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1.
西藏冈底斯斑岩铜矿带含矿岩体的相对氧化状态:来自锆石Ce(Ⅳ)/Ce(Ⅲ)比值的约束 总被引：3，自引：0，他引：3
对西藏冈底斯斑岩铜矿带三个斑岩铜矿床含矿斑岩进行了锆石与全岩的微量元素分析,通过理论计算获得三个矿床含矿斑岩的锆石Ce(Ⅳ)/Ce(Ⅲ)比值和δEu值:拉抗俄矿床为492.25和0.5341,冲江矿床为263.83和0.4353,南木矿床为291.94和0.5273.认为锆石Ce(Ⅳ)/Ce(Ⅲ)比值>260,δEu>0.4是斑岩成矿的地球化学标志.冈底斯斑岩铜矿带的锆石Ce(Ⅳ)/Ce(Ⅲ)比值自东向西呈递减趋势,指示岩浆在上升侵位过程中东部较西部受到更大程度的上部地壳物质的混染.冈底斯斑岩铜矿带的矿化机理可表述为:深部岩浆在上升侵位过程中受到上部地壳物质的混染,使岩浆的氧逸度增加,在随后的结晶分异过程中产生高Cu、Au浓度的岩浆热液流体,并在继续上升的过程中,随着压力、温度的降低,在适当的条件下发生了成岩成矿作用. 相似文献
2.
卡特巴阿苏大型金矿床位于新疆西天山中部那拉提北缘断裂带南侧,找矿前景较好。为查明矿区容矿岩浆岩的成因及其与矿床形成的联系,对主要矿石类型含金蚀变二长花岗岩和含金石英硫化物脉进行LA-MC-ICP-MS锆石U-Pb测年和地球化学研究。结果表明,锆石稀土元素显示较陡的左倾配分模式,具有明显的正Ce异常和负Eu异常,指示岩浆锆石成因。根据锆石Ce异常值,获得含矿岩石有关岩浆岩氧逸度对数值(Log(fo_2))为-29.2～5.1,指示岩浆具有较高的氧逸度,有利于金在岩体中初步富集。同时,氧逸度具有较大的变化范围,指示岩浆演化过程中,存在明显的上地壳混染。应用锆石Ti温度计,获得含金蚀变二长花岗岩锆石结晶温度为765～975℃,反映岩浆来自下地壳缺水条件下的部分熔融。含金石英硫化物脉锆石具有较低的结晶温度(641～823℃),可能与早期角闪石的分异结晶有关。以上2种矿石类型的锆石U-Pb年龄分别为350.4±1.6Ma和348.9±1.4Ma,代表了容矿二长花岗岩的结晶年龄。岩体结晶年龄早于前人报道的矿床成矿年龄,表明岩体侵位与成矿作用无直接关系。 相似文献
3.
四会岩体:一个潜在的含钼铜矿化岩体 总被引：1，自引：0，他引：1
四会岩体位于广东省四会市境内,主要由黑云母花岗岩、白云母花岗岩和钾长花岗岩组成。在全岩主、微量元素分析的基础上,对采自该岩体的黑云母花岗岩进行了微区原位LA-ICP-MS锆石微量元素分析和U-Pb定年。CL图像显示这些锆石自形,具有明显的岩浆生长环带,个别有暗色的核。获得了20个有效的206Pb/238U年龄,年龄范围从161~1069Ma。锆石微量元素分析显示这些锆石样品具有高的Th、U和REE含量,明显富集HREE,其Th/U比值普遍高于0.4,表明这些锆石属于岩浆成因。其中年龄最新的一组共10个点比较集中,206Pb/238Pb加权平均年龄为166.6±2.9Ma,代表岩体的成岩时代;其余较老的10个年龄数据比较分散,代表捕获锆石信息。同时这些锆石的Ce(Ⅳ)/Ce(Ⅲ)值为146~681,平均为441,表明形成该岩体的岩浆具有较高的氧逸度;Eu/Eu*值为0.41~0.60,明显高于一般不含矿的岩体(0.4)。将四会岩体锆石Ce(Ⅳ)/Ce(Ⅲ)和Eu/Eu*与邻区粤北大宝山含矿斑岩中锆石(Ce(Ⅳ)/Ce(Ⅲ)=13.9~414;Eu/Eu*=0.14~0.70)进行对比,发现两个参数都比较一致。综合分析表明,四会岩体可能是一个潜在的具有铜钼矿成矿潜力的含矿岩体。 相似文献
4.
