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1.
都龙锡锌多金属矿床LA-MC-ICPMS锡石U-Pb测年及其意义 总被引：12，自引：9，他引：3
云南都龙锡锌多金属矿床是我国最大的锡石硫化物矿床之一。缺乏精确可靠的成矿年代学判据,是该矿床成因认识存在较大分歧的重要原因之一,严重制约了地质勘探工作的深入。本文应用LA-MC-ICP-MS微区原位U-Pb同位素测年技术,对都龙矿区曼家寨矿段的锡石样品进行了研究,获得DL12-716、DL12-722、DL12-740等三件样品的206Pb/207Pb-238U/207Pb等时线年龄分别为89.2±4.1Ma(N=22,MSWD=4.5)、88.0±1.6Ma(N=24,MSWD=2.3)和87.2±3.9Ma(N=31,MSWD=14),207Pb/206Pb-238U/206Pb谐和年龄分别为96.6±3.5Ma(MSWD=8.1)、93.6±1.6Ma(MSWD=5.8)和82.0±2.5Ma(MSWD=11)。结合矿床地质特征和前人成岩-成矿年代学成果,表明都龙矿区锡成矿作用主要发生在晚白垩纪,与燕山晚期岩浆热液活动关系密切,结合地质事实,表明燕山晚期岩浆热液活动是老君山矿集区锡钨多金属成矿的关键。通过区域地质及年代学对比,表明滇东南地区晚白垩世存在大规模花岗岩成岩-锡成矿事件。 相似文献
2.
广西大厂矿田长坡——铜坑锡多金属矿床锡石LA-MC-ICP-MSU-Pb年龄及其地质意义 总被引：3，自引：0，他引：3
长坡—铜坑锡多金属矿位于广西大厂锡多金属矿田的西矿带,层状矿体广泛发育,但由于缺乏直接的成矿年龄数据,其成因还存在较大争议。利用锡石原位LA-MC-ICP-MS U-Pb法对采自92号层状矿体的三个锡石样品进行年代学研究,获得n(206Pb)/n(207Pb)—n(238U)/n(207Pb)等时线年龄为95.8±2.6 Ma(MSWD=6.3),与通过石英40Ar/39Ar法、透长石的激光原位40Ar/39Ar法及石英Rb-Sr等时线法获得的年龄(91.4±2.9~94.52±0.33)Ma在误差范围内一致,说明通过锡石原位LA-MC-ICP-MS U-Pb法定年在该类型矿床的年代学研究行之有效。同时,通过年代学佐证了锡的成矿与龙箱盖岩体第二阶段侵位(96.6~93.86 Ma)为同一时期,认为成矿与岩浆作用关系密切。 相似文献
3.
四川马尔康党坝花岗伟晶岩型稀有金属矿床成矿时代的限定：来自LA- MC- ICP- MS锡石U- Pb定年的证据 总被引：9，自引：0，他引：9
四川党坝花岗伟晶岩型稀有金属矿床位于四川西部可尔因矿田东南部,松潘甘孜造山带中部,是近年新发现的以锂为主,共伴生铌、钽、铍、铷、锡的超大型矿床。本文在花岗伟晶岩地质特征研究的基础上,对花岗伟晶岩中的锡石矿物开展电子探针成分分析以及LA-MC-ICP-MS U-Pb定年工作。电子探针波谱定量分析结果显示,党坝矿床的锡石都是与稀有金属伟晶岩有关的锡石,并非来自热液作用的锡石。U-Pb定年结果显示,锂辉石钠长石伟晶岩脉(DB2)和含锂云母锂辉石钠长石伟晶岩脉(DB1)两件样品的~(207)Pb/~(206)Pb-~(238)U/~(207)Pb谐和年龄分别为208.1±1.9Ma(n=31,MSWD=2.5)和199.3±1.6Ma(n=11,MSWD=0.68),可以代表花岗伟晶岩脉的形成时代,并且表明党坝花岗伟晶岩型稀有金属矿床形成于晚三叠世,与印支晚期的岩浆热液活动密切相关。松潘甘孜造山带稀有金属矿床成矿年代学对比显示,党坝、李家沟、雪宝顶和甲基卡等矿床具有相似的成矿类型和成矿年龄,形成于造山后构造背景。松潘甘孜造山带印支晚期和燕山早期存在大规模的锂铌钽铍锡稀有多金属成矿事件。 相似文献
4.
