全文获取类型
收费全文 | 833篇 |
免费 | 193篇 |
国内免费 | 276篇 |
专业分类
测绘学 | 17篇 |
大气科学 | 86篇 |
地球物理 | 403篇 |
地质学 | 547篇 |
海洋学 | 190篇 |
天文学 | 1篇 |
综合类 | 38篇 |
自然地理 | 20篇 |
出版年
2024年 | 3篇 |
2023年 | 4篇 |
2022年 | 29篇 |
2021年 | 36篇 |
2020年 | 39篇 |
2019年 | 36篇 |
2018年 | 32篇 |
2017年 | 36篇 |
2016年 | 40篇 |
2015年 | 45篇 |
2014年 | 49篇 |
2013年 | 49篇 |
2012年 | 64篇 |
2011年 | 78篇 |
2010年 | 76篇 |
2009年 | 73篇 |
2008年 | 71篇 |
2007年 | 48篇 |
2006年 | 94篇 |
2005年 | 59篇 |
2004年 | 52篇 |
2003年 | 29篇 |
2002年 | 34篇 |
2001年 | 31篇 |
2000年 | 31篇 |
1999年 | 29篇 |
1998年 | 19篇 |
1997年 | 16篇 |
1996年 | 15篇 |
1995年 | 16篇 |
1994年 | 11篇 |
1993年 | 6篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 10篇 |
1989年 | 6篇 |
1988年 | 9篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有1302条查询结果,搜索用时 15 毫秒
1.
Aubry Vanderstraeten Steeve Bonneville Stefania Gili Jeroen de Jong Wendy Debouge Philippe Claeys Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329
Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements. 相似文献
2.
目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法(GC-MS),由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度,在污染物的环境行为研究中得到广泛应用,GC-MS法的定性效果好,但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况,结果显示,即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度,同时保证检测灵敏度,实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法,最终选择中等极性的TG-35MS为第一色谱柱,非极性的(DB-1)为第二色谱柱,将鲜样与无水硫酸钠混合均匀后,以正己烷-丙酮(1:1,V/V)为提取剂进行索氏提取,采用全二维气相色谱-电子捕获检测器进行检测,外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系,相关系数均大于0.995,检出限为0.02~0.17μg/kg。用标准加入法进行回收实验,测得回收率为80.7%~103.5%,测定值的相对标准偏差(n=6)为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合,在保证检测灵敏度的同时增加了峰容量,有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg(全扫模式),本方法检出限显著降低,且操作简单,可为复杂基质样品中的痕量超痕量检测提供参考。 相似文献
3.
陷落柱是煤田勘探开发中常见的地质灾害体,陷落柱的精确探测一直是煤田安全生产研究的重点,单纯依靠常规纵波地震勘探技术难以满足现阶段煤田精细勘探的需求。多波地震勘探技术能够获得纵波和转换波地震资料,提供更丰富的波场信息,且转换波对于埋深较浅的小幅度构造有更高的分辨率,充分利用多分量地震资料可以有效的提高地震勘探的精度。本文将多波地震技术应用到煤层陷落柱研究中,利用数值方法对煤层陷落柱进行多波地震勘探模拟研究,采用弹性波有限差分方法对构建的陷落柱模型进行多分量正演模拟,然后分别对波场分离后的PP波和PS波地震数据进行叠前深度偏移成像测试。通过对两个小尺寸陷落柱模型进行多波地震数值试算表明,多波地震勘探技术是一种有效的煤层陷落柱探测方法,充分利用多波地震资料有利于查明煤层陷落柱构造,对陷落柱取得更好的勘探效果。 相似文献
4.
A new model is presented for multiblock columns subjected to earthquakes, which contains an impact and an opening model. Both in the impact and in the opening model, all the possible opening configurations are investigated because it was found that in many practical cases, unexpected patterns may occur. The model is purely mechanical: assuming rigid blocks and classical (inelastic) impact. The effect of energy dissipation during impact was investigated. Using our model in accordance with the literature, it was found that monolithic blocks are more vulnerable to overturning than multiblock systems. 相似文献
5.
Kaj Sullivan Daniel Layton‐Matthews Matthew Leybourne James Kidder Zoltn Mester Lu Yang 《Geostandards and Geoanalytical Research》2020,44(2):349-362
The characterisation of relative copper isotope amount ratios (δ65Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ65Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ65Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ65Cu. Additionally, four reference materials (with published δ65Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g?1 to 497 µg g?1 and δ65Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment. 相似文献
6.
结合夏县中心地震台CIC-200型离子色谱仪实际观测,从仪器输液系统、分离系统、基线、管路等方面详细阐述色谱仪常见故障,逐一分析原因,并给出相应故障排除方法,为同类仪器维护提供参考,并为获得准确观测数据,延长仪器使用寿命,提出日常维护方法及建议。 相似文献
7.
