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1.
东昆仑可支塔格蛇绿混杂岩的地质地球化学特征 总被引：1，自引：0，他引：1
东昆仑可支塔格蛇绿混杂岩属于木孜塔格-鲸鱼湖大断裂的西延部分,主要由辉橄岩、辉长岩、闪长岩、斜长花岗岩、辉绿岩、玄武岩及硅质岩等组成,形成时代为早石炭世。为构造强烈破坏的蛇绿混杂岩,形成于俯冲带环境,属SSZ型蛇绿岩。其中辉橄岩以相对低SiO2、TiO2、Al2O3和CaO、高MgO为特征,贫有色金属成矿元素,富集相容元素Cr、Ni、Co。稀土总量低,接近于球粒陨石稀土元素总量,以LREE略富集为特征。闪长岩SiO2、K2O含量较低,MgO、CaO、Na2O较高,稀土总量高,∑REE为90.95μg/g,LREE富集。斜长花岗岩SiO269.8%,Na2O>K2O,K2O/Na2O为0.78,A/CNK为1.68,具有大洋斜长花岗岩的岩石化学特征。闪长岩、斜长花岗岩的微量元素特征相似,表现为大离子亲石元素K、Sr、Rb、Ba相对富集,高场强元素Nb、Ta、Zr、Hf相对亏损。研究表明,辉橄岩来源于亏损的地幔岩,接近于强烈亏损的方辉橄榄岩,而明显不同于结晶分异作用成因的超镁铁质岩石。闪长岩、斜长花岗岩为蛇绿混杂岩的浅色岩组分,是地幔岩浆结晶分异的产物。 相似文献
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云海铜镍矿位于觉罗塔格构造带西段,成矿岩体为多期次侵入的杂岩体,岩体分异演化充分,镁铁质和超镁铁质岩石均有发育,主要岩石类型为角闪辉石岩、橄榄苏长岩、辉长岩、闪长岩。主量元素化学组成表明,该杂岩体属拉斑玄武岩系列,岩石具同源演化特征,显示高铁、高镁、低钛、低铝特征,富集大离子亲石元素Rb,Ba,亏损Nb,Ta,轻稀土富集。岩浆源区有部分熔融而交代的岩石圈地幔,岩浆在上升过程中受到地壳物质混染,发生橄榄石、斜方辉石、斜长石的分离结晶。岩体形成于早二叠世,为构造活动和地幔柱双重作用下的产物。 相似文献
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《西北地质》2020,(3)
笔者在野外调查和花岗伟晶岩带划分的基础上,通过对塔埠头稀土矿床岩相学、同位素年代学及地球化学的分析研究,确定了成岩、成矿年龄,探讨了成矿物质来源及花岗伟晶岩与稀土成矿的联系,建立了该矿床成因模式。元素地球化学特征显示,含稀土的花岗伟晶岩具有低硅、低碱、富铁过铝质特征,钾长-斜长花岗伟晶岩、钾长花岗伟晶岩和钾长花岗岩3类花岗伟晶岩均具有高硅高碱低铁过铝质的特征,轻重稀土元素分异较明显,亏损Ta、Ti、Nb、P等高场强元素,富集K、Rb等大离子亲石元素。LA ICP-MS同位素测年结果表明,含稀土花岗伟晶岩氟碳铈矿Th-Pb测年结果为(128.5±2.0)Ma、(134.4±1.2)Ma,指示稀土成矿发生在中生代白垩纪。 相似文献
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青海省乌兰地区肯得隆富钛铁矿镁铁-超镁铁质岩体的岩石与矿石成因 总被引：3，自引：3，他引：0
肯得隆镁铁-超镁铁质岩体位于青海柴达木盆地北缘欧龙布鲁克微陆块中。岩体为半隐伏岩体,地表零星出露。岩体岩石类型丰富,有蛇纹岩、单辉橄榄岩、二辉橄榄岩、橄榄二辉岩、橄榄单辉岩、橄榄苏长辉长岩、橄榄角闪辉长岩、角闪辉长岩、蚀变辉长岩、斜长岩。辉长岩、辉石岩中见稀疏浸染状、星点浸染状钛铁矿。钛铁矿含量以5%~10%为主,个别含量可达10%~20%,具海绵陨铁结构,属岩浆晚期矿化作用产物。岩体中辉长岩锆石U-Pb年龄为491±3Ma(MSWD=0.7)。岩体岩石的化学组成属于拉斑玄武质系列,各岩性岩石的稀土元素配分形式基本一致,均呈轻稀土富集的右倾型。微量元素特征表现为富集大离子亲石元素(Cs、Rb、Ba、Th、U),亏损高场强元素(Nb、Ta、Ti、P)。岩体(87Sr/86Sr)i值为0.704731~0.710280,εNd(t)=-4.49~+0.83。岩浆在冷凝过程中发生了橄榄石-单斜辉石-斜方辉石-斜长石-普通角闪石的分离结晶作用。岩石地球化学特征表明岩体受到同化混染作用。肯得隆岩体的原生岩浆为普通的玄武质岩浆,源自被古生代俯冲熔/流体交代的富集岩石圈地幔。钛铁矿的富集机制是:岩浆在氧逸度低于NNO条件下经历了相对高度的分异演化而最终达到钛铁矿富集。 相似文献
