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1.
中新世是青藏高原隆升、增厚的重要时期,并且在这一时期内拉萨地块广泛发育碰撞后岩浆岩。本文对南拉萨地块米拉山地区的钙碱性钾质火山岩进行了锆石U-Pb年代学、Lu-Hf同位素和全岩主量、微量元素的测定与系统研究。米拉山中新世火山岩为粗面英安岩、英安岩和流纹岩(SiO2=59.89%~71.78%)。锆石U-Pb定年结果为16.1±0.2Ma~20.4±0.3Ma,表明其喷发时代为中新世。岩石具有较高的Al2O3含量(13.54%~16.31%),低MgO(0.46%~1.95%)、高Sr(388×10-6~804×10-6)、低Y(6.55×10-6~11.20×10-6)和Yb(0.70×10-6~1.07×10-6)的特征,具有较高的Sr/Y值(51~80)、低相容元素(Cr=4.26×10-6~32.53×10-6,Ni=4.16×10-6~25.75×10-6)和弱Eu负异常。岩石具有轻稀土元素和Rb、Th、U、K等元素富集、重稀土元素和高场强元素Nb、Ta、Ti亏损的特征。米拉山中新世火山岩显示出埃达克质岩石的地球化学特征,可能来自于的镁铁质加厚下地壳的部分熔融,推测下地壳源区是石榴石角闪岩。锆石εHft)值为+2.2~+7.8,表明源区为新生地壳物质,有俯冲板片熔体加入。米拉山中新世火山岩的喷发时代与米拉山断裂活动时间一致,二者可能同为拉萨地块岩石圈拆沉的结果。  相似文献   

2.
曲林岩体位于冈底斯带中段的南缘,为渐新世-中新世复合岩体,主体为粗粒花岗斑岩,被后期煌斑质、花岗闪长质和花岗质岩脉切割,是多期岩浆作用的产物,出露面积约8km2。花岗斑岩两组样品(T0849-PG和T0849-G)的锆石U-Pb定年结果分别为29.7±0.1Ma和30.0±0.2Ma。花岗斑岩为高钾,准铝质,低MgO,高度富集轻稀土元素(LREE)和大离子亲石元素(LILE),亏损重稀土元素(HREE)和高场强元素(HFSE)。此外具有高Sr、Sr/Y、(La/Yb)N;低Y和Yb,弱Eu负异常等特征。岩体内发育一系列近南北向展布的花岗闪长玢岩脉,其中两组样品的锆石U-Pb定年结果分别为15.5±0.1Ma(T0848-PY)和14.4±0.1Ma(T0850)。两条花岗闪长玢岩脉具有与岩体主体相似的稀土和微量元素分布模式,同样富集轻稀土及大离子亲石元素,亏损重稀土及高场强元素。花岗斑岩的87Sr/86Sr(i)=0.706102~0.706202,εNdt)=-0.6~+0.6,锆石εHft)=+4.9~+7.9;花岗闪长玢岩脉的87Sr/86Sr(i)=0.705429~0.705474,εNdt)=-1.4~-0.2,锆石εHft)=+2.6~+7.6。本文数据和文献数据结果表明:曲林花岗斑岩与花岗闪长玢岩脉均来源于加厚南拉萨下地壳的部分熔融,很可能与增厚的深部岩石圈的拆沉或俯冲印度岩石圈的撕裂诱发软流圈上涌有关。  相似文献   