西藏冈底斯矿带南缘矽卡岩型铜矿床含矿岩体锆石U-Pb年龄及意义 总被引：11，自引：4，他引：7
西藏冈底斯矿带发育大量斑岩铜钼矿床及铜铅锌多金属矿床,形成斑岩铜矿带及多金属矿带。过去的工作表明,冈底斯带南部矿床同位素年龄多小于30Ma,形成于碰撞期后伸展环境。本文测定了冈底斯矿带南缘克鲁-冲木达矽卡岩型铜(金、钼)矿集区桑布加拉矽卡岩型铜(金)矿化岩体锆石LA-ICP-MSU-Pb年龄及锆石Ce4+/Ce3+比值。矿化岩体锆石U-Pb年龄:92.1±0.6Ma,MSWD=1.0,锆石Ce4+/Ce3+比值在90～562之间,平均值为287。锆石Ce4+/Ce3+比值和玉龙矿带含矿岩体锆石的比值基本一致,显示矽卡岩矿化岩体岩浆氧逸度较高。印度板块与欧亚板块碰撞时间在65～45Ma之间,桑布加拉矽卡岩型铜矿化岩体锆石U-Pb年龄表明冈底斯带不但发育碰撞期后大规模成矿作用,也发育与洋壳俯冲构造岩浆事件有关的成矿作用。这为冈底斯矿带洋壳俯冲有关矿床的寻找提供了依据。 相似文献
5.
《地质学报》2020,(8)
包古图斑岩铜矿位于新疆西准噶尔地区,是区内规模最大的斑岩型矿床,成矿作用与晚石炭世中酸性侵入体密切相关。Ⅲ-2岩体位于矿区南部,该岩体全岩矿化,但品位较低,是探讨成矿岩浆性质的理想对象。本文结合岩石学和角闪石、锆石等矿物成分分析,通过与典型斑岩铜矿进行对比,探讨了成矿岩浆的氧逸度。研究表明,包古图Ⅲ-2岩体以石英闪长(玢)岩和闪长岩为主,少量辉石闪长岩,主要由斜长石、角闪石、黑云母、石英和钾长石组成,含少量钛铁矿、榍石和磷灰石。石英闪长岩中早期结晶的自形角闪石属于钙质闪石,Mg~#较高(0.72～1.00),成分分析指示成矿岩浆的氧逸度为:△NNO+1.4～△NNO+2.6,位于斑岩铜矿含矿岩体的分布范围。从中分选出的锆石REE含量高(338×10~(-6)～959×10~(-6)),具有左倾型稀土配分模式,轻稀土亏损,重稀土富集,显示强烈Ce正异常和Eu负异常。Ce~(4+)/Ce~(3+)比值为29.55～89.50,Eu/Eu~*比值为0.32～0.47,分布于斑岩铜矿含矿岩体和未矿化岩体的叠加部位。研究结果显示,包古图斑岩铜矿Ⅲ-2岩体成矿岩浆氧逸度较高,有利于成矿元素的溶解和迁移,对斑岩铜矿的形成有促进作用。 相似文献
6.
