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1.
在柴北缘东段识别出早古生代埃达克岩-富Nb玄武岩的火山岩组合。埃达克岩富Na2O、贫K2O,K2O/Na2O比值介于0.14~0.43之间;高Sr（614×10-6~1043×10-6）,但亏损Y（3.26×10-6~14.1×10-6）和Yb（0.33×10-6~1.46×10-6）,具有高的Sr/Y比值（44~282）;富集Sr、Ba等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素及Cr、Ni、Co、V等相容元素。富Nb玄武岩富Na2O、贫K2O、高TiO2,其Nb含量较高,介于16.9×10-6~17.9×10-6之间,具有高的Nb/Ta、Nb/U、（Nb/La）N比值,同时富集高场强元素。埃达克岩锆石U-Pb定年得到453±4Ma和457±4Ma的结晶年龄。锆石εHf（t）范围较大,介于3.40~13.23之间,对应的二阶段模式年龄tDM2介于1059~566Ma之间,显示以新生物质为主的特征。综合研究表明柴北缘东段埃达克岩可能为岛弧环境下俯冲的南祁连大洋板片部分熔融的产物。板片来源的埃达克质熔体交代或与上覆地幔楔橄榄岩反应,导致被交代的地幔橄榄岩部分熔融而形成富Nb玄武质岩浆。柴北缘东段埃达克岩-富Nb玄武岩火山岩组合的厘定表明南祁连洋可能直到~455Ma之前并未完全闭合,同时表明俯冲大洋板片的部分熔融可能是柴北缘早古生代地壳增生的一种重要方式。  相似文献   

2.
辽东半岛在中生代发生大规模的岩浆活动和金成矿作用,其中尤以白垩纪岩浆作用最为强烈。本文对早白垩世三股流岩体进行了锆石U-Pb年代学、全岩地球化学和Sr-Nd同位素研究。三股流岩体主要由似斑状角闪黑云花岗岩和细粒黑云母花岗岩组成,分别形成于125.1±1.2Ma和128.7±2.2Ma。穿切三股流岩体的闪长岩脉形成于125.1±2.4Ma。角闪黑云花岗岩具有准铝质、富水、高氧逸度特征,为高钾钙碱性I型花岗岩。微量元素模拟和Sr-Nd同位素表明角闪黑云花岗岩可能来源于古元古代变基性岩和辽河群变中性岩的部分熔融。细粒黑云母花岗岩并非直接来源于中下地壳岩石的部分熔融,而是角闪黑云花岗岩分异演化的结果。岩相学和微量元素模拟表明,分离相主要为钾长石+斜长石+角闪石+黑云母+石英。细粒黑云母花岗岩亏损中稀土的特征表明榍石也是重要的分离相。随着岩浆的演化,粒间高硅熔体由于发生水饱和而快速结晶形成具有细粒结构的高硅黑云母花岗岩。闪长岩脉具有高Mg#（0.51~0.52）和高Sr/Y（83.3~85.5）特征,属于埃达克质高镁闪长岩。相对于三股流花岗岩,较低的87Sr/86Sr初始值（0.708723）、负的εNd（t）值（-14.1）指示闪长岩脉可能形成于幔源岩浆和壳源岩浆的混合作用。由于太平洋板块的俯冲造成华北克拉通的减薄,早白垩世辽东半岛处于强烈伸展体制,富集岩浆圈地幔部分形成的玄武质岩浆底侵下地壳,引起中下地壳发生部分熔融并发生强烈的结晶分异,形成三股流岩体。同时,玄武质岩浆在上升过程中与壳源花岗质岩浆发生一定程度的混合作用,形成埃达克质高镁闪长岩脉。  相似文献   

