Controls on metamorphic equilibration: the importance of intergranular solubilities mediated by fluid composition          下载免费PDF全文

W. D. Carlson  J. D. Hixon  J. M. Garber  R. J. Bodnar 《Journal of Metamorphic Geology》2015,33(2):123-146

A dramatic demonstration of the role of intergranular solubility in promoting chemical equilibration during metamorphism is found in the unusual zoning of garnet in pelitic schist exposed at Harpswell Neck, Maine, USA. Many garnet crystals have irregular, patchy distributions of Mn, Cr, Fe and Mg in their inclusion‐rich interiors, transitioning to smooth, concentric zoning in their inclusion‐poor outer rims; in contrast, zoning of Ca and Y is comparatively smooth and concentric throughout. We re‐assess the disputed origin of these zoning features by examining garnet growth in the context of the thermal and structural history of the rocks, and by evaluating the record of fluid–rock interaction revealed in outcrop‐scale veining and fluid‐inclusion assemblages. The transition in the character of garnet zoning correlates with the onset of a synkinematic, simple‐shear‐dominated phase of garnet growth and with a shift in the composition of the intergranular fluid from CO₂‐rich to H₂O‐rich. Compositional variations in garnet are therefore best explained by a two‐stage growth history in which intergranular diffusive fluxes reflect differences in the concentration of dissolved species in these two contrasting fluids. Interiors of garnet crystals grew in the presence of a CO₂‐rich fluid, in which limited solubility for Mn and Cr (and perhaps Fe and Mg) produced patchy disequilibrium overprint zoning, while appreciable solubility for Ca and Y permitted their rock‐wide equilibration. Rims grew in the presence of an H₂O‐rich fluid, in which high intergranular concentrations for all elements except Cr enabled diffusion over length scales sufficient for rock‐wide equilibration. This striking example of partial chemical equilibrium during reaction and porphyroblast growth implies that thermal effects may commonly be subsidiary in importance to solubilities in the intergranular medium as determinants of length scales for metamorphic equilibration.  相似文献   

Reaction softening by dissolution–precipitation creep in a retrograde greenschist facies ductile shear zone,New Hampshire,USA          下载免费PDF全文

R. J. McAleer  D. L. Bish  M. J. Kunk  K. R. Sicard  P. M. Valley  G. J. Walsh  B. A. Wathen  R. P. Wintsch 《Journal of Metamorphic Geology》2017,35(1):95-119

We describe strain localization by a mixed process of reaction and microstructural softening in a lower greenschist facies ductile fault zone that transposes and replaces middle to upper amphibolite facies fabrics and mineral assemblages in the host schist of the Littleton Formation near Claremont, New Hampshire. Here, Na‐poor muscovite and chlorite progressively replace first staurolite, then garnet, and finally biotite porphyroblasts as the core of the fault zone is approached. Across the transect, higher grade fabric‐forming Na‐rich muscovite is also progressively replaced by fabric‐forming Na‐poor muscovite. The mineralogy of the new phyllonitic fault‐rock produced is dominated by Na‐poor muscovite and chlorite together with late albite porphyroblasts. The replacement of the amphibolite facies porphyroblasts by muscovite and chlorite is pseudomorphic in some samples and shows that the chemical metastability of the porphyroblasts is sufficient to drive replacement. In contrast, element mapping shows that fabric‐forming Na‐rich muscovite is selectively replaced at high‐strain microstructural sites, indicating that strain energy played an important role in activating the dissolution of the compositionally metastable muscovite. The replacement of strong, high‐grade porphyroblasts by weaker Na‐poor muscovite and chlorite constitutes reaction softening. The crystallization of parallel and contiguous mica in the retrograde foliation at the expense of the earlier and locally crenulated Na‐rich muscovite‐defined foliation destroys not only the metastable high‐grade mineralogy, but also its stronger geometry. This process constitutes both reaction and microstructural softening. The deformation mechanism here was thus one of dissolution–precipitation creep, activated at considerably lower stresses than might be predicted in quartzofeldspathic rocks at the same lower greenschist facies conditions.  相似文献   