甘肃天水三叠纪太阳山斑岩铜钼矿床位于西秦岭造山带东段。矿体主要赋存于石英闪长斑岩、二长斑岩、石英二长斑岩和泥盆系大草滩群。氧逸度是表征岩石物理化学性质的重要参数,对岩浆热液成矿具有明显的控制作用。在综合评述常用氧逸度计算方法及适用性的前提下,文中应用激光剥蚀等离子质谱分析方法对太阳山矿床含矿岩体锆石微量元素进行测定,选用含量较高的Sm、Nd进行Ce异常计算,查明含矿斑岩岩浆氧逸度,探讨其成矿意义。太阳山矿床岩浆氧逸度计算结果表明,太阳山成矿二长斑岩和石英二长斑岩相对氧逸度ΔFMQ分别为+3.04和+3.15,成矿前石英闪长斑岩相对氧逸度ΔFMQ为-1.83,成矿岩体氧逸度明显高于成矿前岩体。成矿岩体岩浆氧逸度高于成矿前岩体的原因可能与富集地幔有关。富集岩石圈地幔的加入,带来了大量的硫和金属铜,并提高了岩浆氧逸度。 相似文献
7.
凹山铁矿床是玢岩铁矿床的典型代表之一,矿床中发育有辉石闪长玢岩和花岗闪长斑岩两类侵入岩。锆石微量元素分析结果显示,两类岩浆岩中锆石的稀土元素配分模型相似,花岗闪长斑岩中的锆石较辉石闪长玢岩中锆石具有较高的U含量,较高的U/Yb比值以及相似的Yb、Hf和Y含量,结合前人的研究认为,两者的源区具有一致性,均源于富集地幔,并在其上涌就位过程中混染了壳源物质,其中花岗闪长斑岩混染了更多的壳源物质。花岗闪长斑岩中锆石的Ce(Ⅳ)/Ce(Ⅲ)比值集中于0～100,远低于斑岩铜矿成矿岩体Ce(Ⅳ)/Ce(Ⅲ)>300的特征,具有较弱的形成斑岩型铜金矿的特征,但在宁芜地区发育的这类花岗闪长斑岩是否具有形成铜金矿化的潜力仍需进一步的研究和勘查。 相似文献
8.
右江褶皱带东南缘西大明山矿集区燕山期长英质岩浆锆石SHRIMP原位氧同位素组成与地质意义 总被引：1，自引：1，他引：0
右江褶皱带晚白垩世岩浆岩的物质来源和成因机制及其相关的大规模Sn-W多金属成矿作用是目前研究的热点和前沿问题之一。本文在已获得锆石U-Pb年龄及Hf同位素基础上,对广西西大明山地区酸性岩浆进行了锆石SHRIMP氧同位素研究。石英斑岩δ~(18)O_(Zrn)值为5.31‰~9.31‰(平均值为7.61±2.17‰)、绢英岩化黑云母花岗岩δ~(18)O_(Zrn)值为7.11‰~9.79‰(平均值为8.36±1.33‰)、细粒黑云母花岗岩δ~(18)O_(Zrn)值为5.06‰~9.27‰(平均值为7.73±2.23‰)、中粒黑云母花岗岩δ~(18)O_(Zrn)值为5.06‰~9.27‰(平均值为7.73±2.23‰)二长花岗岩δ~(18)O_(Zrn)值为5.48‰~10.99‰(平均值为7.55±2.77‰)。测试结果显示广西西大明山地区酸性岩浆锆石氧同位素普遍具有双峰式分布特征且Hf-O同位素组成构成负相关性,暗示地壳组份和富集地幔两端元混合的特征。Hf-O同位素特征指示酸性岩浆岩源主要来自古老的地壳,并混有部分幔源物质。地幔物质的存在暗示了同时期来自地幔的物质不仅参与右江褶皱带晚白垩世岩浆作用的形成,可能为的地壳部分熔融,花岗岩岩浆的形成提供了热能。西大明山地区酸性岩浆具有高δ~(18)O_(Zrn)值和低ε_(Hf)(t)值且低Ce(Ⅳ)/Ce(Ⅲ)比值(即低氧逸度),显示出有利于形成大型以Pb-Zn为主的矽卡岩型矿床特征。本文研究结果表明,锆石O-Hf同位素综合研究能限定幔源岩浆参与花岗岩形成中的作用能帮助更加准确的限定岩浆源区。同时锆石氧同位素可以作为成矿规律研究的有效途径之一。 相似文献
9.
