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1.
新疆彩霞山铅锌矿床成因分析及与MVT型矿床成因对比   总被引:3,自引:0,他引:3  
彩霞山铅锌矿床位于塔里木板块北缘活动带卡瓦布拉克-星星峡中间地块,容矿地层为长城系星星峡群,含矿岩性为角砾状硅化粉砂岩、白云石大理岩.通过对矿体特征、稳定同位素、流体包裹体、微量元素等分析,认为彩霞山铅锌矿床成因类型为碎屑岩-碳酸盐岩容矿的后生层控-热液改造型矿床.通过与我国广东凡口铅锌矿床、新疆卡兰古铅锌矿床成因对比研究发现,彩霞山铅锌矿床与二者成因特征类似,具有MVT型矿床成因特征.  相似文献   

2.
新疆阿克陶县塔木—卡兰古铅锌矿带矿体地质特征   总被引:8,自引:1,他引:7  
新疆塔木-卡兰古铅锌矿带矿床属于台缘碳酸盐岩容矿的超低温度热液成因。矿麻赋存于中泥盆统一下石炭统3个控矿的由碎屑岩与碳酸盐岩组成的古含水层中,角砾岩、矿体均具有复杂的产状,影响矿体产出了主要因素包括碎屑岩-碳酸盐岩界面、构造、低温热液交代作用以及容矿围岩的岩性,铅锌、铜、铁矿均是统一的成矿系统的一部分,锌(铅)矿围岩以碳酸盐岩为主,铜矿围岩为紫工色碎屑岩,铅矿围岩为灰白色碎屑岩,各主要矿空部及外围均存在较好的找矿前景。  相似文献   

3.
新疆霍什布拉克铅锌矿床地质、地球化学特征研究   总被引:3,自引:3,他引:3  
新疆霍什布拉克铅锌矿床的矿体和含矿地层的产状一致,主矿体的矿石具有条带状、纹层状构造,矿石中大量发育霉球状、管状和环带状生物结构,显示出层控、热水沉积成因的特点。含矿地层和矿石样品的主量元素PER图解显示含矿碳酸盐岩以含石膏的灰岩为主,围岩的白云岩化微弱,矿化与硅化关系密切。矿石、含矿碳酸盐岩和页岩、粉砂质灰岩和泥质粉砂岩等碎屑岩具有各自鲜明的微量元素分布特征,上层矿体矿石中较强的富集过渡族元素Ti、V、Cr、Mn、Co、Ni、非活动性元素Zr、Hf及大离子亲石元素Sr和Pb,亏损活动性元素Na、K、Rb、Ba和非活动性元素Nb、Th。其围岩重结晶泥晶灰岩富集Ti、Mn、Ni、Sr和Pb,亏损Na、K、V、Fe、Rb、Ba、Zr、Hf、Nb和Th。下层矿体的围岩页岩和泥质、粉砂质灰岩样品的微量元素分布在平均上地壳线附近,部分样品较明显的富集Ti、V、Cr、Mn、Co、Ni、Rb、Y、Zr和Hf,亏损Na、Fe、Sr、Nb。上层矿体矿石和下层矿体围岩中的部分碎屑岩富集强亲岩浆元素Cr、Co、Ni,且上层矿体矿石的稀土元素分布模式具有强的正Eu异常,部分下层矿体围岩具有较明显的正Eu异常。地质和地球化学特征显示该矿床属于热水沉积矿床中的SEDEX型矿床。  相似文献   

4.
泗顶铅锌矿床是桂北铅锌成矿区重要的大型铅锌矿床之一。对泗顶铅锌矿床铅锌矿石及围岩样品的稀土元素特征进行分析与对比,结果显示二者具有相似的稀土元素特征,都表现为LREE富集、HREE亏损、中等Eu负异常和无明显Ce异常,指示了浓缩海水与淡水掺合的还原性卤水参与了成矿过程,结合区域及矿床地质特征综合分析,认为泗顶铅锌矿床为中低温热液矿床,而同生沉积作用则是导致泗顶铅锌矿床远矿围岩—近矿围岩—蚀变围岩—矿石的稀土总量下降、配分曲线总体相似的主要原因。  相似文献   

5.
本文对三墩铜铅锌多金属矿进行了系统矿石微量元素、矿石硫化物S同位素研究,并结合矿床地质特征探讨其矿床成因。微量元素结果表明:三墩铜铅锌多金属矿成矿元素Cu、Pb、Zn明显富集,Ag、Au比较富集。稀土元素研究表明,矿石稀土总量较低,稀土模式配分曲线与花岗岩稀土模式配方曲线类似,成矿作用与岩浆作用相关。硫同位素分析结果暗示矿床硫同位素主要来自上地幔或下地壳的深源岩浆,有部分围岩地层物质的混入。矿床为中低温岩浆热液充填矿床。  相似文献   