3.
甜水海地块作为西昆仑-喀喇昆仑造山带重要的组成部分,夹持于麻扎-康西瓦板块缝合带和洪山湖-乔尔天山板块缝合带之间,其构造属性的探讨对认知西昆仑地区早古生代地质演化具有重要的科学意义。笔者在甜水海地块中部麻扎地区通过野外填图新发现并厘定出一套火山岩-沉积岩组合,主要由安山岩、英安岩、流纹岩及其火山碎屑岩和少量沉积岩组成;与安山岩互层产出的英安岩和流纹岩锆石U-Pb年龄为519~513Ma,表明这套火山-沉积地层形成于中寒武世。该火山岩套的地球化学特征为:安山岩SiO2含量为57.0%~67.2%,具有高MgO(1.91%~7.17%)含量和Mg#值(39.1~65.3,平均值为55.0),较高Cr(31.0×10-6~190×10-6)和Ni(12.2×10-6~121×10-6)含量,低FeOT/MgO比值(1.12~3.26),低Al2O3(13.7%~17.3%)和K2O(1.12%~5.52%)含量的特征,属于低铁钙碱系列高镁安山岩-镁安山岩;英安岩较安山岩SiO2含量高(63.8%~71.8%),具有相似的Al2O3(13.4%~15.4%)含量,低MgO(0.28%~1.19%)含量和Mg#值(9.98~36.5,平均值为25.3),低Cr(11.5×10-6~25.2×10-6)和Ni(4.33×10-6~11.8×10-6)含量,高FeOT/MgO比值(3.64~18.9)和K2O(4.84%~9.27%)含量的特征,属于高钾钙碱性系列。安山岩和英安岩总体表现出右倾轻稀土富集分配模式,富集Rb、Ba、K、Th等大离子亲石元素,亏损Nb、Ta、Ti高场强元素,具有典型的岛弧岩浆岩特征。野外调查表明,安山岩与英安岩在空间上相邻,呈互层产出,且它们都出露于中寒武系地层中,暗示了二者在成因上紧密相联。岩石地球化学特征指示了安山岩和英安岩可能源于富集地幔楔不同比例的部分熔融作用,所产生的岩浆在上升过程中又遭受了不同比例的地壳混染。推测麻扎地区寒武纪火山岩形成于原特提斯洋向南俯冲消减机制下的岛弧构造环境,同时结合区域资料,认为在寒武纪甜水海地块存在两期岩浆作用,在早寒武系末期(~520Ma)原特提斯洋发生双向俯冲,甜水海地块北缘转化为活动大陆边缘。  相似文献   

4.
扬子陆块西缘晚中元古代地质演化史一直存在较大争议,本文选择以扬子西缘元谋杂岩中一套二长花岗岩为研究对象,开展岩相学、锆石U-Pb年代学、全岩地球化学等综合研究,为认识和理解扬子西缘晚中元古代地质演化提供支撑。两件元谋二长花岗岩样品的LA-ICP-MS锆石U-Pb年龄分别为1086±10 Ma(MSWD=1.4,n=50)和1099±10 Ma(MSWD=1.8,n=58)。所有样品具有高硅(SiO2为69.44%~73.98%)、富碱(Na2O+K2O为6.11%~7.72%)、贫钙(CaO为0.39%~1.46%)、贫镁(MgO为0.52%~0.76%)、低钛(TiO2为0.30%~0.59%)的特点,同时表现出强过铝质(A/CNK=1.19~1.35)及中钾钙碱性–钾玄岩系列特征。它们具有高的稀土元素总量(∑REE=211.60×10-6~349.01×10-6),呈现轻稀土元素富集和重稀土元素亏损((La/Yb)N=4.32~7.36);富集Rb、U、Th等大离子亲石元素和Zr、Th、Hf等,亏损Nb、Ta、Ba等元素,并具有明显的负Eu异常(δEu=0.46~0.59),锆石饱和温度介于827~912℃之间,展示了A型花岗岩的属性。这些二长花岗岩可能是通过中上地壳的中酸性火成岩的部分熔融形成,结合前人的研究成果,它们最可能形成于弧后的伸展环境,综合扬子陆块周缘晚中元古代的岩浆记录,元谋杂岩中1.09 Ga二长花岗岩的形成应与扬子陆块开始参与Rodinia超大陆聚合有关。  相似文献   

5.
园珠顶铜钼矿床位于钦杭成矿带南段的大瑶山隆起北缘,为大型斑岩型铜钼矿床。通过LA-ICP-MS锆石U-Pb同位素测年,获得了花岗斑岩的高精度成岩年龄,为(154.3±1.7) Ma (n=12,MSWD=3.1),为晚侏罗世岩浆活动的产物,与辉钼矿的Re-Os同位素年龄155 Ma相吻合。岩石地球化学分析表明,园珠顶花岗斑岩高硅〔w(SiO2)为68.81%~70.21%〕、富碱〔w(Na2O)+w(K2O)为6.78%~8.01%〕、准铝质-弱过铝质(A/CNK为0.96~1.04);稀土元素总量中等(ΣREE 为142.15×10-6~170.83×10-6),富集轻稀土元素(ΣLREE 为135.05×10-6~162.34×10-6),轻重稀土元素分馏明显〔(La/Yb)N=30.97~32.10〕,弱的Eu负异常(δEu=0.86~0.89),稀土元素配分模式总体右倾;岩石相对富集Rb、K等大离子亲石元素(LILE)及高场强元素Th、U,亏损Nb、Ta、P、Ti等高场强元素(HFSE)及部分大离子亲石元素Ba、Sr。LA-MC-ICP-MS锆石Hf 的原位分析表明,176Hf/177Hf值变化于0.282 500~0.282 801之间,εHft)值介于-6.27~4.19。综合分析表明,园珠顶花岗斑岩为准铝质-弱过铝质的I型花岗岩,具有壳幔混合源成因,锆石εHft)值反映了园珠顶花岗斑岩的成岩源区较为复杂,总体具亏损岩浆源区的特征,以幔源物质为主,但在岩浆侵位过程中遭受了古老地壳物质的混染。结合区域构造背景和前人研究成果,认为园珠顶斑岩体及铜钼矿,与钦杭成矿带北段的永平铜矿具有一致的成岩成矿构造背景,形成于板块俯冲环境。  相似文献   