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新疆可支塔格蛇绿混杂岩位于青藏高原北缘东昆仑西段,属于木孜塔格-鲸鱼湖大断裂的西延部分。主要由辉橄岩、辉长岩、闪长岩、斜长花岗岩、辉绿岩、玄武岩及硅质岩等组成,形成时代为早石炭世。其中辉橄岩具有高Mg,贫Al,Ca,低硅、低碱的特点,富集相容元素Cr,Ni,Co。稀土总量低,接近于球粒陨石稀土元素总量,以LREE略富集为特征。闪长岩SiO2,K2O含量较低,MsO,CaO,Na2O较高,稀土总量高,∑REE为90．95×10^-6,LREE富集。斜长花岗岩SiO2 69．8％,Na2O〉K2O,K2O／Na2O为0．78,A／CNK为1．68,具有大洋斜长花岗岩的岩石化学特征。闪长岩、斜长花岗岩的微量元素特征相似,表现为大离子亲石元素K,Sr,Rb,Ba相对富集,高场强元素Nb,Ta,Zr,Hf相对亏损。研究表明,辉橄岩来源于亏损的地幔岩,接近于强烈亏损的方辉橄榄岩,而明显不同于结晶分异作用成因的超镁铁质岩石。闪长岩、斜长花岗岩为蛇绿混杂岩的浅色岩组分,是地幔岩浆结晶分异的产物,但可能受到了围岩的混染和后期热液交代影响。 相似文献
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湖南仁里稀有金属矿田是中国近年来新发现的一处重要的花岗伟晶岩型铌、钽、锂等稀有金属矿产地,文章针对矿田含锂伟晶岩地球化学特征、成矿时代及其与花岗岩的关系,选取传梓源锂铌钽矿床内规模最大的206号锂辉石伟晶岩脉开展地球化学和白云母Ar-Ar定年工作,并与区内其他伟晶岩、花岗岩的地球化学特征、成岩时代对比分析.传梓源206号锂辉石伟晶岩属高分异稀有金属伟晶岩,形成时代为(135.4±1.4)Ma,岩石地球化学表现为高硅、高铝、低钙、相对富碱、钙碱性及过铝质特征;稀土元素总量很低,以轻稀土元素为主;微量元素富集Cs、Rb、U、Ta、Nb、Zr、Hf,相对亏损Ba、Ti,Zr/Hf、Nb/Ta比值低且集中.幕阜山地区稀有金属成矿可分为2期:第1期稀有金属成矿时代约145 Ma,与燕山早期岩浆活动有关;第2期稀有金属成矿时代135～125 Ma,为主成矿期,该期稀有金属伟晶岩与燕山晚期的二云母二长花岗岩存在成因联系,两者为同源岩浆连续结晶分异过程中不同阶段的产物.稀有金属富集成矿经历了岩浆-热液两阶段作用,Be、Nb、Ta、Li、Rb、Cs等稀有元素的富集多发生于岩浆结晶分异晚期,热液作用使Ta、Li、Rb、Cs再次富集. 相似文献
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山东沂水杂岩中变基性岩的岩石地球化学特征及锆石SHRIMP U-Pb定年 总被引：7，自引：0，他引：7
山东沂水杂岩由新太古代岩浆杂岩和中太古代的变质杂岩组成,其后者中的变基性岩石,特别是基性麻粒岩,常与紫苏花岗岩紧密伴生,而且多呈大小不等的包体或呈层状体产出。本文主要对变基性岩进行岩石地球化学和锆石SHRIMP UPb定年研究。根据岩石学特征,可将变基性岩分为三类：含紫苏辉石斜长角闪岩、含石榴子石角闪二辉斜长麻粒岩和含尖晶石—石榴子石的角闪二辉麻粒岩。它们原岩分别为安山质玄武岩、高铁镁质玄武岩和玄武质科马提岩（？）。三类岩石稀土元素和微量元素配分有一定差别：第一类含紫苏辉石斜长角闪岩富集轻稀土和大离子亲石元素,亏损Nb、Ta、Zr、Hf等高场强元素;后二类麻粒岩相变质岩的稀土配分模式为近平坦型或轻稀土略为富集, K、Rb、Ba等元素也轻微富集,其他元素与MORB的比值接近于1。变基性岩中锆石定年结果显示有四组年龄值,其中2719Ma和2560～2607Ma分别代表早期麻粒岩相变质作用的年龄下限和上限;2509～2522Ma代表另一期角闪岩相—麻粒岩相变质作用的时代,发生在沂水岩浆杂岩侵入之后;2485Ma和2497Ma代表与流体作用有关的变质作用和新生锆石的形成年龄。 相似文献
