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桂东南大容山-十万大山S型花岗岩带的成因：地球化学及Sr-Nd-Hf同位素制约 总被引：11，自引：9，他引：11
本文报道桂东南大容山-十万大山花岗岩带浦北岩体(东北带)、旧州岩体(中部带)和台马岩体(西南带)全岩的主、微量元素、Sr-Nd同位素和锆石的LAM-MC-ICPMS原位Hf同位素分析结果。岩石学及元素地球化学结果显示:上述三个岩体为典型S型花岗岩;高I_(Sr)(>0.721)和低ε_(Nd)(t)(-13.0～-9.9)意味着它们可能来自古老地壳的重熔。岩浆结晶(～230Ma)锆石的ε_(Hf)(t)值主要集中在-11～-9,相应的T_(DM2)模式年龄为1.9～1.8Ga;少数结晶锆石的ε_(Hf)(t)值逐渐升高到-4.5,T_(DM2)降低为～1.5Ga。捕获锆石(1681～384Ma)的的ε_(Hf)(t)值分布在-17.1～ 3.4,T_(DM2)主要集中在2.4Ga、1.9Ga和1.5Ga。大部分岩浆结晶锆石ε_(Hf)(t)值与根据"全岩ε_(Nd)(t)值和‘地壳Hf-Nd相关’预测值"基本一致,表明平均地壳存留年龄为1.9Ga的地壳是最重要的物源区。部分岩浆锆石与捕获锆石具有相同的T_(DM2)～1.5Ga,表明平均地壳存留年龄为1.5Ga的物源区参与了该花岗岩带的形成;由于缺少T_(DM2)>2.0Ga的岩浆锆石,少量平均地壳存留年龄为2.4Ga的再循环地壳物质参与了该花岗岩带的形成。因为缺少显著幔源特征的高ε_(Hf)(t)值锆石,本文认为地幔物质基本没有参与该S型花岗岩带的形成。 相似文献
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用LA-ICP-MS技术对北大别木子店地区细粒二长花岗岩脉中的锆石进行原位U-Pb年龄和Hf同位素测定,结果表明,该花岗岩形成于128.9±0.7Ma,为早白垩世岩浆活动的产物,在锆石中发现古元古代和新元古代的锆石核;锆石ε_(Hf)(t)介于-25.1~-19.2之间,平均值为-22.7,二阶段模式年龄T_(DM2)主要介于2115~2505Ma之间,2个继承锆石分析点分别给出了-10.5和6.5的ε_(Hf)(t)值,对应的二阶段模式年龄T_(DM2)分别为1151Ma和1709Ma。木子店地区细粒二长花岗岩脉的锆石年龄和Hf同位素特征表明,花岗岩为古元古代古老地壳物质部分熔融形成,岩石源区可能有中元古代地幔物质及太古宙古老地壳物质的贡献,形成于大别造山带从挤压向伸展的转换阶段。 相似文献
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本文报道了华北克拉通南缘鲁山县下汤地区早前寒武纪变质基底岩石的地球化学、锆石定年和Hf同位素组成。上太华岩群两个变质沉积岩样品的变质锆石年龄为1.91~1.93 Ga,由于变质作用强烈改造,碎屑锆石真正的形成年龄难以确定。碎屑锆石ε_(Hf)(t)和t_(DMW(CC))(Hf)分别为-0.26~10.41和2244~2958 Ma。一个变质辉长闪长岩样品的捕获锆石年龄为2.32 Ga,变质锆石年龄为1.93 Ga。捕获锆石的ε_(Hf)(t)和t_(DM2(CC))(Hf)分别为-1.79~2.22和2695~2940 Ma。两个片麻状奥长花岗岩样品的岩浆锆石和变质锆石年龄分别为1.93 Ga和1.92 Ga,岩浆锆石的ε_(Hf)(t)和t_(DM2(CC))(Hf)分别为-3.30~1.30和2481~2764 Ma。一个片麻状正长花岗岩样品的岩浆锆石和变质锆石年龄分别为1.93 Ga和1.92 Ga,岩浆锆石的ε_(Hf)(t)和t_(DM2(CC))(Hf)分别为-3.67~2.40和2415~2788 Ma。结合地球化学和前人研究结果,可得出如下结论:(1)上太华岩群形成时代形成于古元古代早期;(2)进一步支持了该区存在约2.3 Ga岩浆作用的认识;(3)发现广泛分布的1.91~1.93 Ga壳源奥长花岗岩和正长花岗岩;(4)确定1.91~1.94 Ga变质作用在该区广泛发育。 相似文献
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桂北地区丹洲群碎屑锆石LA-ICP-MS U-Pb年龄和Hf同位素特征及其地质意义 总被引：1，自引：0，他引：1