从平衡-封闭-静态转向非平衡-开放-动力学研究-热液矿床成因的若干新概念概述     

张荣华  胡书敏  张雪彤 《地质学报》2016,90(9):2437-2453

热液金属矿床成因研究过程中,观测与实验始终是密切结合的。上世纪70年代,平衡热力学的实验数据的快速积累,使人们用热力学理论计算可以预测和反演矿石和岩石的成因。但是,没有矿物-水溶液的反应速率数据,又没有与流体力学的结合,搞清楚矿石成因是困难的。七、八十年代,开始研究矿物与水溶液的反应动力学实验。科学家们开始瞄准了从平衡-封闭-静态转向非平衡-开放-动力学研究的这个大方向。1992年我们建立地球化学动力学开放研究实验室。研究高温高压矿物与水反应速率,发现固液的开放体系的自组织现象。实验发现温度影响矿物的各个元素反应速率改变,发现在跨越水临界态时矿物与水反应速率涨落、在近临界的气-液两相不混溶区一些金属进入气相、超临界流体的氧化作用及特别的溶剂性能影响矿物溶解性质。实验证实:临界态区流体与矿石成因有关。水岩相互作用的反应动力学实验温度从低温到550度,揭示矿石的金属来源、迁移、金属与蚀变分带机制。一大批大于300度的矿物与水反应动力学实验在国际界是少有报道的。九十年代,超高压的科学发展,与同步辐射光源的技术进步的结合,使固体地球科学又迈向了地球深内部。我们发展了高温高压流体性质的原位直测(测量850℃水溶液)红外谱,发现深部流体的新性质:气液两相流体的新结构,在临界温度区(300~400℃),水分子氢键网络的破坏受压力影响不大(23MPa~3GPa),同时,出现水的高电导率。研发新仪器为开放-流动-非平衡的反应动力学实验与极端条件下物质性质的直接观测结合,在科学前沿领域开辟了创新道路。  相似文献   

Reactivity of micas and cap-rock in wet supercritical CO2 with SO2 and O2 at CO2 storage conditions     

《Applied Geochemistry》2016

Seal or cap-rock integrity is a safety issue during geological carbon dioxide capture and storage (CCS). Industrial impurities such as SO₂, O₂, and NOx, may be present in CO₂ streams from coal combustion sources. SO₂ and O₂ have been shown recently to influence rock reactivity when dissolved in formation water. Buoyant water-saturated supercritical CO₂ fluid may also come into contact with the base of cap-rock after CO₂ injection. Supercritical fluid-rock reactions have the potential to result in corrosion of reactive minerals in rock, with impurity gases additionally present there is the potential for enhanced reactivity but also favourable mineral precipitation.The first observation of mineral dissolution and precipitation on phyllosilicates and CO₂ storage cap-rock (siliciclastic reservoir) core during water-saturated supercritical CO₂ reactions with industrial impurities SO₂ and O₂ at simulated reservoir conditions is presented. Phyllosilicates (biotite, phlogopite and muscovite) were reacted in contact with a water-saturated supercritical CO₂ containing SO₂, or SO₂ and O₂, and were also immersed in the gas-saturated bulk water. Secondary precipitated sulfate minerals were formed on mineral surfaces concentrated at sheet edges. SO₂ dissolution and oxidation resulted in solution pH decreasing to 0.74 through sulfuric acid formation. Phyllosilicate dissolution released elements to solution with ∼50% Fe mobilized. Geochemical modelling was in good agreement with experimental water chemistry. New minerals nontronite (smectite), hematite, jarosite and goethite were saturated in models. A cap-rock core siltstone sample from the Surat Basin, Australia, was also reacted in water-saturated supercritical CO₂ containing SO₂ or in pure supercritical CO₂. In the presence of SO₂, siderite and ankerite were corroded, and Fe-chlorite altered by the leaching of mainly Fe and Al. Corrosion of micas in the cap-rock was however not observed as the pH was buffered by carbonate dissolution. Ca-sulfate, and Fe-bearing precipitates were observed post SO₂-CO₂ reaction, mainly centered on surface cracks and an illite rich illite-smectite precipitate quantified. Water saturated impure supercritical CO₂ was observed to have reactivity to rock-forming biotite, muscovite and phlogopite mineral separates. In the cap-rock core however carbonates and chlorite were the main reacting minerals showing the importance of assessing actual whole core.  相似文献   