6.
沂沭断裂带内发育了大量的中生代火山岩,其成因研究对剖析断裂带活动规律具有重要意义。本文对断裂带北段潍坊、安丘、鄌郚地区中生代火山岩进行了详细的岩石学、锆石U-Pb年代学和主量元素、微量元素、Sr-Nd-Pb同位素分析。探讨了沂沭断裂带中生代火山岩成因及其形成的地球动力学过程。断裂带北段火山岩年龄集中在131~124Ma之间,喷发于早白垩世。岩石为一套高钾钙碱性火山岩,包括玄武安山岩、粗安岩、粗面岩、英安岩。火山岩富集Rb、Ba等大离子亲石元素,相对亏损Nb、Ta、Ti等高场强元素。稀土元素含量高(∑REE=140.5×10-6~433.1×10-6),富集轻稀土、亏损重稀土(∑LREE/∑HREE=9.8~31.0),无明显的Eu负异常。火山岩具有富集且变化范围较大的Sr-Nd-Pb同位素组成,(87Sr/86Sr)i=0.708054~0.711692,εNdt)值为-15.3~-7.4,(206Pb/204Pb)i=17.213~17.962,(207Pb/204Pb)i=15.425~15.590,(208Pb/204Pb)i=37.597~38.365。研究表明,高钾钙碱性火山岩的源区与区域基性岩源区一致,均为富集岩石圈地幔。玄武安山岩、粗安岩、粗面岩经基性岩浆分离结晶作用形成,英安岩则遭受了华北下地壳强烈混染。三叠纪末期,由于扬子板块向华北克拉通俯冲,扬子地壳析出的流体/熔体交代了华北古老岩石圈地幔,形成富集岩石圈地幔。早白垩世,受古太平洋板块俯冲和后撤作用,富集岩石圈地幔部分熔融形成基性岩浆,岩浆在上升过程中发生分离结晶作用,受沂沭断裂深切作用影响,部分地区遭受华北下地壳混染,最终形成区内各类高钾钙碱性火山岩。  相似文献   

7.
江西省都昌县阳储岭钨钼矿床位于江南造山带东段,为准确厘定阳储岭钨钼矿床的成岩成矿时代,本次在详实的野外地质调查基础上,对阳储岭成矿花岗闪长斑进行锆石U-Pb定年工作,同时开展辉钼矿Re-Os同位素定年研究。LA-ICP-MS锆石U-Pb年龄为(145.08±0.35)Ma(MSWD=0.51,n=7);辉钼矿Re-Os模式年龄为(143.3±2.0)Ma~(145.5±2.2)Ma,等时线年龄为(145.4±1.0)Ma。阳储岭成矿花岗闪长斑岩锆石U-Pb年龄与辉钼矿Re-Os等时线年龄基本一致,表明阳储岭钨钼矿床成岩成矿时代约为145 Ma。辉钼矿中Re含量为16.62×10-6~87.76×10-6,平均值为44.68×10-6,与壳幔混源岩浆热液矿床中Re的含量相似,指示阳储岭钨钼矿床成矿物质来源于壳幔混源。  相似文献   

