Dissolved organic matter variations in coastal plain wetland watersheds: The integrated role of hydrological connectivity,land use,and seasonality          下载免费PDF全文

Jacob D. Hosen  Alec W. Armstrong  Margaret A. Palmer 《水文研究》2018,32(11):1664-1681

Dissolved organic matter (DOM) is integral to fluvial biogeochemical functions, and wetlands are broadly recognized as substantial sources of aromatic DOM to fluvial networks. Yet how land use change alters biogeochemical connectivity of upland wetlands to streams remains unclear. We studied depressional geographically isolated wetlands on the Delmarva Peninsula (USA) that are seasonally connected to downstream perennial waters via temporary channels. Composition and quantity of DOM from 4 forested, 4 agricultural, and 4 restored wetlands were assessed. Twenty perennial streams with watersheds containing wetlands were also sampled for DOM during times when surface connections were present versus absent. Perennial watersheds had varying amounts of forested wetland (0.4–82%) and agricultural (1–89%) cover. DOM was analysed with ultraviolet–visible spectroscopy, fluorescence spectroscopy, dissolved organic carbon (DOC) concentration, and bioassays. Forested wetlands exported more DOM that was more aromatic‐rich compared with agricultural and restored wetlands. DOM from the latter two could not be distinguished suggesting limited recovery of restored wetlands; DOM from both was more protein‐like than forested wetland DOM. Perennial streams with the highest wetland watershed cover had the highest DOC levels during all seasons; however, in fall and winter when temporary streams connect forested wetlands to perennial channels, perennial DOC concentrations peaked, and composition was linked to forested wetlands. In summer, when temporary stream connections were dry, perennial DOC concentrations were the lowest and protein‐like DOM levels the highest. Overall, DOC levels in perennial streams were linked to total wetland land cover, but the timing of peak fluxes of DOM was driven by wetland connectivity to perennial streams. Bioassays showed that DOM linked to wetlands was less available for microbial use than protein‐like DOM linked to agricultural land use. Together, this evidence indicates that geographically isolated wetlands have a significant impact on downstream water quality and ecosystem function mediated by temporary stream surface connections.  相似文献   

Tellurium,selenium and cobalt enrichment in Neoproterozoic black shales,Gwna Group,UK: Deep marine trace element enrichment during the Second Great Oxygenation Event          下载免费PDF全文

Joseph G. T. Armstrong  John Parnell  Liam A. Bullock  Magali Perez  Adrian J. Boyce  Jorg Feldmann 《地学学报》2018,30(3):244-253

Black shales of the late Neoproterozoic Gwna Group (570–580 Ma), UK, contain enrichments of tellurium (Te), selenium (Se) and cobalt (Co) relative to average shale compositions. The Te and Co enrichments bear comparison with those of ferromanganese crusts in the modern deep ocean. Gwna Group deposition coincides with the Second Great Oxidation Event, which had a significant effect on trace element fixation globally. Selenium and Te concentrations within these black shales indicate increased continental weathering rates, high biological productivity and corresponding increases in atmospheric O₂ concentrations. Cobalt, nickel (Ni) and arsenic (As) enrichments in this succession are secondary mineralisation phases. Demand for many of the trace elements found enriched in the Gwna Group black shales make their mechanisms of accumulation, and variations through the geological record, important to understand, and suggests that new resources may be sought based on black shale protoliths from this period.  相似文献   

Coal mining‐derived ochres in the UK: a potential selenium trap     

Liam A. Bullock  John Parnell  Magali Perez  Joseph G.T. Armstrong 《Geology Today》2019,35(4):140-145

Thanks to the pioneering research of Paul Younger over the past 20 years, acid mine drainage in the UK has been recognized as a major environmental issue. Acid mine drainage and hydrous ferric oxide deposition are environmental hazards resulting from centuries of extensive coal mining activities across the UK. Oxidative weathering of pyrite in coal from spoil heaps and exposed bedrock can liberate trace elements, releasing them into local water systems. In addition to posing an environmental threat through water and ground contamination, ochres can also act as a remediation material, trapping elements such as selenium. Trace elements with a close association to iron oxides, such as selenium, may fix to the fine‐grained ochre materials, resulting in hyper‐enriched ochres. Selenium in coals has been known to cause an environmental issue in areas of North America but is also an important commodity for solar cells and nanotechnologies. Coal‐bearing areas of the UK, such as Northumberland, are known to contain a high selenium content, and coal‐derived ochres in these regions also contain significant selenium. The widespread occurrence of ochres in UK coal‐mining regions may therefore present a unique ‘E tech’ trace element source and prevent a toxicity problem for which they were once thought to be responsible.  相似文献   