3.
南冈底斯晚白垩世岩浆岩的成因及地球动力学机制一直存在争议。本文对冈底斯南缘努林花岗闪长岩开展地球化学、锆石U-Pb年代学及同位素示踪研究。结果显示,该岩体具有富SiO2（66.62%～67.81%）、高Al2O3（15.11%～15.66%）、高Sr（>481×10-6）,低Y（≤8.13×10-6）和低Yb（≤0.73×10-6）特征,Sr/Y比值达59～111,显示埃达克岩的特征;岩石轻稀土富集,重稀土亏损,具有显著的Eu正异常;富集大离子亲石元素,亏损高场强元素。（87Sr/86Sr）i=0.704011～0.704244,εNd（t）=＋3.61～＋5.75,总体反映地幔源区的Sr、Nd同位素特征。锆石U-Pb LA-ICP-MS测年显示存在83Ma和89Ma两组年龄。结合地质及地球化学分析,认为努林花岗闪长岩是新特提斯洋洋脊俯冲引起的镁铁质新生下地壳部分熔融的产物。  相似文献   

4.
胶东早白垩世高镁闪长岩类的发现及其构造背景   总被引：3，自引：2，他引：1  
胶东地区发育大规模早白垩世壳幔混合源花岗岩类,但一直未发现与花岗岩类相关的独立的幔源侵入体,给深入理解早白垩世壳幔演化带来了困惑。胶东的柳林庄和夏河城岩体以往被认为是三叠纪闪长岩类,本文在详细的野外地质工作基础上,通过年代学、岩石地球化学、同位素地球化学分析,发现这2个岩体为早白垩世高镁闪长岩。样品的SiO2含量在53.29%~62.54%之间,MgO含量为3.60%~8.10%,Mg#主要介于0.47~0.68之间;富集Ba、Rb、K等大离子亲石元素,亏损Nb、Ta、Zr等高场强元素;初始87Sr/86Sr值为0.7082~0.7083,与地幔平均值接近;εNd（t=113Ma）值很低（-20.5~-16.8）,与胶东地区的基性脉岩同位素组成一致。2个岩体相比而言,柳林庄岩体富K2O、Fe2O3T,REE、LILE、HFSE含量较高,而MgO、Ni和Cr含量偏低。3件样品的锆石LA-ICP-MS U-Pb同位素加权平均年龄值分别为120.1±1.6Ma、118.3±1.7Ma和122.3±4.0Ma,与壳幔混合源的伟德山型花岗岩及胶东金矿的成岩、成矿时代一致,指示他们形成于统一的地球动力学背景。高镁闪长岩的地球化学特征介于高镁埃达克岩与赞岐岩及埃达克岩与Piip型高镁安山岩之间,指示其形成于古太平洋板块俯冲的地幔楔环境,为富集岩石圈地幔部分熔融的产物。夏河城岩体的岩浆直接来源于含角闪石的富集岩石圈地幔源区,而柳林庄岩体岩浆源区为含金云母的岩石圈地幔并且在岩浆上侵过程中混染了部分地壳物质。  相似文献   

