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1.
南沙微地块花岗质岩石LA ICP MS锆石U Pb定年及其地质意义 总被引：1，自引：0，他引：1
南沙微地块一直被作为华南大陆的一部分,但缺乏基底岩石学证据的支持。本文首次报道了南沙微地块花岗质岩石岩浆锆石年龄。测年方法为激光剥蚀等离子体质谱（LAICPMS）测年技术。在站位S0818获得2个斜长花岗岩样品年龄: 分别为159.1±1.6 Ma和157.8±1.0 Ma,在站位S0832获得两个二长花岗岩样品年龄: 分别为153.6±0.3 Ma和127.2±0.2 Ma, 表明它们为燕山期晚侏罗世—早白垩世岩浆事件的产物。其中153～159 Ma年龄值可与南岭燕山期花岗岩年龄比较,而127 Ma年龄值可与浙闽沿海燕山期花岗岩年龄对比。一个样品中存在一个年龄为656.7 Ma的残余锆石核,结合中西沙发现的前寒武纪基底岩石资料,表明南海内散落的微地块可能广泛存在前寒武纪结晶基底,本区中生代花岗岩为古老陆壳重熔形成的。这一新的资料,对研究燕山期岩浆作用在中国南部的影响范围、南海微陆块前寒武纪地质及微陆块的裂离动力学都具有重要意义。 相似文献
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南沙微地块一直被作为华南大陆的一部分,但缺乏基底岩石学证据的支持.本文首次报道了南沙微地块花岗质岩石岩浆错石年龄.测年方法为激光剥蚀等离子体质谱(LA-ICPMS)测年技术.在站位S 08-18获得两个斜长花岗岩样品年龄:分别为159.1±1.6 Ma和157.8±1.0 Ma,在站位S 08-32获得两个二长花岗岩样品年龄:分别为153.6±0.3 Ma和127.2±0.2 Ma,表明它们为燕山期晚侏罗世-早白垩世岩浆事件的产物. 相似文献
3.
对云开地区1∶25万区调中划归前寒武纪或新元古代的(片麻状)花岗岩进行了锆石LA-ICP-MS U-Pb定年,获得的年龄分别为(443.3±2.6)Ma(样品1009,陆川县陆透水库东南)、(445.7±2.3)Ma(样品1010,陆川县月垌村)、(441.1±2.0) Ma(样品1012,高州市谢鸡镇)和(443.7±1.7)Ma(样品10108,信宜市朱砂镇),表明它们属于加里东期的产物而不是以往认为的前寒武纪基底或新元古代岩石.结合前人的研究表明,这些花岗岩主要由元古宙基底岩石发生深熔作用而成,是华南地区加里东期陆内造山作用的响应.随着云开地区前寒武纪基底中大量加里东期年龄的发现,说明加里东运动对该区的影响非常强烈,1∶25万区调中划归前寒武纪基底或新元古代的部分片麻状花岗岩应归属加里东期.云开地区前寒武纪基底主要是以片麻岩类为代表的高州杂岩和以变沉积岩类为代表的云开群,高州杂岩形成时代为中新元古代,云开群形成时代可能为新元古代.从整个华夏地块来看,存在古-中元古代结晶基底,但出露可能并不像以往认为的那么广泛. 相似文献
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通过LA-ICP-MS方法对柴北缘全吉地块基底的斜长角闪岩和花岗闪长岩进行了锆石U-Pb年代学及锆石微区微量元素的研究。斜长角闪岩中的岩浆锆石上交点年龄为2 396±26 Ma,代表了锆石结晶的年龄,下交点为905±140 Ma,代表了锆石发生铅丢失事件的年龄。其岩浆锆石具有U/Yb较高(0.1~1),Hf值较低(10 000×10~(-6)),U值较低(150×10~(-6))的特点,显示其岩浆源区与富集地幔密切相关。在锆石微量元素判别图解中数据主要落在陆弧区和洋岛区,指示其形成的构造环境为弧后盆地。花岗闪长岩中岩浆锆石的加权平均年龄为484±21 Ma,岩浆锆石具有U/Yb较高(1)和U值较高(平均值为640×10~(-6))的特点,显示岩浆源区为典型陆壳。锆石微量元素判别图解显示其形成于陆弧。研究结果表明,全吉地块基底除前寒武纪岩石外,还包含早古生代的岩石组合。全吉地块基底内部岩石组合与形成时代的复杂性,与全吉地块经历的多次洋壳俯冲、陆陆碰撞密切相关。 相似文献
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鄂东南地区古家山岩体锆石U-Pb年龄和Hf同位素组成:对岩浆源区的指示 总被引：1，自引：0，他引：1