6.
从矿床地球化学特征入手,对下金宝矿体矿石、矿体围岩的常量元素、稀土元素和微量元素特征进行探讨。结果表明:下金宝岩体的花岗斑岩类岩石属于硅酸过饱和类钙碱性过铝质岩石,属于A型花岗岩,且K、Nd、Hf、Th、Rb相对富集,而亏损Ta、Nb、Sr和Ti,说明其岩浆并非单纯来源于上地幔,在岩浆上升过程可能受到了地壳物质的混染;结合下金宝金矿床的控矿因素、蚀变分带特征、岩体地球化学特征、矿石结构构造、围岩蚀变、成矿温度,得出斑岩体是区内成矿的必要因素,下金宝金矿床应是以次火山热液作用为主的斑岩型金矿床。  相似文献   

7.
辽宁省宽甸县甬子沟滑石矿床分布于古元古界辽河群大石桥组三段的白云质大理岩中,矿床明显受控于北西向断裂,围岩蚀变以滑石化、透闪石化最为发育.矿床成因属中低温热液交代型层控矿床.依成矿地质条件和找矿潜力,寻找隐伏矿体、已知矿体外围是主要的找矿方向.  相似文献   

8.
新疆彩霞山铅锌矿微量和稀土元素地球化学特征初步研究   总被引:4,自引:0,他引:4  
彩霞山铅锌矿床是目前中天山地区发现的唯一规模可达大型的铅锌矿床,研究意义较大,但研究资料少.文章通过对矿区不同类型岩石的微量元素、稀土元素地球化学特征研究,探讨了岩石中微量元素的变化规律,建立了岩石的REE配分模式,并与不同类型矿石中微量元素和稀土元素地球化学特征进行对比,结果表明矿区白云石大理岩,尤其是多期活化一千麋岩化一滑石化白云石大理岩,其微量元素分布、稀土元素配分模式与不同类型矿石是趋于一致,显示蚀变白云石大理岩与成矿具有同源性.  相似文献   

9.
比利亚谷铅锌银矿位于海拉尔-根河中生代火山盆地北西缘。该矿床赋存于上侏罗统满克头鄂博组酸性火山岩中,受NW向断裂构造控制,主矿体呈脉状产出。火山岩围岩及主要矿石矿物的微量稀土特征相似:具有富集Rb、Th等大离子亲石元素,而亏损Sr、Nb、Ta等高场强元素的特点,表明其均产于板内构造环境。不同之处为:1矿石矿物的稀土微量元素总量明显小于火山岩围岩;2火山岩围岩呈现出明显的负Eu异常,而矿石矿物则具有强弱不等的正Eu异常。综合分析认为比利亚谷铅锌银矿为火山-次火山热液型矿床,其主要成矿作用与晚侏罗世-早白垩世(140Ma左右)火山活动有着密切联系,区域地质背景上对应于构造体制大转折的晚期,但是成矿期后矿体受到了120Ma大规模岩浆活动的影响,本期岩浆活动是区域岩石圈快速减薄引起,产生了一期深变质作用以及壳幔相互作用有关的深部流体活动,受其强烈改造,引起了矿石矿物微量稀土元素含量的改变。  相似文献   

10.
纳雍枝铅锌矿床位于五指山背斜南东翼,矿体产于下寒武统清虚洞组白云岩中,矿石矿物以闪锌矿为主。利用ICP-MS对矿床矿石、矿化岩石及围岩的微量及稀土元素进行测试,结果显示,矿石中以富集As、Cd、Sb、Bi、Ge、Mo、Sn、Cs、Tl等微量元素,亏损V、Cr、Co、Cu、Rb、Sr、Nb、Ba、Ta等元素。分散元素Ga、Ge、Cd富集与Zn、As呈正相关,说明流体本身富含该类元素。Ga/In值及矿石产出状态指矿床是中低温热液成因。矿石、矿化白云岩及围岩的稀土配分模式相似,均以Eu负异常为特征,不同矿石类型之间富集元素类型及富集程度差别较大,认为该矿床成矿物质可能来源于含矿地层本身和下伏的灯影组地层及深部基底。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

15.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

16.
17.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

19.
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2O3-SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.  相似文献   

20.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

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