5.
甜水海地块作为西昆仑-喀喇昆仑造山带重要的组成部分,夹持于麻扎-康西瓦板块缝合带和洪山湖-乔尔天山板块缝合带之间,其构造属性的探讨对认知西昆仑地区早古生代地质演化具有重要的科学意义。笔者在甜水海地块中部麻扎地区通过野外填图新发现并厘定出一套火山岩-沉积岩组合,主要由安山岩、英安岩、流纹岩及其火山碎屑岩和少量沉积岩组成;与安山岩互层产出的英安岩和流纹岩锆石U-Pb年龄为519~513Ma,表明这套火山-沉积地层形成于中寒武世。该火山岩套的地球化学特征为：安山岩SiO2含量为57.0%~67.2%,具有高MgO（1.91%~7.17%）含量和Mg#值（39.1~65.3,平均值为55.0）,较高Cr（31.0×10-6~190×10-6）和Ni（12.2×10-6~121×10-6）含量,低FeOT/MgO比值（1.12~3.26）,低Al2O3（13.7%~17.3%）和K2O（1.12%~5.52%）含量的特征,属于低铁钙碱系列高镁安山岩-镁安山岩;英安岩较安山岩SiO2含量高（63.8%~71.8%）,具有相似的Al2O3（13.4%~15.4%）含量,低MgO（0.28%~1.19%）含量和Mg#值（9.98~36.5,平均值为25.3）,低Cr（11.5×10-6~25.2×10-6）和Ni（4.33×10-6~11.8×10-6）含量,高FeOT/MgO比值（3.64~18.9）和K2O（4.84%~9.27%）含量的特征,属于高钾钙碱性系列。安山岩和英安岩总体表现出右倾轻稀土富集分配模式,富集Rb、Ba、K、Th等大离子亲石元素,亏损Nb、Ta、Ti高场强元素,具有典型的岛弧岩浆岩特征。野外调查表明,安山岩与英安岩在空间上相邻,呈互层产出,且它们都出露于中寒武系地层中,暗示了二者在成因上紧密相联。岩石地球化学特征指示了安山岩和英安岩可能源于富集地幔楔不同比例的部分熔融作用,所产生的岩浆在上升过程中又遭受了不同比例的地壳混染。推测麻扎地区寒武纪火山岩形成于原特提斯洋向南俯冲消减机制下的岛弧构造环境,同时结合区域资料,认为在寒武纪甜水海地块存在两期岩浆作用,在早寒武系末期（~520Ma）原特提斯洋发生双向俯冲,甜水海地块北缘转化为活动大陆边缘。  相似文献   

6.
北山柳园地区中志留世埃达克质花岗岩类及其地质意义   总被引：7，自引：3，他引：4  
北山柳园地区发育的埃达克质片麻状花岗闪长岩为钙碱性岩浆系列,具有较高SiO2 (>56%),Al2O3 (>15%)和较低的MgO (<3%)含量,Na2O>K2O; 并且具有高的Sr含量(>400×10-6)和Sr/Y比值; 样品轻重稀土强烈分异(La/Yb)N ＝18~86,强烈亏损重稀土Yb与Y,具有不明显的Eu异常(δEu＝0.90~0.95); 富集LREE和大离子亲石元素(LILE),而亏损HREE、高场强元素(HFSE: Nb、Ta),与世界上典型的俯冲洋壳熔融形成的埃达克岩相似。然而样品具有相对高的(87Sr/86Sr)I (0.70635~0.70636)和相对低的εNd(t) (-0.8~-0.9),以及锆石具有相对较低的εHf (t) (-0.8~+2.7)同位素特征,比典型的俯冲洋壳熔融形成埃达克岩具有更多的放射成因,推测可能是源区加入了地壳物质/沉积物/或特殊的洋壳(OIB/E-MORB)熔融,以及侵位过程中地壳物质的混染所造成的。埃达克质片麻状黑云母花岗岩锆石LA-ICPMS年龄为424±4Ma,代表了花岗岩埃达克花岗岩的结晶年龄。花牛山岛弧带在中晚志留世时期具有较高的地热梯度,发育了大面积高εNd(t)钙碱性花岗岩和区域围岩发生了高温变质作用。因此,柳园埃达克岩是由于热的洋壳向花牛山岛弧地体俯冲过程中熔融形成的,俯冲洋壳熔融是本地区早古生代大规模地壳增生的重要方式之一。  相似文献   