对扬子陆块鄂东南地区古家山花岗闪长斑岩体进行了锆石CL显微结构分析和LA-(MC)-ICP-MS法U-Pb年龄测定及Lu-Hf同位素分析.结果表明该花岗闪长斑岩中的锆石为岩浆锆石,其晶体内部多包裹有经历变质重结晶程度不同的继承锆石.岩浆锆石206pb/238U加权平均年龄为145.4±1 Ma (MSWD=1.5),表明古家山岩体形成于晚侏罗世.岩浆锆石εHf(t)值为-4.33-17.41,Hf同位素两阶段模式年龄tDM2为1470 ～ 2294 Ma.继承锆石207Pb/206Pb年龄为1746 ～ 2959 Ma,以古元古代为主;εHf(t)值为-18.2～ 2.65,表明该地区存在太古宙-古元古代基底物质再循环.综合野外地质调查与岩石化学、锆石微区原位分析结果,古家山花岗闪长斑岩为壳源花岗岩,其源区为古元古代基底.对古家山花岗闪长斑岩体的研究表明鄂东南地区确切存在太古宙-元古代基底,为研究扬子陆块前寒武纪基底演化提供了新的信息和线索. 相似文献
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西藏安多地区早古生代及中生代造山记录:来自安多微陆块-南羌塘锆石U-Pb年代学及Hf同位素研究 总被引：1，自引：1，他引：0
安多地区位于青藏高原腹地,为拉萨地体、羌塘地体及安多微陆块的结合部位,是研究拉萨地体、羌塘地体起源以及特提斯造山过程的关键位置。我们对采自安多地区的前中生代基底岩石及侏罗系沉积岩样品进行了岩石学、锆石U-Pb年代学及Hf同位素研究。研究结果表明:安多花岗片麻岩中锆石同时记录了510～505Ma岩浆年龄以及187Ma变质年龄;187Ma的变质锆石与510～505Ma的岩浆锆石具有相似的Hf同位素模式年龄(1.7～1.5Ga),表明寒武纪花岗岩主要来源于古老地壳重熔。碎屑锆石年代学分析结果揭示了安多微陆块石英岩具有498～484Ma、800～1000Ma和1800～1950Ma的年龄峰值,与南羌塘地体及特提斯喜马拉雅碎屑锆石年龄分布特征相似,表明其在早古生代时位于冈瓦纳大陆北部印度陆块边缘。南羌塘坳陷东南部中侏罗世砂岩及钙质砂岩碎屑锆石年代学分析结果显示其具有182～171Ma、450～600Ma、800～1000Ma、1800～1950Ma及2400～2600Ma的年龄峰值,这种年龄分布特征与安多微陆块及南羌塘地体相似,而与拉萨地体不同,说明南羌塘坳陷东南部下-中侏罗统物源主要来自安多微陆块及南羌塘地体,在早-中侏罗世时安多微陆块与南羌塘地体已经发生了碰撞造山。 相似文献
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利用EMP独居石定年法探讨浙闽武夷山地区变质基底岩石与花岗岩的年龄 总被引：11，自引：0，他引：11
利用EMP独居石定年法佐以LA-ICPMSU-Pb锆石定年法对浙闽武夷山地区5个前寒武纪变质基底岩石及附近5个显生宙花岗岩体进行年龄分析,结果显示独居石多为加里东期的产物且常呈现两期次的生长。前寒武纪变质基底岩石中,万全群杜潭组混合岩为533.0±44.4Ma及451.0±17.7Ma(锆石无年龄群落,但均大于800Ma),八都群堑头组混合岩淡色体为422.0±13.7Ma及360.0±14.9Ma(锆石年龄为436.4±4.7Ma),天井坪组云母石英片岩为443.3±11.3Ma(锆石无年龄群落,但主要散布在450～350Ma),麻源群南山组片麻岩不含独居石,但锆石年龄为859.1±9.2Ma,万全群黄潭组变粒岩不含独居石及可资定年的锆石。显生宙花岗岩的河田岩体(162.3±4.4Ma)及富城岩体(215.3±4.5Ma),均能符合原所预期之晚燕山期及印支期时代;另原认为分属印支期的玮埔(418.7±16.4Ma及360.6±15.3Ma)、海西期的真峰顶(429.3±15.6Ma)及加里东期的宁化(438.2±9.5Ma及348±20Ma)三岩体均获致加里东的年龄,有些并伴有海西期的讯号。这些结果指示:(1)华夏陆块遭受强烈加里东运动的影响,除了有大规模花岗岩侵入外,尚对前寒武基底进行强烈改造;(2)海西期的年龄主要由高铀独居石反应出来,锆石并未明确指出这期事件的事实尚难论断此区历经海西运动,若有此一运动其变质程度亦只影响到独居石;(3)太古代的锆石均为继承锆石,不足以支持武夷山地区有太古代的基底出露;(4)台湾西部大量早元古代的独居石源于武夷山地区的观点尚未落实。 相似文献