桂北丹洲群顶部拱洞组粉砂岩的碎屑锆石的阴极发光图像和Th/U(0.2~2.4)值显示,它们均为岩浆成因的锆石。锆石~(206)Pb/~(238)Pb年龄分布在730~769Ma和771~850Ma之间,这些锆石的Hf同位素成分范围较大,ε_(Hf)(t)值和二阶段Hf模式年龄(T_(DM2))分别为-18.4~11.4和1020~2812Ma。此外,样品中还有一些年龄较老的锆石颗粒,~(207)Pb/~(206)Pb年龄为1910~3140Ma,ε_(Hf)(t)值和二阶段Hf模式年龄(T_(DM2))分别为-13.6~3.4和2740~3635Ma。结合前人的研究推测,桂北丹洲群拱洞组沉积年龄小于等于706±10Ma,物源主要由扬子板块新元古代岩浆岩组成,也有少量太古宙岩浆岩的加入。推测中国华南地区存在对应于Rodinia超大陆聚合相关的格林威尔运动的响应。根据已测锆石的ε_(Hf)(t)值和Hf二阶段模式年龄推断,研究区地壳生长主要经历3个阶段:(1)3.64~3.25Ga,初生地壳出现在3.64Ga;(2)2.98~2.37Ga;(3)2.19~1.28Ga,地壳生长的主要时期。 相似文献
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本文采用LA-MC-ICP-MS方法获得班韦乌卢地块卡萨马北部正长花岗岩中锆石的~(207)Pb/~(206)Pb年龄加权平均值为2 011±20 Ma(N=17,MSWD=3.9),表明班韦乌卢地块基底中正长花岗岩主要形成于古元古代且可能与古元古代乌本迪构造带的活动有关。岩石中锆石Lu-Hf同位素的T_(DM2)年龄变化范围为3 018～2 184 Ma,明显大于锆石的形成年龄;具有不均一的ε_(Hf)(t)值(-7.1～6.6)显示形成正长花岗岩的原始岩浆具有壳幔混合的特点,可能为新太古代-古元古代地壳与幔源混染物质。 相似文献
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新疆中天山雅西辉长岩体出露于阿其克库都克—沙泉子断裂南侧,主要岩相为辉长岩,含少量辉石岩和闪长岩,岩体有明显的钒钛磁铁矿化。利用LA-MC-ICP-MS技术开展对辉长岩中锆石U-Pb年代学和Hf同位素研究,结果表明,锆石加权平均年龄为(311.7±3.5)Ma(MSWD=0.104,n=14),代表岩体侵位于晚石炭世。锆石(~(176)Hf/~(177)Hf)i值为0.282637~0.282945,对应的ε_(Hf)(t)值为+2.1~+13,平均值为+4.7,计算得到的锆石单阶段Hf模式年龄T_(DM1)为430~865 Ma,表明岩浆主要来源于亏损地幔并有壳源物质的加入。结合已有报道的东天山地区辉长岩形成时代和Hf同位素组成特征,本文认为雅西辉长岩的年代学和Hf同位素组成特征为准噶尔古洋壳在晚古生代期间向南俯冲提供了重要证据。 相似文献
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以赣西地区蒙山岩体为研究对象,通过对该岩体地球化学、锆石U-Pb年龄及Hf同位素的研究,探讨其岩浆物质来源及构造背景。该岩体经历了印支期、燕山期岩浆侵入活动,形成六种岩石类型,LA-ICP-MS锆石U-Pb年龄分别为224.0±2.10 Ma(n=19,MSWD=1.9)、223.0±2.20 Ma(n=21,MSWD=2.6)、222.0±2.80 Ma(n=21,MSWD=2.7)、220.0±1.90 Ma(n=16,MSWD=1.5)、217.0±3.70 Ma(n=8,MSWD=1.8)、142.0±0.98 Ma(n=21,MSWD=1.4),表明岩体经历了印支期、燕山期两期岩浆活动。印支期花岗质岩石地球化学具高硅富钾、准铝-过铝质特征;微量元素富集高场强元素Zr、Hf、Th、U和稀土元素La、Ce、Sm、Nd、Y,明显亏损Rb、Ba、Sr、Ti、P;稀土元素分馏程度不高,δEu介于0.03~0.15,具强Eu负异常,Ce异常不明显,稀土配分曲线呈“V”型;为同源岩浆演化的特点。CaO/Na_(2) O比值<0.3、Rb/Sr>5,岩石二阶段模式年龄T DM2主体介于868~1465 Ma,为中-新元古代,εHf(t)对应的T DM2值显示,岩体物源起源于成熟地壳,后期有大量新生地壳物质的加入,表明岩石来源于含水矿物(如白云母、绿帘石/黝帘石)的脱水反应导致成熟度高地壳物质的熔融而形成。在花岗岩构造环境判别图上,投于碰撞大地构造背景上的花岗岩和造山后花岗岩类(POG)区域,锆石U-Pb年龄表明成岩时段滞后于印支运动高峰期(258~243 Ma),为受印支运动造成华南地壳加厚滞后,地壳进入伸展阶段,减压熔融形成的花岗质岩浆。 相似文献
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《西北地质》2021,(3)
