted.Total As contents in soil solution and soil solid were analyzed,along with the soil solid phase properties.The As in soil solution was significantly higher in the upper layer(0—20 cm) and had a definite tendency to decrease towards 40 cm regardless of the sampling locations.When the concentration of arsenic in soil solution decreased,its content in solid phase increased.Field-based partition coefficient(K_d) for As was determined by calculating the ratio of the amount of As in the soil solid phase to the As concentration in the soil solution.K_d values varied widely in vertical samples and correlated well with soil pH,total organic carbon(TOC) and total As. The results of this study would be useful for evaluating the accumulation trends of arsenic in soil profiles and in improving the management of the agricultural soils.  相似文献   

绿春大马尖山铜砷矿矿床成因     

郑世红 《云南地质》2010,29(4):420-423

矿体赋存于下志留统变质砂板岩及侵入其中的石英斑岩中,与燕山晚期构造运动及岩浆活动有关。水平及垂直分带明显。属低温热液硫化物充填—交代型铜砷矿。  相似文献   

黔东南火烧寨金锑(砷)矿矿床地球化学特征及矿化富集规律浅析          下载免费PDF全文

陈兴龙 《地质找矿论丛》2010,25(2):129-133

火烧寨锑金(砷)矿位于黔东南雷公山多金属成矿带的双尧—火烧寨成矿亚带。通过对成矿地质特征和矿床地球化学特征的研究,提出矿带主要受控于深切地幔的独山—松桃深大断裂及分支断裂,成矿活动与构造-岩浆活动具有同步性,并总结了成矿富集规律。  相似文献