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撮科杂岩是最近在滇中地区发现的早前寒武纪基底杂岩，对深入探究扬子陆块早期演化具有重要意义.报道了4件代表性岩石样品的锆石U-Pb年代学和Hf同位素新数据.奥长花岗质片麻岩样品的结晶年龄为2 845±33 Ma，具有正的锆石εHf（t）值（1.7~4.6）和相对年轻的亏损地幔二阶段（TDM2）模式年龄（2.97~3.12 Ga），表明其形成于新生地壳的重熔.变二长花岗岩和片麻状花岗岩样品的结晶年龄分别为2 401±15 Ma和2 320±16 Ma，显示负的锆石εHf（t）值（-6.2~-0.8）和明显老的TDM2模式年龄（2.90~3.11 Ga），指示其来自古老地壳物质的重熔.斜长黑云碎粒岩的变质锆石的年龄为1 948±16 Ma，结合已有变质年龄揭示一期1.96~1.95 Ga区域变质作用.扬子陆块西南缘存在太古代结晶基底，并保留了与Nuna超大陆聚合有关的多期构造-岩浆事件的记录. 相似文献
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大兴安岭北部锆石U—Pb年龄对额尔古纳地块构造归属的制约 总被引：7，自引：0，他引：7
近几年,有关额尔古纳地块基底性质的锆石U-Pb样品测年,为讨论额尔古纳地块的构造归属提供了重要资料。绿林林场兴华渡口岩群二云母石英片岩的碎屑锆石U-Pb年龄892±20Ma、韩家园子兴华渡口岩群含十字石榴二云片岩的碎屑锆石U-Pb年龄1000～1100Ma、韩家园子兴华渡口岩群绿帘石化斜长角闪片岩的岩浆锆石U-Pb年龄816±27Ma、韩家园子达拉罕片麻杂岩(区域上相当于呼中地区凤水山片麻杂岩)的岩浆锆石U-Pb年龄981.0±6Ma～820±3Ma等数据,表明兴华渡口岩群及其相伴的变质深成岩形成于新元古代拉伸纪(青白口纪)至成冰纪(南华纪)早期。兴华渡口岩群普遍发育混合岩化。根据韩家园子东兴华渡口群的建群处混合岩化长英质脉体的变质锆石U-Pb年龄431.5±1.6～430±16Ma,及葛文春等对塔河地区早古生代花岗岩锆石的U-Pb年龄和Hf同位素研究表明,广布于额尔古纳地块上的众多早加里东期的后造山花岗岩是古生代早期额尔古纳地块快速隆升-剥蚀过程中所引起的降压导致下地壳物质熔融的产物;而兴华渡口群的混合岩化作用是早加里东期的后造山花岗岩侵位后,残余岩浆于早志留纪对兴华渡口群混合岩化作用的结果。部分测年样品中岩石的蚀源区或围岩的2800Ma、2600Ma、2400Ma、2200Ma、1888Ma等数据表明,额尔古纳地块内的确存在着相当于新太古代—早元古代的古老结晶基底。漠河地区门都里河一带出露的"兴华渡口群"的岩石组合为以含石墨为特征的孔兹岩系,可与黑龙江省东部麻山岩群、兴东岩群大马河岩组相对比。据此,额尔古纳地块的古老的结晶基底可能位于漠河地区门都里河一带,其东南侧出露的兴华渡口岩群系新元古代中期大陆边缘增生产物,早古生代后造山花岗岩的侵位、焊接,使其转化为稳定的陆块。 相似文献
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目前对松辽盆地是否存在前寒武纪结晶基底的认识存在分歧。笔者对松辽盆地北部早白垩世火山岩中锆石SHRIMP定年研究过程中,在多个样品中发现了古老锆石,其年龄表明这些锆石主要形成于前寒武纪,并且认为它们可能来源于盆地北部深层的基底岩石,是火山喷发过程中捕获的。锆石年龄大致可分为3组:(1848±34)Ma、(1600±29)Ma和(1293±41)Ma,指示了盆地基底在古元古代和中元古代期间经历的多次构造-岩浆作用事件,由此认为松辽盆地北部存在前寒武纪基底。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
19.
Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
20.
Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献