7.
本文以华北陆块东部早白垩世滁州闪长玢岩和管店石英闪长岩为研究对象,报道了新的全岩地球化学（主量元素、微量元素以及Sr-Nd同位素）以及锆石U-Pb年代学和Hf同位素的综合研究结果,进而约束其岩石成因和构造意义。滁州闪长玢岩中锆石发育振荡环带,管店石英闪长岩中锆石具条痕状吸收的特点,它们均为岩浆成因。锆石LA-ICP-MS U-Pb定年结果显示,滁州和管店闪长质锆石年龄分别为128±1Ma和130±2Ma,表明二者均形成于早白垩世。地球化学特征显示,滁州和管店闪长质岩石具有类似的主量元素和微量元素组成,整体具中等的SiO2含量（58.55%~60.12%）和富MgO（4.43%~5.10%,Mg#=57~61）的特征,Na2O/K2O比值为1.20~1.47,属于高钾钙碱性系列岩石;富集轻稀土元素和大离子亲石元素（如Rb、Ba）,亏损重稀土元素和高场强元素（如Nb、Ta、Zr、Hf）,并具不同程度的Eu负异常（δEu=0.85~0.93）。它们具高的Sr（575×10-6~1035×10-6）和低的Y含量（10.2×10-6~15.3×10-6）以及高的Sr/Y比值（57~69）,属于埃达克质岩石。此外,滁州和管店闪长质岩石具有类似的Sr-Nd以及锆石Hf同位素的特征,滁州闪长玢岩的87Sr/86Sr初始比值介于0.7061~0.7066之间,εNd（t）值为-17.7~-16.9,锆石εHf（t）值变化于-23.1~-19.1之间,而管店石英闪长岩的87Sr/86Sr初始比值为0.7046~0.7059,εNd（t）值为-18.7~-15.8,锆石εHf（t）值为-25.6~-20.0。综合上述,滁州和管店闪长质岩石均属于高镁埃达克质岩石,起源于拆沉的加厚下地壳部分熔融的熔体与地幔橄榄岩反应的产物,形成于早白垩世华北东部陆块拆沉作用下的伸展背景。  相似文献   

8.
叶现韬  张传林 《岩石学报》2020,36(11):3397-3413
塔里木克拉通前寒武纪构造演化,特别是早前寒武纪构造演化一直是地质学家讨论的焦点。本文通过对阿尔金北缘新太古代TTG片麻岩进行详细的野外调查、岩相学观察、地球化学分析以及锆石SHRIMP U-Pb定年来揭示该岩石的成因以及探讨塔里木克拉通早前寒武纪构造演化。锆石SHRIMP U-Pb定年结果显示阿尔金北缘TTG片麻岩的形成年龄为2740±19Ma,而后经历了新太古代（2494±53Ma）混合岩化作用和古元古代（1962±78Ma）麻粒岩相变质作用。阿尔金北缘英云闪长质片麻岩显示低的MgO含量（1.33%~3.08%）和Mg#（37~52）,具有高Sr（469×10-6~764×10-6）含量、低Y（4.72×10-6~13.5×10-6）和Yb（0.37×10-6~0.99×10-6）含量的特点,它们的Sr/Y比值可达到41~99。岩石的这些特征与基性下地壳部分熔融形成的TTG相同。并且,该新太古代TTG片麻岩还具有正的εNd（t）值（0.2~3.6）、高的Nd同位素初始值（0.509088~0.509260）和古太古代两阶段模式年龄（3.62~3.70Ga）。因此,阿尔金北缘新太古代TTG片麻岩可能来源于基性下地壳部分熔融,并且岩浆源区有石榴石、角闪石和金红石的残留。综合前人的研究成果,对比相邻区域TTG的形成时代,变质事件的记录以及太古宙地壳增生差异都指示阿尔金北缘和敦煌-库鲁塔格地区可能来源于不同的大陆块体。  相似文献   

