The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K2O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ41K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K2O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ41K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K2O content and K isotope compositions (0.02–0.05 wt%; δ41K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation. 相似文献
Subsurface dams are rather effective and used for the prevention of saltwater intrusion in coastal regions around the world. We carried out the laboratory experiments to investigate the elevation of saltwater wedge after the construction of subsurface dams. The elevation of saltwater wedge refers to the upward movement of the downstream saltwater wedge because the subsurface dams obstruct the regional groundwater flow and reduce the freshwater discharge. Consequently, the saltwater wedge cannot further extend in the longitudinal direction but rises in the vertical profile resulting in significant downstream aquifer salinization. In order to quantitatively address this issue, field-scale numerical simulations were conducted to explore the influence of various dam heights, distances, and hydraulic gradients on the elevation of saltwater wedge. Our investigation shows that the upward movement of the saltwater wedge and its areal extension in the vertical domain of the downstream aquifer become more severe with a higher dam and performed a great dependence on the freshwater discharge. Furthermore, the increase of the hydraulic gradient and the dam distance from the sea boundary leads to a more pronounced wedge elevation. This phenomenon comes from the variation of the freshwater discharge due to the modification of dam height, location, and hydraulic gradient. Large freshwater discharge can generate greater repulsive force to restrain the elevation of saltwater wedge. These conclusions provide theoretical references for the behaviour of the freshwater–seawater interface after the construction of subsurface dams and help optimize the design strategy to better utilize the coastal groundwater resources. 相似文献
ABSTRACT Pedestrian networks play an important role in various applications, such as pedestrian navigation services and mobility modeling. This paper presents a novel method to extract pedestrian networks from crowdsourced tracking data based on a two-layer framework. This framework includes a walking pattern classification layer and a pedestrian network generation layer. In the first layer, we propose a multi-scale fractal dimension (MFD) algorithm in order to recognize the two different types of walking patterns: walking with a clear destination (WCD) or walking without a clear destination (WOCD). In the second layer, we generate the pedestrian network by combining the pedestrian regions and pedestrian paths. The pedestrian regions are extracted based on a modified connected component analysis (CCA) algorithm from the WOCD traces. We generate the pedestrian paths using a kernel density estimation (KDE)-based point clustering algorithm from the WCD traces. The pedestrian network generation results using two actual crowdsourced datasets show that the proposed method has good performance in both geometrical correctness and topological correctness. 相似文献
The transfer and evolution of stress among rock blocks directly change the void ratios of crushed rock masses and affect the flow of methane in coal mine gobs. In this study, a Lagrange framework and a discrete element method, along with the soft-sphere model and EDEM numerical software, were used. The compaction processes of rock blocks with diameters of 0.6, 0.8, and 1.0 m were simulated with the degrees of compression set at 0%, 5%, 10%, 15%, 20%, and 25%. This study examines the influence of stress on void ratios of compacted crushed rock masses in coal mine gobs. The results showed that stress was mainly transmitted downward through strong force chains. As the degree of compression increased, the strong force chains extended downward, which resulted in the stress at the upper rock mass to become significantly higher than that at the lower rock mass. It was determined that under different degrees of compression, the rock mass of coal mine gobs could be divided, from the bottom to the top, into a lower insufficient compression zone (ICZ) and an upper sufficient compression zone (SCZ). From bottom to top, the void ratios in the ICZ sharply decreased and those in the SCZ slowly decreased. Void ratios in the ICZ were 1.2–1.7 times higher than those in the SCZ.
High concentrations of calcite fossil granules produced by earthworms (ECG) have been identified in most of the stratigraphical units along the loess‐palaeosol reference sequence of Nussloch (Germany). They are particularly abundant in interstadial brown soils and in tundra gley horizons, the latter reflecting short‐term phases of aggradation then degradation of permafrost. These granules are characterized by a radial crystalline structure produced in the earthworms by specific bio‐mineralization processes. In our study, we used this biological indicator combined with 14C and OSL dating, and sedimentological parameters to characterize millennial‐time scale climatic variations recorded in loess sequences. The approach is based on high‐resolution counts of ECG throughout a 17‐m‐thick loess sequence (332 samples). Strong increases in granule and mollusc concentrations suggest warmer climate conditions during palaeosol formation phases, associated with increasing biodiversity, biological activity and vegetation cover. Decreased granule concentrations occur within primary loess deposits, indicating a strong correlation with palaeoenvironmental conditions and demonstrating the reliability of ECG concentration variations as a new palaeoenvironmental proxy. Finally, this pattern is also recorded in loess sequences located about 600 km westward in northern France demonstrating the large‐scale validity of this new palaeoclimatic proxy. 相似文献
Based on the high abundance of fine‐grained material and its dark appearance, NWA 11024 was recognized as a CM chondrite, which is also confirmed by oxygen isotope measurements. But contrary to known CM chondrites, the typical phases indicating aqueous alteration (e.g., phyllosilicates, carbonates) are missing. Using multiple analytical techniques, this study reveals the differences and similarities to known CM chondrites and will discuss the possibility that NWA 11024 is the first type 3 CM chondrite. During the investigation, two texturally apparent tochilinite–cronstedtite intergrowths were identified within two thin sections. However, the former phyllosilicates were recrystallized to Fe‐rich olivine during a heating event without changing the textural appearance. A peak temperature of 400–600 °C is estimated, which is not high enough to destroy or recrystallize calcite grains. Thus, calcites were never constituents of the mineral paragenesis. Another remarkable feature of NWA 11024 is the occurrence of unknown clot‐like inclusions (UCLIs) within fine‐grained rims, which are unique in this clarity. Their density and S concentration are significantly higher than of the surrounding fine‐grained rim and UCLIs can be seen as primary objects that were not formed by secondary alteration processes inside the rims. Similarities to chondritic and cometary interplanetary dust particles suggest an ice‐rich first‐generation planetesimal for their origin. In the earliest evolution, NWA 11024 experienced the lowest degree of aqueous alteration of all known CM chondrites and subsequently, a heating event dehydrated the sample. We suggest to classify the meteorite NWA 11024 as the first type 3 CM chondrite similar to the classification of CV3 chondrites (like Allende) that could also have lost their matrix phyllosilicates by thermal dehydration. 相似文献