U–Pb SHRIMP data constraints on calc-alkaline granitoids with 1.3–1.6 Ga Nd TDM model ages from the central domain of the Borborema province,NE Brazil     

I.P. Guimarães  A.F. Silva Filho  C.N. Almeida  M.B. Macambira  R. Armstrong 《Journal of South American Earth Sciences》2011,31(4):383-396

The Tabira, Itapetim and Timbaúba granitoids are intruded into metasedimentary sequences and Cariris Velhos (Tonian) orthogneisses from the Central Domain of the Borborema Province, NE Brazil. They have U–Pb SHRIMP ages of 593 ± 7 Ma; 615 ± 9 Ma and 616 ± 5 Ma respectively. The studied granitoids have zircon cores inherited from the protholith, with a large number of analyses showing ²⁰⁶Pb/²³⁸U ages ranging from 950 to 1200 Ma. Oscillatory zoning typical of magmatic zircon is common, although it is faint in some inherited cores.The studied granitoids are calc-alkaline and show Nd T_DM model ages ranging from 1.30 to 1.56 Ga and ?Nd (600 Ma) ranging from ?2.40 to ?5.34. These values are similar to those recorded in the country rocks. The lowest values of ?Nd (600 Ma) were recorded in enclaves of dioritic composition. Nd and U–Pb SHRIMP data suggest a significant participation of the metasedimentary rocks in the protholith of these granitoids. The Mesoproterozoic Nd T_DM model ages recorded in the studied granitoids are interpreted as the result of a hybrid source involving melting of metagraywackes, metamafic rocks of Tonian ages and/or biotite – bearing orthogneisses (Cariris Velhos Orthogneisses). The resulted melting was modified by mingling with juvenile Brasiliano melts, diorite in composition.The Timbaúba granitoids intrusions are coeval with high-T metamorphism and flat-lying foliation forming event in an intracontinental setting, during the Brasiliano convergence and contractional deformation. The Itapetim Pluton was emplaced in the convergence - lateral escape setting and the Tabira granitoids were intruded after the flat-lying foliation event, representing sin transcurrent intrusions.Our data show that within the Central Domain of the Borborema Province, granitoids with similar petrographic and geochemical compositions can have distinct ages and be intruded in distinct tectonic regimes.  相似文献   

Best practices for the use of meteorite names in publications     

Philipp R. Heck  Christopher Herd  Jeffrey N. Grossman  Dmitry Badjukov  Audrey Bouvier  Emma Bullock  Hasnaa Chennaoui‐Aoudjehane  Vinciane Debaille  Tasha L. Dunn  Denton S. Ebel  Ludovic Ferrire  Laurence Garvie  Jrme Gattacceca  Matthieu Gounelle  Richard Herd  Trevor Ireland  Emmanuel Jacquet  Robert J. Macke  Tim McCoy  Francis M. McCubbin  Takashi Mikouchi  Knut Metzler  Mathieu Roskosz  Caroline Smith  Meenakshi Wadhwa  Linda Welzenbach‐Fries  Toru Yada  Akira Yamaguchi  Ryan A. Zeigler  Michael Zolensky 《Meteoritics & planetary science》2019,54(7):1397-1400

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Mud volcanoes and evaporite seismites in a tidal flat of northern Kuwait—implications for fluid flow in sabkhas of the Persian (Arabian) Gulf     

Michael J. Duane  Linda Reinink-Smith  Christopher Eastoe  Ali T. Al-Mishwat 《Geo-Marine Letters》2015,35(3):237-246

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Predicting small business demise after a natural disaster: an analysis of pre-existing conditions     

Maria I. Marshall  Linda S. Niehm  Sandra B. Sydnor  Holly L. Schrank 《Natural Hazards》2015,79(1):331-354