8.
周玉  周雄  张贻  秦志鹏  贾志泉  梁兵 《中国地质》2022,49(6):1984-2001
研究目的】查明松潘—甘孜地块东南部花岗岩地球化学及构造演化特征,对在该区寻找稀有金属矿产具有重要意义。【研究方法】在野外地质调查基础上,采集了地块东南部前人研究未涉及的苏地岩体二长花岗岩样品开展了镜下鉴定、岩石地球化学及锆石LA-(MC)-ICP-MS U-Pb和Lu-Hf同位素测试工作。【研究结果】结果表明,苏地岩体二长花岗岩SiO2含量为63.72%~66.48%,中—高钾、富钠、贫钙,AR值为1.44~1.83,A/CNK值为0.98~1.16,为中—高钾钙碱性系列;岩石相对富集K、Rb、Cs等大离子亲石元素(LILE),亏损Nb、Ta、Ti等高场强元素(HFSE);岩石稀土总量为157.16×10-6~187.88×10-6,LREE/HREE为6.26~9.46,δEu为0.62~0.74,具有弱—中等的负铕异常;锆石U-Pb定年结果为(221.1±1.5)Ma(MSWD=0.30,n=22)和(214.5±1.5)Ma(MSWD=0.22,n=22),表明苏地岩体原始岩浆初始结晶时代为晚三叠世中期;锆石Lu-Hf同位素εHf(t)和TDM2分别为-6.56~-4.12和1.67~1.51 Ga。【结论】综合分析认为苏地二长花岗岩为较为典型的I型花岗岩,其可能为源于下地壳的初始岩浆于晚三叠世中期在造山碰撞闭合转入伸展体制下上升侵位过程中形成。松潘—甘孜地块东南部在晚三叠世中期处于后碰撞造山环境。  相似文献   

9.
铁坑坳铁锡多金属矿床位于粤东莲花山断裂带西部,矿区出露的花岗岩类主要有粗粒二长花岗岩和花岗闪长斑岩,花岗质岩石与碳酸盐岩的接触带中发育铁锡多金属矿化。该矿区的成岩成矿时代尚不明确,成矿与哪一种岩体具有成因上的联系也不清楚。文章选择与铁锡多金属矿体相关的花岗岩类的锆石和块状矿石中的锡石,首次开展LA-ICP-MS U-Pb定年和Nd-Hf同位素研究。结果表明:粗粒二长花岗岩和花岗闪长斑岩的锆石U-Pb年龄分别为(132±1) Ma (n=24,MSWD=0.78)和(94±1) Ma (n=25,MSWD=1.80);块状矿石中锡石U-Pb年龄为(130±3) Ma (n=36,MSWD=0.62),成矿时代与粗粒二长花岗岩形成时代基本一致,均形成于早白垩世;粗粒二长花岗岩的锆石εHft)变化于-4.9~-0.1,平均值为-2.8,地壳Hf模式年龄TDMC=1192~1497 Ma,平均值为1366 Ma,全岩εNdt)值介于-8.8~-8.7,Nd同位素二阶段模式年龄TDM2变化于1630~1642 Ma;花岗闪长斑岩的锆石εHft)变化于-5.7~-2.9,平均值为-4.4,地壳Hf模式年龄TDMC=1342~1523 Ma,平均值为1440 Ma,全岩εNd (t)值介于-5.4~-4.9,Nd同位素二阶段模式年龄TDM2变化于1291~1332 Ma。Nd-Hf同位素综合研究表明,粗粒二长花岗岩的源区物质主要来自于中元古代地壳,有少量幔源组分或新生地壳的加入,花岗闪长斑岩的源区物质中幔源组分或新生地壳的混入比例高于粗粒二长花岗岩。  相似文献   

10.
松林口岩体位于松潘—甘孜造山带中东部,为确定岩体的侵位时代和地球化学特征,通过镜下薄片观察、主微量元素分析以及锆石U-Pb测年,对松林口岩体进行了研究。结果表明,松林口岩体由二长花岗岩体和花岗闪长岩体组成,花岗闪长岩锆石206Pb/238U年龄加权平均值为(212.4±0.9) Ma (MSWD=0.66),二长花岗岩锆石206Pb/238U年龄加权平均值为(222.4±1.1) Ma (MSWD=0.39),形成于晚三叠世,由两期次岩浆作用形成;岩石的SiO2含量56.56%~61.97%;铝饱和指数A/CNK=0.93~1.05,全碱含量3.78~5.38,K2O/Na2O=1.02~1.68,里特曼指数σ=1.194~1.612,样品属于准铝质中—高钾钙碱性岩系列。岩石轻重稀土比值LREE/HREE=5.22~7.13,LaN/YbN比值为6.93~8.96,轻、重稀土分异较明显,具较强的负Eu异常。岩石Mg#值较高(50.97~61.27),w(Rb)/w(Sr)为0.12~0.25,Rb-(Y+Nb)图解显示为后碰撞环境。因此,松林口二长花岗岩—花岗闪长岩属后碰撞准铝质中—高钾钙碱性I型花岗岩类。  相似文献   