四川可尔因矿田李家沟伟晶岩型稀有金属矿床锡石LA-MC-ICP-MS U-Pb定年及地质意义 总被引：2，自引：0，他引：2
四川李家沟伟晶岩型锂铌钽铍锡稀有金属矿床位于松潘-甘孜造山带中部、可尔因矿田东南部,是近年新发现的超大型矿床,成矿时代尚不清楚。本文在伟晶岩地质特征研究的基础上,对李家沟锂辉石伟晶岩中的锡石矿物开展电子探针成分分析以及LA-MC-ICP-MS U-Pb定年工作。电子探针波谱定量分析结果显示,李家沟矿床的锡石都是与稀有金属矿床有关的锡石,并非来自热液矿床的锡石。U-Pb定年结果显示,含锂辉石钠长石伟晶岩样品(LPD4H2)的~(207)Pb/~(206)Pb-~(238)U/~(207)Pb谐和年龄为211. 4±3. 3 Ma(n=28,MSWD=2. 9),可以代表稀有金属伟晶岩脉的年龄。表明李家沟稀有金属矿床形成于晚三叠世,与印支晚期的岩浆热液活动密切相关。区域成岩成矿年代学对比显示,李家沟与雪宝顶和甲基卡等矿床具有相似的成矿类型和成矿年龄,形成于造山后趋于稳定阶段。松潘-甘孜造山带印支晚期-燕山早期存在大规模的锂铌钽铍锡稀有多金属成矿事件。 相似文献
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内蒙古道伦达坝铜钨锡矿床LA-ICP-MS锆石和锡石U-Pb年龄及其地质意义 总被引：6，自引：1，他引：5
道伦达坝矿床位于大兴安岭南段,是一个铜钨锡矿床,其铜、钨、锡储量均达中型。矿体呈脉状,主要产于二叠系砂板岩中的断裂破碎带中,华力西期黑云母花岗岩中的断裂破碎带中亦赋存有矿体。文章选取2件石英-萤石-白云母-电气石-锡石-黑钨矿阶段的矿石样品对其中的进行了LA-ICP-MS U-Pb定年,获得2件样品的~(207)Pb/~(206)Pb-~(238)U/~(206)Pb谐和年龄分别为(134.7±6.6)Ma(MSWD=1.4)和(136.8±7.4)Ma(MSWD=1.7),~(206)Pb/~(207)Pb-~(238)U/~(207)Pb等时线年龄分别为(132±12)Ma(MSWD=0.76)和(135±13)Ma(MSWD=0.9)。锡石定年结果表明,道伦达坝矿床形成于早白垩世。对矿区外围张家营子岩体中的斑状细粒花岗岩进行了LA-ICP-MS锆石U-Pb测年,获得的~(206)Pb/~(238)U加权平均年龄为(135±1)Ma(MSWD=1.3),该岩体的形成年龄与道伦达坝矿床的成矿年龄在误差范围内一致。本次定年结果表明道伦达坝矿床形成于早白垩世,与同期的花岗质岩浆活动有密切的成因联系,该矿床属于与花岗岩有关的岩浆热液脉型矿床。 相似文献
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大兴安岭南段维拉斯托锡多金属矿床LA-ICP-MS锡石和锆石U-Pb年龄及其地质意义 总被引：6，自引：0，他引：6
维拉斯托锡多金属矿床位于大兴安岭南段西坡的内蒙古克什克腾旗,是近年来发现的一个以锡为主,共伴生钨、锌、铜、钼、铷、铌和钽的大型矿床。矿化类型包括深部以锡为主,伴生锌、铷、铌和钽的蚀变花岗岩型矿体;中部以锡为主,伴生铜和锌的隐爆角砾岩型矿体及浅部锡、钨、锌、铜和钼的石英大脉型和网脉型矿体。该矿床的主要工业矿体为石英脉型,呈北北东向产于古元古界宝音图群和华力西期石英闪长岩中的断裂破碎带内,而蚀变花岗岩型和隐爆角砾岩型矿石的品位较低。文中选取1件石英脉型锡矿体中的锡石样品进行了LA-ICP-MS锡石U-Pb定年,获得锡石的206Pb/207Pb238U/207Pb等时线年龄为(136.0±6.1) Ma(MSWD=0.94),207Pb/206Pb238U/206Pb谐和年龄为(132.3±5.4) Ma(MSWD=2.8),表明维拉斯托锡多金属矿床形成于早白垩世;选取1件与成矿相关的北大山岩体花岗岩样品开展了LA-ICP-MS锆石U-Pb定年,获得206Pb/238U年龄为(140±2) Ma(MSWD=0.10),表明成矿岩体亦形成于早白垩世。维拉斯托锡多金属矿床属于与花岗岩有关的岩浆热液型矿床。通过统计大兴安岭南段主要锡多金属矿床的成矿年龄和成矿岩体的年龄,发现几乎所有的锡多金属矿床均形成于140～135 Ma期间,表明早白垩世是大兴安岭南段锡多金属矿床成矿高峰期。 相似文献
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都龙锡锌矿床锡石和锆石U-Pb年代学：滇东南白垩纪大规模花岗岩成岩-成矿事件 总被引：22，自引：13，他引：22