9.
为解释南冈底斯晚白垩世埃达克质岩石成因及其地球动力学机制,本文对西藏扎囊县札佐地区二长花岗岩开展了锆石U-Pb年代学、Hf同位素和全岩地球化学分析。札佐二长花岗岩锆石U-Pb定年为80.43±0.62 Ma,其SiO2为66.19%~66.84%,Al2O3为15.17%~15.48%,MgO为1.67%~1.91%,Mg#为47.4~51.5,K2O为3.86%~4.09%,A/CNK=0.91~1.01,属准铝质高钾钙碱性岩石。岩石轻稀土富集明显,高Sr（492×10-6~670.2×10-6）,低Y（8.27×10-6~14.99×10-6）,Yb（1.07×10-6~1.79×10-6）,高Sr/Y（35.0~81.0）,高La/Yb（17.4~21.4）,弱负Eu异常,具埃达克岩地球化学特征。相对富集大离子亲石元素（LILE）,亏损高场强元素（HFSE）和重稀土。锆石εHf（t）值为10.5~14.1,单阶段Hf模式年龄（tDM1）为184.8~326.1 Ma,平均为203.4 Ma,二阶段Hf模式年龄（tDM2）为247.2~476.0 Ma,平均为287.1 Ma,略大于侵位年龄,指示岩浆物质来源于俯冲洋壳,并可能卷入俯冲沉积物。岩石中地幔组分印记Mg#值和相容元素Ni、Cr含量较高,表明熔体在上升过程中与上覆地幔楔发生反应。研究分析表明,在新特提斯洋洋脊俯冲作用下,高温热流透过板片窗导致洋壳（及俯冲沉积物）部分熔融形成札佐埃达克质二长花岗岩。同时表明,在80 Ma左右,新特提斯洋仍处于洋脊俯冲阶段。  相似文献   

10.
王仁民  李孟江  程素华 《岩石学报》2012,28(4):1037-1043
在华北克拉通北部,太古代麻粒岩古陆核与陆外沉积盆地(红旗营子群)之间已经厘定出一个晚太古代的古洋壳残片(Wang et al., 2009)。此残片南北两侧又发现了低Al2O3 型TTG岩体(2512±19Ma)、富钾高铬的深熔花岗岩(Closepet-like),含Cr 97×10-6~308×10-6,以及含大量密集的煌斑岩脉的含石英的二长岩(Sanukitoid-like)等三类在成因上与俯冲带密切相关的岩体。低Al2O3型TTG是在角闪麻粒岩亚相条件下由俯冲中的滑片部分熔融所生成。深熔花岗岩是TTG再熔融的产物,而它们的基性化演化和Cr的增高是幔源岩浆与富钾深熔花岗岩经复杂的岩浆混合和交代改造的结果。  相似文献   

11.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

14.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

15.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

16.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

17.
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds.  相似文献   

18.
《GeoJournal》1986,13(2):187
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19.
《GeoJournal》1986,13(2):187-187
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20.
The Samchampi-Samteran alkaline igneous complex (SAC) is a near circular, plug-like body approximately 12 km2 area and is emplaced into the Precambrian gneissic terrain of the Karbi Anglong district of Assam. The host rocks, which are exposed in immediate vicinity of the intrusion, comprise granite gneiss, migmatite, granodiorite, amphibolite, pegmatite and quartz veins. The SAC is composed of a wide variety of lithologies identified as syenitic fenite, magnetite ± perovskite ± apatite rock, alkali pyroxenite, ijolite-melteigite, carbonatite, nepheline syenite with leucocratic and mesocratic variants, phonolite, volcanic tuff, phosphatic rock and chert breccia. The magnetite ± perovskite ± apatite rock was generated as a cumulus phase owing to the partitioning of Ti, Fe at a shallow level magma chamber (not evolved DI = O1). The highly alkaline hydrous fluid activity indicated by the presence of strongly alkalic minerals in carbonatites and associated alkaline rocks suggests that the composition of original melt was more alkalic than those now found and represent a silica undersaturated ultramafic rock of carbonated olivine-poor nephelinite which splits with falling temperature into two immiscible fractions—one ultimately crystallises as alkali pyroxenite/ijolite and the other as carbonatite. The spatial distribution of varied lithotypes of SAC and their genetic relationships suggests that the silicate and carbonate melts, produced through liquid immiscibility, during ascent generated into an array of lithotypes and also reaction with the country rocks by alkali emanations produced fenitic aureoles (nephelinisation process). Isotopic studies (δ18O and δ13C) on carbonatites of Samchampi have indicated that the δ13C of the source magma is related to contamination from recycled carbon.  相似文献   

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