白海子南岩体是库鲁克塔格地区典型的古生代花岗质侵入岩。深入了解该岩体岩石成因及物质来源,对研究库鲁克塔格地区构造背景及古生代地壳演化过程具有重要意义。笔者对白海子南岩体进行了系统的全岩Sr-Nd和锆石Hf同位素及锆石微量元素研究。结果表明,该岩体具有中等I_(Sr)(0.710 01～0.712 87)比值,富集的ε_(Nd)(t)值(-21.01～-18.07)和ε_(Hf)(t)值(-26.55～-17.28),对应的Nd二阶段模式年龄(T_(DM2))和Hf模式年龄(T_(DMC))分别为2.60～2.84 Ga和2.43～3.00 Ga,表明其是古元古代早期—新太古代地壳物质再循环的产物。锆石微量元素分析表明,该岩体锆石为壳源岩浆锆石,T_(Zr)均值为745℃,T_(Ti)均值为692℃,属于"冷"岩浆,岩体形成于主动大陆边缘,是南天山洋向南俯冲到塔里木克拉通之下后期阶段的产物,俯冲过程中幔源岩浆底侵产生的余热为该岩体熔融提供热源。在库鲁克塔格地区发现多期次古生代花岗质侵入岩,这些岩体的ε_(Nd)(t)值和锆石ε_(Hf)(t)值随年龄的减小呈现先上升后下降的趋势,结合前人已有资料,推测在南天山洋向塔里木克拉通俯冲过程中,库鲁克塔格地区奥陶纪—早石炭世地壳演化经历了先减薄再加厚的演化过程。 相似文献
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西秦岭厂坝、黄渚关岩体的锆石U-Pb年龄、Hf同位素组成及其地质意义 总被引：1，自引：1，他引：0
厂坝及黄渚关岩体位于商丹缝合带和勉略缝合带之间的秦岭微板块,主要由花岗闪长岩及二长花岗岩组成。LA-MC-ICP-MS锆石U-Pb定年显示,黄渚关及厂坝岩体的演化可划分为中三叠世(229 Ma)和晚三叠世(215~209 Ma)2期。黄渚关中心部位的年龄((229.2±1.0)Ma)老于边部岩体((215.8±0.8)Ma),厂坝岩体中心部位年龄((218.3±1.2)Ma),老于边部年龄((209.4±0.8)Ma),结合岩体中心相和边缘相渐变的特征,说明2个岩体是由中心部位侵位,边部岩体的侵位冷却时间较晚造成的。黄渚关岩体的ε_(Hf)(t)为-3.13~-14.51,集中于-10~-6;厂坝岩体的ε_(Hf)(t)为-5.17~-14.51,集中于-12~-6。在ε_(Hf)(t)-t图解中,ε_(Hf)(t)均在球粒陨石之下和古元古地壳演化线之上;二阶段模式年龄黄渚关岩体主要集中在1.8~2.1 Ga,厂坝岩体主要集中在2.0~2.2Ga,结合继承锆石年龄1932 Ma、2039 Ma,表明古元古代地层可能为岩体的源区之一,在黄渚关岩体发现的暗色包体说明岩浆在上升的过程中发生了壳-幔岩浆的混合。因此,笔者认为黄渚关、厂坝岩体起源于古老地壳重熔,并在上升的过程中与幔源岩浆发生一定比例混合。 相似文献
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西南三江地区是我国重要的成矿区带之一,具有复合叠加成矿特征。阿德博独居石矿床位于云南省金平县境内,印度地块、哀牢山-金沙江断裂带南侧,属于哀牢山隆起的东南延伸部分。该矿床赋存于花岗质风化壳中,岩性主要有片麻状花岗岩、二长花岗岩、花岗片麻岩;矿体中主要含有独居石,少量磷钇矿、锆石、金红石、钛铁矿、榍石。岩体中片麻状花岗岩的锆石U-Pb谐和年龄为31.40±0.16Ma(MSWD=7.8),二长花岗岩的锆石U-Pb谐和年龄为34.52±0.22 Ma(MSWD=1.3),表明阿德博岩体形成于新生代古近纪,与三江地区构造体制转换阶段富碱斑岩体的成矿时期一致。片麻状花岗岩中45个锆石Hf同位素数据结果较均一,(~(176)Hf/~(177)Hf)i比值范围为0.282583～0.282712,平均为0.282633,εHf(t=31.40 Ma)范围为-6.00～-1.44,平均值为-4.21。二长花岗岩中13个锆石Hf同位素数据结果变化范围较大,(~(176)Hf/~(177)Hf)i=0.282484～0.282814(平均值为0.282681),εHf(t=31.40 Ma)=-9.43～2.22(平均值为-2.45);其中有8粒锆石的εHf(t)为负值,5颗锆石的εHf(t)为正值,暗示岩体的源区主要为地壳物质的部分熔融,可能有地幔物质的混合。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
19.
Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
20.
Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献