The aim of this work is to model beam‐column behavior in a computationally effective manner, revealing reliably the overall response of reinforced concrete members subjected to intensive seismic loading. In this respect, plasticity and damage are considered in the predominant longitudinal direction, allowing for fiber finite element modeling, while in addition the effect of inelastic buckling of longitudinal rebars, which becomes essential at later stages of intensive cyclic loading, is incorporated. Α smooth plasticity‐damage model is developed for concrete, accounting for unilateral compressive and tensile behavior, nonlinear unloading and crack closure phenomena. This is used to address concrete core crushing and spalling, which triggers the inelastic buckling of longitudinal rebars. For this reason, a uniaxial local stress‐strain constitutive relation for steel rebars is developed, which is based on a combined nonlinear kinematic and isotropic hardening law. The proposed constitutive model is validated on the basis of existing experimental data and the formulation of the buckling model for a single rebar is developed. The cross section of rebar is discretized into fibers, each one following the derived stress‐strain uniaxial law. The buckling curve is determined analytically, while equilibrium is imposed at the deformed configuration. The proposed models for concrete and rebars are embedded into a properly adjusted fiber beam‐column element of reinforced concrete members and the proposed formulation is verified with existing experimental data under intensive cyclic loading. 相似文献
8.
Ching-Yi Tsai Keh-Chyuan Tsai Chao-Hsien Li Chung-Che Wu Ker-Chun Lin Sheng-Jhih Jhuang 《地震工程与结构动力学》2020,49(13):1344-1362
Steel box columns are widely used in steel building structures in Taiwan due to their dual strong axes. To transfer the beam-end moment to the column, diaphragm plates of the same thickness and elevations as the beam flanges are usually welded inside the box column. The electro-slag welding (ESW) process is widely used to connect the diaphragms to the column flanges in Taiwan because of its convenience and efficiency. However, ESW may increase the hardness of the welds and heat-affected zones (HAZs), while reducing the Charpy-V notch strength in the HAZ. This situation can cause premature fracture of the diaphragm-to-column flange welds before a large plastic rotation is developed in the beam-to-box column joints. To quantify the critical eccentricity and the effectiveness of fracture prediction, this study uses fracture prediction models and finite element model (FEM) analysis to correlate the test results. In this study, two beam-to-box column connection subassembly tests are conducted with different loading protocols and ESW chamber shapes. To implement a fracture prediction model, the material parameters are established from circumferential notched tensile tests and FEM analysis. Test results indicate that the fracture instances can be predicted on the basis of the cumulative plastic deformation in the HAZs. Analytical results indicate that fracture instances and locations are sensitive to the relative locations of the ESW joints and beam flange. Tests also confirm that the possible fracture of the diaphragm-to-column flange joints can be mitigated by enlarging the chamber of the ESW joint. 相似文献
9.
Wave Energy Converters (WECs) have excellent potential as a source of renewable energy that is yet to be commercially realised. Recent attention has focused on the installation of Oscillating Water Column (OWC) devices as a part of harbor walls to provide advantages of cost–sharing structures and proximity of power generation facilities to existing infrastructure. In this paper, an incompressible three–dimensional CFD model is constructed to simulate a fixed Multi–Chamber OWC (MC–OWC) device. The CFD model is validated; the simulation results are found to be in good agreement with experimental results obtained from a scale physical model tested in a wave tank. The validated CFD model is then used for a benchmark study of 96 numerical tests. These investigate the effects of the PTO damping caused by the power take–off (PTO) system on device performance. The performance is assessed for a range of regular wave heights and periods. The results demonstrate that a PTO system with an intermediate damping can be used for all chambers in the MC–OWC device for most wave period ranges, except for the long wave periods. These require a higher PTO damping. An increased incident wave height reduces the device capture width ratio, but there is a noticeable improvement for long wave periods. 相似文献
10.
应用气相色谱-气体同位素质谱(GC-C-IRMS)分析正构烷烃单体碳同位素之前,需要对饱和烃样品中正构烷烃和异构烷烃进行预分离、富集,在预分离和富集过程中正构烷烃单体碳同位素是否发生分馏是高精度分析正构烷烃单体碳同位素比值(δ~(13)C)的关键。本文以正构烷烃混合溶液为对象,利用柱色谱、5■分子筛络合、环己烷-正戊烷混合溶剂两次洗脱,GC-C-IRMS分析正构烷烃单体碳同位素,研究前处理过程中正构烷烃单体碳同位素是否发生分馏。结果表明:使用柱色谱分离前后,多数正构烷烃单体碳同位素比值相差-0.2‰~0.2‰;当5■分子筛不完全络合时,未络合的正构烷烃单体碳同位素比值偏重约0.7‰,可能发生了微弱的碳同位素分馏,但并未影响洗脱后的正构烷烃单体碳同位素比值;使用环己烷-正戊烷混合溶剂洗脱前后,碳同位素比值相差-0.2‰~0.5‰,以同样方式洗脱第二次,获得的正构烷烃单体碳同位素比值与模拟样品相差-0.3‰~0.2‰。分析不同回收率(20%)正构烷烃的单体碳同位素比值,处理前后的差值基本在0.3‰以内,可见当正构烷烃回收率低至20%左右时,其单体碳同位素仍未发生明显分馏。柱色谱分离-5■分子筛络合-混合溶剂洗脱方法适用于回收率大于20%的正构烷烃单体碳同位素分析。 相似文献