皖南泾县榔桥岩体锆石U-Pb定年、Hf同位素和地球化学特征及其找矿指示意义 总被引：7，自引：0，他引：7
安徽泾县榔桥花岗闪长岩体为分布于皖南台褶带北缘壳幔同熔型复式岩体。该岩体主侵入期两个花岗闪长岩样品和侵入后期脉岩一个花岗斑岩样品的锆石U-Pb年龄分别为135.6±1.8Ma,137.6±2.0Ma,136.4±1.9Ma,显示岩体形成于早白垩世。锆石Hf同位素分析表明榔桥岩体可能由中元古代地壳物质部分熔融形成,同时混染有少量古元古代地壳物质。根据全岩Zr含量计算出榔桥岩体花岗闪长岩"锆石饱和温度"为749~781℃,脉岩花岗斑岩"锆石饱和温度"为722~745℃,指示岩浆在成岩过程中快速冷却;元素地球化学研究显示,本区岩石在成岩过程中发生斜长石、钾长石以及副矿物磷灰石、钛铁矿的分离结晶作用。锆石Ce(Ⅳ)/Ce(Ⅲ)比值计算表明榔桥岩体成岩过程中的高氧逸度有利于该区域发生Cu-Au矿化,而斜长石的分离结晶使得EuN/EuN*比值降低,为0.2~0.4。榔桥岩体具有富集大离子亲石元素以及Pb,亏损高场强元素(Nb、Ta、Zr,Ti),以及轻重稀土发生明显的分异,轻稀土相对重稀土明显富集的特征,与岛弧岩浆岩类似;大地构造背景判别表明该岩体的形成与古太平洋板块对欧亚大陆的俯冲碰撞作用密切相关。 相似文献
10.
11.
奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
12.
Xiaoyu ZHAO Wuyi WANG Hairong LI Fujian FENG Lizhen WANG 《中国地球化学学报》2006,25(B08):80-81
Brick-tea-type fluorosis is a peculiar endemic disease in China, which had been discovered in minority areas of western China since 1980, and distributed mainly in Tibet, Inner Mongolia, Gansu, Xinjiang, Qinghai and parts of Sichuan Province. The prevalence rate of fluorosis in Tibetan and Mongolian nationality people was higher. Epidemiological investigation showed that fluorosis morbidity and degrees were different in different brick-tea drinking areas, and it was probably caused by drinking various kinds of brick tea from different regions. Therefore, we collected 33 samples of brick tea from six provinces where minority nationalities were accustomed to drinking a large quantity of brick tea. F concentrations were determined by the combustion hydrolysis-ion selective electrode method. The results showed that among the brick teas, the F concentrations ranged from the minimum 74.1 mg/kg in Yunnan Province to the maximum 991.2 mg/kg in Sichuan Province. Besides, there was a great difference among the various kinds of brick tea, and F concentrations decreased in the order of Kang brick tea, Green brick tea, Black brick tea, Mi brick tea, Fu brick tea, Chitsu ping tea, Puerh tea, and Tuo tea. The average F concentration in brick teas was 431.92 mg/kg. 相似文献
13.
