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1.
本文研究并建立了海水中测定砷形态的液相色谱—原子荧光法,进行了实验参数流动相浓度、pH、流速的优化。在优化的实验条件下,采用Hamilton PRP-X100分析柱在6 min内可以完成三价砷、甲基砷和五价砷3种形态的分离、检测。在载流5%HCl,还原剂2%KBH4和0.5%KOH,进样量100μL条件下,三价砷、甲基砷和五价砷检出限分别为0.31μg/L、0.52μg/L和0.36μg/L。在浓度2~80μg/L范围内,3种砷形态均有良好的线性关系,相关系数均优于0.999。用本文所建立的方法进行了海水样品中无机砷和有机砷形态的测试,海水中三价砷、甲基砷的含量较低,五价砷稍高,说明海水中砷形态主要以五价砷存在,当加标量为5~10μg/L时,加标回收率在73%~104%之间。该方法操作前处理简单,灵敏度高、运行费用低廉,适用于海水中砷形态的测试。 相似文献
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This work evaluates the application potential of a new indigenous aerobic denitrifi er, strain Pseudomonas CW-2, isolated from a largemouth bass culture pond. The rate of ammonium-N removal by strain CW-2 was approximately 97% at a DO concentration of 5.2 mg/L. Furthermore, when nitrate and ammonia coexisted, the strain gave priority to assimilating ammonia, and thereafter to denitrifi cation. Under optimal cultivation conditions, citrate and acetate were the carbon resources, C/N was 8, dissolved oxygen was 5.2 mg/L, and pH was 7; the removal rate of ammonium reached nearly 90%. The changing patterns of different bacteria in strain CW-2-treated and the control pond water were also compared. Lower levels of ammonia, nitrite, and phosphates were observed in the treated water as compared with the controls. Meanwhile, phylum-level distributions of the bacterial OTUs revealed that P roteobacteria, Bacteroidetes, Planctomycetes, and N itrospirae continuously changed their relative abundances in relation to carbon and the addition of strain CW-2; this finding implies that the conventional denitrifi cation process was weakened under the ef fects of carbon or the presence of strain CW-2. We propose that strain CW-2 is a promising organism for the removal of ammonium in intensive fish culture systems, according to our evaluations of its denitrifi cation performance. 相似文献
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This study is focused on the northwestern part of Gansu Province, namely the Hexi Corridor. The aim is to address the question of whether any trend in the annual and monthly series of temperature and precipitation during the period 1955-2011 appears at the scale of this region. The temperature and precipitation variation and abrupt change were examined by means of linear regression, five-year moving average, non-parameter Mann-Kendall test, accumulated variance analysis and Pettitt test method. Conclusions provide evidence of warming and wetting across the Hexi Corridor. The mean annual temperature in Hexi Corridor increased significantly in recent 57 years, and the increasing rate was 0.27℃/10a. The abrupt change phenomenon of the annual temperature was detected mainly in 1986. The seasonal average temperature in this region exhibited an evident upward trend and the uptrend rate for the standard value of winter temperature indicated the largerst of four seasons. The annual precipitation in the Hexi Corridor area displayed an obviously increasing trend and the uptrend rate was 3.95 mm/10a. However, the annual precipitation in each basin of the Hexi Corridor area did not passed the significance test. The rainy season precipitation fluctuating as same as the annual one presented insignificant uptrend. No consistent abrupt change was detected in precipitation in this study area, but the rainy season precipitation abrupt change was mainly observed in 1968. 相似文献
4.
基于离散元法的节理岩体边坡稳定性分析 总被引:9,自引:0,他引:9
节理岩体边坡的稳定性在很大程度上取决于节理的强度及其分布形式。由于节理岩体边坡的失稳破坏具有大变形和非连续的特点,因此,离散单元法成为研究节理岩体边坡破坏机制的最有效方法之一。通过采用离散元软件PFC2D进行数值模拟,对完整岩石及节理的力学性能进行研究,并建立含密集节理的岩体边坡模型,讨论了节理连通率对边坡破坏形式的影响。结果表明,节理岩体边坡的失稳破坏是一个渐进的过程;在多组节理密集分布的岩体边坡中,连通率越大,其稳定性越差;随着连通率的减小,边坡的破坏形式由大范围的滑坡转变为局部崩塌的形式 相似文献
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西金河铁矿赋存于五台群台怀亚群柏枝岩组中下部磁铁石英岩中,属火山沉积变质硅铁建造铁矿床。本区通过物探、槽探、钻探、样品测试等手段,大致查明了该区铁矿的矿体特征、矿石质量、矿石自然类型。本文根据我院长期在本区开展地质找矿取得的勘查成果,进行系统总结,提出下一步找矿方向。 相似文献
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文章评估了黄河三角洲邻近海域的生态系统服务价值,并揭示了其空间分布特征。结果表明,2008年和2013年黄河三角洲邻近海域生态系统服务价值分别为79.70亿元和149.35亿元,生态系统服务利用属于供给服务和文化服务共同主导的综合开发利用类型。黄河入海口邻近海域为服务价值最高值区。2008—2013年间,养殖生产、捕捞生产和休闲娱乐3项服务价值变动较大。建议在黄河三角洲邻近海域调整养殖结构,大力发展高附加值品种养殖;持续开展增殖放流,提高捕捞生产价值;进一步开发利用旅游资源,提高休闲娱乐价值。 相似文献
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西金河铁矿赋存于五台群台怀亚群柏枝岩组中下部磁铁石英岩中,属火山沉积变质硅铁建造铁矿床。本区通过物探、槽探、钻探、样品测试等手段,大致查明了该区铁矿的矿体特征、矿石质量、矿石自然类型。本文根据我院长期在本区开展地质找矿取得的勘查成果,进行系统总结,提出下一步找矿方向。 相似文献
9.
本文研究并建立了海水中测定砷形态的液相色谱—原子荧光法。进行了实验参数流动相浓度、pH、流速的优化。在优化的实验条件下,采用Hamilton PRP-X100分析柱在6 min内可以完成三价砷、甲基砷和五价砷3种形态的分离、检测。在载流5% HCl,还原剂2% KBH4、0.5% KOH,进样量100 μL的条件下,三价砷、甲基砷和五价砷的检出限分别为0.31 μg/L、0.52 μg/L和0.36 μg/L。在浓度2~80 μg/L范围内,3种砷形态均有良好的线性关系,相关系数均优于0.999。用本文所建立的方法进行了海水样品中无机砷和有机砷形态的测试,海水中三价砷、甲基砷的含量较低,五价砷稍高,说明海水中砷形态主要以五价砷存在,当加标量为5~10 μg/L,加标回收率在73%~104%之间。该方法操作前处理简单,灵敏度高、运行费用低廉,适用于海水中砷形态的测试。 相似文献
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