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Stratigraphy of the Triassic?Jurassic Boundary Successions of the Southern Margin of the Junggar Basin, Northwestern China   总被引：2，自引：1，他引：1  

SHA Jingeng  Vivi VAJDA  PAN Yanhong  Linda LARSSON  YAO Xiaogang  ZHANG Xiaolin  WANG Yaqiong  CHENG Xiansheng  JIANG Baoyu  DENG Shenghui  CHEN Siwei  PENG Bo 《《地质学报》英文版》2011,85(2):421-436

The Triassic?Jurassic (Tr?J) boundary marks a major extinction event, which (~200 Ma) resulted in global extinctions of fauna and flora both in the marine and terrestrial realms. There prevail great challenges in determining the exact location of the terrestrial Tr?J boundary, because of endemism of taxa and the scarcity of fossils in terrestrial settings leading to difficulties in linking marine and terrestrial sedimentary successions. Investigation based on palynology and bivalves has been carried out over a 1113 m thick section, which is subdivided into 132 beds, along the Haojiagou valley on the southern margin of the Junggar Basin of the northern Xinjiang, northwestern China. The terrestrial Lower Jurassic is conformably resting on the Upper Triassic strata. The Upper Triassic covers the Huangshanjie Formation overlaid by the Haojiagou Formation, while the Lower Jurassic comprises the Badaowan Formation followed by the Sangonghe Formation. Fifty six pollen and spore taxa and one algal taxon were identified from the sediments. Based on the key-species and abundance of spores and pollen, three zones were erected: the Late Triassic (Rhaetian) Aratrisporites?Alisporites Assemblage, the Early Jurassic (Hettangian) Perinopollenites?Pinuspollenites Assemblage, and the Sinemurian Perinopollenites?Cycadopites Assemblage. The Tr?J boundary is placed between bed 44 and 45 coincident with the boundary between the Haojiagou and Badaowan formations. Beds with Ferganoconcha (?), Unio?Ferganoconcha and Waagenoperna?Yananoconcha bivalve assemblages are recognized. The Ferganoconcha (?) bed is limited to the upper Haojiagou Formation, Unio?Ferganoconcha and Waagenoperna?Yananoconcha assemblages are present in the middle and upper members of the Badaowan Formation. The sedimentary succession is interpreted as terrestrial with two mainly lake deposit intervals within Haojiagou and Badaowan formations, yielding fresh water algae and bivalves. However, the presence of brackish water algae Tasmanites and the marine?littoral facies bivalve Waagenoperna from the Badaowan Formation indicate that the Junggar Basin was influenced by sea water caused by transgressions from the northern Tethys, during the Sinemurian.  相似文献   

A study of arsenic,iron and other dissolved ion variations in the groundwater of Bishnupur District,Manipur, India   总被引：1，自引：1，他引：0  

Jayalakshmi Devi Oinam  AL. Ramanathan  Anurag Linda  Gurmeet Singh 《Environmental Earth Sciences》2011,62(6):1183-1195

The presence of arsenic (As) in groundwater and its effect on human health has become an issue of serious concern in recent years. The present study assessed the groundwater quality of the Bishnupur District, Manipur, with respect to drinking water standards. Higher concentrations of pH, iron and phosphate were observed at several locations. Phosphate and iron levels were highest in the pre-monsoon, followed by monsoon and post-monsoon seasons. The arsenic concentrations were highest during post-monsoon (1–200 μg L⁻¹) as compared to pre-monsoon (1–108 μg L⁻¹) and monsoon (2–99 μg L⁻¹). Kwakta and Ngakhalawai show higher levels of arsenic concentration as compared to the prescribed World Health Organization (WHO) and Bureau of Indian Standards (BIS) norms. Arsenic showed a strong positive correlation with phosphate and negative correlation with sulphate, suggesting a partial influence of anthropogenic sources. The study suggests that the Bishnupur area has an arsenic contamination problem, which is expected to increase in the near future.  相似文献   

Swashed away? Storm impacts on sandy beach macrofaunal communities     

Linda Harris  Ronel Nel  David Schoeman 《Estuarine, Coastal and Shelf Science》2011,94(3):210-221

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