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大水沟金矿位于东昆仑中段,目前矿区西部共圈定金矿(化)体9条,结合化探异常和区域地质背景对比,认为该区具有良好的找矿前景。本文利用LA-MC-ICPMS锆石U-Pb定年技术,首次获得与金矿成矿有密切关系的英云闪长岩加权平均年龄为(239.5±0.9)Ma,厘定为中三叠世;岩石地球化学研究表明,英云闪长岩为钙碱性系列岩石,轻稀土富集,轻重稀土分馏明显,具弱的负铕异常,岩体明显富集大离子亲石元素(Rb、K)、活泼不相容元素Th、轻稀土元素和Pb,相对亏损高场强元素(Nb、Ta、P、Ti),Rb/Sr、Nb/Ta等特征反映出岩石具有壳幔混合岩浆的特点。结合东昆仑地区已有的年代学资料、岩石地球化学和区域地质构造演化分析,本文认为英云闪长岩形成构造环境为俯冲阶段;俯冲作用促进了幔源流体的运移,在构造有利部位沉淀形成金矿。 相似文献
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【研究目的】为解决敦煌地块敖包山晶质石墨矿集区晶质石墨矿床研究程度较低的问题,通过对该区变质岩原岩特征及古构造环境进行深入研究,以期为该区的成矿规律研究提供地质依据。【研究方法】本文运用岩石地球化学方法对该区变质岩进行原岩恢复,探讨其形成时的古构造环境。【研究结果】二云石英片岩、黑云斜长片麻岩和斜长角闪岩均具有轻稀土富集的特征。斜长角闪岩K2O2O,具有弱的Nb、Ta亏损和强烈的Zr、Hf亏损,LREE/HREE=2.21～6.97,轻重稀土元素分馏程度较弱;黑云斜长片麻岩和二云石英片岩K2O>Na2O,富集大离子亲石元素Rb、K等,亏损Ba、Nb、Ta、Zr、Hf、Ti、Sr等元素,具有明显的Eu负异常,LREE/HREE平均值分别为12.44和8.89,轻重稀土元素分异较强烈。【结论】敖包山晶质石墨矿集区变质岩原岩形成于浅水区,水动力环境较弱。斜长角闪岩的原岩为亚碱性基性火山岩,形成于岛弧环境;二云石英片岩和黑云斜长片麻岩的原岩为页岩、黏土岩,构造环境为活动大陆边缘,古沉积环境... 相似文献
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对辽东桓仁地区辽河群高家峪组中出露的斜长角闪岩进行岩石学、地球化学及年代学研究,显示高家峪组中的斜长角闪岩原岩为基性玄武岩,可划分为低Ti E MORB及高Ti OIB两种类型:低Ti型样品原岩属拉斑玄武岩系列,轻微亏损Nb、Ta、Zr,明显亏损P,弱轻稀土富集、重稀土亏损,具有E-MORB地球化学特征;高Ti样品原岩属碱性玄武岩系列,富集Rb、Th、U等大离子亲石元素,轻稀土富集、重稀土亏损,具有OIB地球化学特征.两类斜长角闪岩具有较低的MgO、Cr、Ni含量及Mg#值,说明它们原岩不是原始岩浆,而是通过不同矿物相分离结晶作用形成.锆石U-Pb测年表明低Ti型和高Ti型斜长角闪岩成岩年龄分别为2158±15 Ma、2173±12 Ma,变质年龄分别为1870±6 Ma、1861±7 Ma.区域地质特征及岩石成因研究共同指示两类斜长角闪岩形成于弧后盆地环境,辽吉地区在古元古代早期可能处于活动大陆边缘弧后盆地构造环境,辽吉造山带的形成与弧-陆碰撞有关. 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
19.
Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
20.
Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献