A catastrophic rockslide-debris flow in Wulong, Chongqing, China in 2009: background, characterization, and causes 总被引：7，自引：3，他引：4
Qiang Xu Xuanmei Fan Runqiu Huang Yueping Yin Shengshan Hou Xiujun Dong Minggao Tang 《Landslides》2010,7(1):75-87
On June 5, 2009, a catastrophic rockslide-debris flow occurred at the crest of the Jiweishan Mountain in Wulong, Chongqing,
China. Approximately five million cubic meters of limestone blocks slid along a weak interlayer of bituminous and carbonaceous
shale. The source mass descended from the upper part of the slope rapidly, crossing a 200-m wide and 50-m deep creek in front
of it. Blocked by the opposite steep creek wall, the sliding mass changed its direction and traveled a further 2.2 km along
the creek in debris-flow mode, finally forming a large accumulation zone with an average depth of 30 m. This is one of the
most catastrophic rockslide events in recent years in China. It buried 12 houses and the entrance of an iron mining tunnel
where some 27 miners were working inside. Ten people died, 64 missing, and eight wounded. Immediately after this disaster
happened, the government organized an expert team to assist the rescue work. As one of the geological experts, the author
did a lot of field investigations and collected first-hand information. Multi-methods including the remote sensing, 3D laser
scanning, geophysical exploration, and numerical modeling were used for analyzing the characteristics and the triggering mechanism
of the Wulong rockslide. The preliminary investigation results reveal that this rockslide with poor geological conditions
was mainly induced by the gravitation and the karst effect and also affected by the previous mining activities. The research
in this paper is meaningful and useful for further research on such kind of rockslides that are geologically similar to the
Wulong rockslide. 相似文献
14.
15.
Joseph Clancy White 《Contributions to Mineralogy and Petrology》1993,113(4):524-532
The textural relationships and structural states of optically isotropic labradorite from the Manicouagan, Quebec, impact structure have been examined by light (optical) and transmission electron (TEM) microscopy. Two distinct diaplectic glasses have been recognized based on their contrasting morphology, timing and the inferred modes of formation. The earliest isotropic bands and grain-scale isotropism (maskelynite) optically exhibit a gradational,in situ transformation from crystalline plagioclase with preservation of relict textures (twins, grain boundaries). The same transformation from crystalline to amorphous structure is observed in TEM to occur heterogeneously at scales on the order of the unit cell. The progressive transformation of optical properties reflects an increase in the volume fraction and eventual coalescence of these amorphous units. This maskelynite-type diaplectic glass is interpreted to form in the solid-state directly from crystalline material during the compressional phase of the shock wave. The other isotropic material occurs in spatially discrete tensiongashes and planar deformation features (PDFs) that overprint the maskelynite-type glass. This second type of diaplectic glass (PDF-type) is developed homogeneously within a given glass band and exhibits sharp crystal-glass boundaries, in contrast to the gradational boundaries of the maskelynite-type glass. PDF-type glass is interpreted to form by melting in tensional release zones during passage of the rarefaction wave. These observations emphasize the ability of naturally shocked rocks to preserve subtle evidence of variations in the shock process from highly transient events. 相似文献
16.
日本北海道音调津的球状石墨 总被引：1，自引：0，他引：1
本文利用光学显微镜、X射线衍射仪、透射电镜等手段对日本北海道音调津球状石墨的成因、结构等进行研究,认为日本北海道音调津球状石墨中除了石墨外,还存在镍黄铁矿﹑黄铜矿﹑磁黄铁矿等金属硫化物矿物。通过透射电子显微镜观察发现音调津石墨中大部分是椭圆状石墨颗粒,高分辨晶格条纹主要是非晶态结构,但是同时也发现了结晶良好的石墨。高结晶度石墨的存在可能是在硫化物Fe-Ni-Cu的触媒作用下形成的。天然球状石墨的微结构和性状研究对天然石墨的形成和开发应用有重要意义,对新型碳材料的制备技术有重要科学意义。 相似文献
17.