都龙锡锌矿床是我国最大的锡石硫化物矿床之一。由于缺少可靠的年代学数据,对该矿床的成因尚存在较大争议。本文报道了利用锡石和锆石U-Pb法,首次获得的都龙锡锌矿床及相关的燕山晚期老君山花岗岩的年龄。其中,锡石TIMS法~(206)Pb/~(238)U年龄加权平均值为79.8±3.2Ma(MSWD=3.16),(238)U/~(204)Pb-~(206)Pb/~(204)Pb等时线年龄为82.0±9.6Ma (MSWD=4.81);隐伏花岗岩的锆石SHRIMP法~(206)Pb/~(238)U年龄加权平均值为92.9±1.9Ma(N=10,MSWD=0.71),花岗斑岩的锆石SHRIMP法~(206)Pb/~(238)U年龄加权平均值为86.9±1.4Ma(N=9,MSWD=3.70),表明锡(铜)矿化主要与晚白垩世岩浆热液活动有关。结合个旧、白牛厂两个超大型矿床和相关花岗岩体的年代学资料,指示滇东南地区于白垩纪存在以锡矿化为特色的大规模花岗岩成岩-成矿事件,可能与晚中生代以来华南地块岩石圈伸展有关。 相似文献
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江西彭山锡多金属矿集区位于江西省德安县,处于钦杭成矿带东段靠扬子板块一侧,是扬子板块东南缘地区一个重要的锡多金属矿集区。目前该地区尚缺乏精确可靠的成矿年代学资料。本文应用LA-MC-ICP-MS微区原位U-Pb同位素测年技术,对矿集区内尖峰坡矿床中锡石样品进行了研究,获得尖峰坡锡矿的206Pb/207Pb-238U/207Pb等时线年龄129.7±2.5Ma(N=31,MSWD=5.5),207Pb/206Pb-238U/206Pb谐和年龄为128.3±2.5Ma(N=31,MSWD=7.6),表明尖峰坡矿区锡成矿作用主要发生在早白垩世,与已报道的彭山地区燕山期花岗岩的成岩年龄相一致。紧密的时间以及空间关系显示燕山晚期岩浆-热液活动对形成彭山锡多金属矿集区的大规模成矿作用至关重要。对华南地区锡钨区域成矿年代学对比表明,扬子板块东南缘的锡钨成矿带均形成于早白垩世(146~124Ma),这与其北侧的长江中下游成矿带九瑞-鄂东南铜多金属矿集区的成岩成矿时代相同,而明显不同于南岭地区晚侏罗世(160~150Ma)以及滇东南-桂西北地区晚白垩世(98~76Ma)的锡钨成矿作用,说明扬子板块东南缘具有与南岭以及滇东南-桂西北地区不同的锡钨成矿背景,而应与长江中下游地区的构造岩浆作用事件统一来开展深入研究。 相似文献
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《矿产与地质》2020,(3)
桂北一洞锡多金属矿床位于扬子板块东南缘、江南造山带西段的宝坛地区,一般认为其成因上与平英复式岩体具有密切关系。但由于缺乏直接的成矿年龄数据,其形成年龄主要是通过平英复式岩体的成岩年龄间接确定的,因此其成矿年龄还存在较大的争议。利用锡石微区原位LA-MC-ICP-MS U-Pb测年方法,对采自一洞锡多金属矿床韧性剪切带内矿体的锡石样品进行测年分析,获得锡石的207Pb/206Pb-238 U/206Pb谐和年龄为(829.0±15.0)Ma(MSWD=31),该年龄值与笔者获得的平英复式岩体中含锡元素最高的第四期次(含)电气石中细粒黑云母(二长-)碱长花岗岩(Pt3ξγ4T)的形成年龄[(831.1±7.1)Ma]在误差范围内基本一致。表明锡多金属矿的成矿物质可能主要来源于平英复式岩体的第四次岩浆作用,而后期的构造活动使锡多金属元素从源岩中运移出来,并在韧性剪切带中富集成矿。 相似文献
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粤东塌山斑岩型锡多金属矿床锆石及锡石U-Pb年代学、Hf同位素组成及其地质意义 总被引：1，自引：0，他引：1
陆河县塌山斑岩型锡多金属矿床位于粤东地区莲花山断裂带南西段,是粤东锡多金属成矿带内与花岗斑岩和石英斑岩密切相关的锡矿床,同时也是全国三个典型斑岩型锡矿之一。本文对与矿化有关的花岗斑岩进行了锆石U-Pb年代学和Hf同位素综合研究。LA-ICP-MS锆石U-Pb定年显示,花岗斑岩侵位年龄为136.8±1.1 Ma,是早白垩世岩浆作用产物。同时本文对锡石进行了U-Pb定年研究,27个数据在~(206)Pb/~(238)U-~(207)Pb/~(238)U谐和年龄图上获得了133.6±8.6 Ma的下交点年龄,在Tera-Wasserburg年龄图解上获得了136.5±8.1 Ma的下交点年龄,两年龄在误差范围内一致,且与花岗斑岩年龄一致,很好的限定了塌山矿区成矿时代。花岗斑岩锆石εHf(t)从-4.87变化到-2.07,二阶段模式年龄(t_(DM2))为1322～1507 Ma,表明其成岩物质主要来自中元古代地壳岩石,可能有少量地幔物质加入。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
13.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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18.
岩石密度和超高压岩石折返速率 总被引：1，自引：3，他引：1
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。 相似文献
19.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献