11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

12.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.  相似文献   

13.
This article advances critical geographies of youth through examining the spatiality implicit in the imagined futures of young women in rural India. Geographers and other scholars of youth have begun to pay more attention to the interplay between young people’s past, present, and imagined futures. Within this emerging body of scholarship the role of the family and peer group in influencing young people’s orientations toward the future remain underexamined. Drawing on eleven months of ethnographic fieldwork, my research focuses on a first generation of college-going young women from socioeconomically marginalized backgrounds in India’s westernmost state of Gujarat. I draw on the “possible selves” theoretical construct in order to deploy a flexible conceptual framework that links imagined post-educational trajectories with motivation to act in the present. In tracing the physical movement of these young women as they navigate and complete college, my analysis highlights the ways in which particular kinds of spaces and spatial arrangements facilitate and limit intra- and inter-generational contact, and the extent to which this affects young women’s conceptions of the future. I conclude by considering the wider implications of my research for ongoing debates surrounding youth transitions, relational geographies of age, and education in the Global South.  相似文献   

14.
15.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

16.
Models have become so fashionable that many scientists and engineers cannot imagine working without them. The predominant use of computer codes to execute model calculations has blurred the distinction between code and model. The recent controversy regarding model validation has brought into question what we mean by a ‘model’ and by ‘validation.’ It has become apparent that the usual meaning of validation may be common in engineering practice and seems useful in legal practice but it is contrary to scientific practice and brings into question our understanding of science and how it can best be applied to such problems as hazardous waste characterization, remediation, and aqueous geochemistry in general. This review summarizes arguments against using the phrase model validation and examines efforts to validate models for high-level radioactive waste management and for permitting and monitoring open-pit mines. Part of the controversy comes from a misunderstanding of ‘prediction’ and the need to distinguish logical from temporal prediction. Another problem stems from the difference in the engineering approach contrasted with the scientific approach. The reductionist influence on the way we approach environmental investigations also limits our ability to model the interconnected nature of reality. Guidelines are proposed to improve our perceptions and proper utilization of models. Use of the word ‘validation’ is strongly discouraged when discussing model reliability.  相似文献   

17.
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments).  相似文献   

18.
The shape of sedimentary particles may carry important information on their history. Current approaches to shape classification (e.g. the Zingg or the Sneed and Folk system) rely on shape indices derived from the measurement of the three principal axes of the approximating tri-axial ellipsoid. While these systems have undoubtedly proved to be useful tools, their application inevitably requires tedious and ambiguous measurements, also classification involves the introduction of arbitrarily chosen constants. Here we propose an alternative classification system based on the (integer) number of static equilibria. The latter are points of the surface where the pebble is at rest on a horizontal, frictionless support. As opposed to the Zingg system, our method relies on counting rather than measuring. We show that equilibria typically exist on two well-separated (micro and macro) scales. Equilibria can be readily counted by simple hand experiments, i.e. the new classification scheme is practically applicable. Based on statistical results from two different locations we demonstrate that pebbles are well mixed with respect to the new classes, i.e. the new classification is reliable and stable in that sense. We also show that the Zingg statistics can be extracted from the new statistics; however, substantial additional information is also available. From the practical point of view, E-classification is substantially faster than the Zingg method.  相似文献   

19.
Partition coefficients of Hf,Zr, and REE between zircon,apatite, and liquid   总被引:25,自引:2,他引:25  
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite.  相似文献   

20.
Pools,riffles, and channelization   总被引:2,自引:0,他引:2  
The addition of regularly spaced deeps (pools) and shallows (riffles) that provide a variety of flow conditions, areal sorting of stream-bed material, cover for wildlife, and a positive aesthetic experience, may be desirable in many channel projects. Such designs will reduce adverse environmental impacts of stream channel modifications. Analysis of variance for pool-to-pool spacing data suggests that there is no significant difference with respect to channel width between pools that form in natural streams and those in streams affected by a variety of human uses. Short of channelization, which changes the channel width, pools and riffles, within limits, are not particularly sensitive to environmental stress. Experiments in Gum Branch near Charlotte, North Carolina, support the hypothesis that channel form and process evolve in harmony and that manipulation of cross-channel morphology can influence the development of desired channel processes. Planned manipulation of its channel form induced Gum Branch to develop as desired. Morphologic stability consisting of incipient point bars, pools, and riffles was maintained over a period of high magnitude flood events, only to be degraded later by a wave of sediment derived from upstream construction and stream-bank failures. Thus, environmentally desirable channel morphology in urban streams cannot remain stable if changes in the sediment load or storm-water runoff exceed the limits of the stream's ability to make internal adjustments while maintaining morphologic stability.  相似文献   

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