夏季长江河口潮间带反硝化作用和N2O的排放与吸收 总被引：15，自引：1，他引：15
采用培养箱乙炔抑制和现场静态箱法,于夏季(7月)在长江河口潮滩潮间带进行了采样,研究表明,长江河口潮滩水体自身N2O产生速率很低,在潮汐淹没期沉积物是上覆水体N2O的来源,其来自沉积物中反硝化、硝化等氮素循环的多个反应过程,沉积物中N2O自然产生速率在0.10～8.50μmol/(m2·h)之间,反硝化速率在21.91～35.87μmol/(m2·h)之间。退潮出露期中潮滩是大气N2O的排放源犤交换速率在-11.03～13.17μmol/(m2·h)之间犦,5～10cm地温是影响N2O排放速率的显著性因素;低潮滩-大气界面N2O排放、吸收速率在-5.75～0.49μmol/(m2·h)之间。总体上看,中潮滩是大气N2O的排放源;而低潮滩对大气N2O有明显的吸收作用。潮滩植被(海三棱草和底栖藻类)的光合作用明显抑制了N2O的排放并可能导致吸收,而其呼吸作用则增加了N2O的排放,潮间带-大气界面N2O的排放和吸收与CO2的排放、吸收有显著的正相关关系。 相似文献
18.
S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
19.
捕虏体麻粒岩是了解下地壳形成和演化的重要样品。汉诺坝新生代玄武岩中的二辉麻粒岩捕虏体样品中富含各种硫化物相,主要类型有:①孤立产出的球状出溶硫化物;②矿物颗粒之间或颗粒内的粗晶硫化物;③次生硫化物包裹体群;④裂隙充填硫化物。电子探针分析表明,硫化物的矿物成分均为贫镍磁黄铁矿,(Ni+Co+Cu)/Fe(原子比)远小于0.2;(Fe+Cu+Co+Ni)/S(原子比)比地幔岩的磁黄铁矿小,多小于0.875,反映了一种S过饱和环境。各种产状的磁黄铁矿中Au、Ag都有一定的含量,其平均值分别为0.19%～0.22%(Au)、0.01%～0.02%(Ag),反映下地壳的麻粒岩化与金矿化的成因联系。磁黄铁矿的Ni、Co、Cu含量与S正相关,说明微量重金属元素与S具有同源的关系,由于地幔去气伴随S而进入下地壳。 相似文献
20.
Compositional evolution in Ca-amphibole in the Karmutsen metabasites, Vancouver Island, British Columbia, Canada 总被引：1，自引：0，他引：1
M. TERABAYASHI 《Journal of Metamorphic Geology》1993,11(5):677-690
Abstract The 6-km-thick Karmutsen metabasites, exposed over much of Vancouver Island, were thermally metamorphosed by intrusions of Jurassic granodiorite and granite. Observations of about 800 thin sections from the Campbell River and Buttle Lake area show that the metabasites provide a complete succession of mineral assemblages ranging from the zeolite to pyroxene hornfels facies around the intrusion. The most important observations are as follows. (1) The compositional change of Ca-amphiboles with increasing metamorphic grade is not straightforward. The tremolite component decreases from the prehnite–actinolite facies to the greenschist facies with a compensating tschermak component increase, but the tendency is not clear thereafter. Instead, the edenite component increases from the amphibolite facies to the pyroxene hornfels facies. (2) The most pargasitic Ca-amphibole occurs in high-Fe2+/Mg metabasite from the greenschist/amphibolite transition zone. (3) The reasons for such irregular compositional trends, even in the rather uniform MORB-like composition of the Karmutsen metabasites, are non-ideal solid solutions of Ca-amphibole at low temperature and the effective control by bulk rock composition in the amphibolite facies. (4) The data from this study support, but do not prove, a transition loop for the actinolite–hornblende compositional gap rather than a solvus. If the gap is a solvus, its shape is asymmetric, and is highly dependent on the other compositional parameters such as Fe3+/Al and Fe2+/Mg. (5) The XNaA/XA±XAb) ratios between Ca-amphibole and plagioclase are most useful as an indicator of metamorphic grade even within the amphibolite facies, and these change systematically from 0.2 to 0.5 from the greenschist to pyroxene hornfels facies. (6) The compositional trend of Ca-amphibole from the Karmutsen metabasites indicates a typical low-P/T metamorphic facies series on a Rbk–Gln–Tr–Ts diagram. 相似文献