Decoding the Development Strategy of a Major Retailer: Wal-Mart's Expansion in the United States     

Murray D. Rice  Anthony Ostrander  Chetan Tiwari 《The Professional geographer》2016,68(4):640-649

This research aims to provide insight regarding Wal-Mart's retail development strategy in its expansion across the continental United States. The study examines store location patterns and relationships between Wal-Mart's store and distribution center locations and markets. The study shows that, although radial expansion is broadly characteristic of the dense store patterns that have been well established for Wal-Mart at the national level, expansion patterns at the regional level are consistent with a selective process based on factors other than store density. These results provide a new perspective on Wal-Mart's expansion, providing insights of value to retail practitioners and local government.  相似文献   

元素分析仪-同位素比值质谱测量碳氮同位素比值最佳反应温度和进样量的确定   总被引：2，自引：2，他引：0  

徐丽  邢蓝田  王鑫  李中平  毛俊丽 《岩矿测试》2018,37(1):15-20

沉积有机质的碳氮稳定同位素值是进行古气候、古环境及生态系统研究不可或缺的主要研究手段,目前碳氮同位素主要利用元素分析仪-同位素比值质谱(EA-IRMS)系统来测定。EA-IRMS测定过程中的反应温度及样品进样量直接影响反应物在测试中的燃烧程度,从而影响测试数据的精度。本文利用EA-IRMS技术,以标准样品为参考,在不同转化温度下测试碳氮同位素值,研究保证测试精度的最佳反应温度条件;同时,通过分析不同含氮量样品的检测限,明确了样品含氮量与最低检测限之间的关系,确定了精确测定氮同位素值的最低进样量。结果表明:反应温度对测试精度有显著影响,在碳同位素测定时,将反应温度设定为900℃或以上时测试精度均能达到±0.2‰;氮同位素测定时,反应温度须设定为950℃时测试精度才能达到±0.3‰。实验得出样品含氮量与检测限之间的线性相关性为R2=0.873,开展氮同位素测定时可根据此关系来判断和控制进样量。  相似文献   

压力对辉长岩矿物反应和部分熔融影响的实验研究     

沙茜  周永胜 《岩石学报》2018,34(3):851-865

本文在高温高压条件下,开展了辉长岩矿物反应与部分熔融实验,利用偏光显微镜与扫描电镜对实验样品微观结构观察,研究实验中的新生矿物与熔体的分布;通过电子探针分析熔体成分特征。实验结果表明,在低压(300MPa)条件下,静压和塑性变形实验样品中,单斜辉石以固体反应方式生成橄榄石,在高压(1300MPa)塑性实验中所有实验样品都没有发现新生矿物颗粒,这与相图中低压条件下斜长石与橄榄石稳定共存,而高压下斜长石-辉石稳定共存相吻合。高压塑性变形条件下,单斜辉石和黑云母首先发生部分熔融,随着温度增高,斜长石逐渐参与熔融,熔体呈薄膜状分布在矿物颗粒边界,熔体成分依赖于参与熔融的矿物成分,表明出现的熔体为非平衡熔融结果。  相似文献   

基于SBAS- InSAR技术的西藏雄巴古滑坡变形特征   总被引：2，自引：0，他引：2  

闫怡秋  郭长宝  张永双  张绪教  郑岳泽  李雪  杨志华  吴瑞安 《地质学报》2021,95(11):3556-3570

大型古滑坡及其强变形和复活灾害日益频发,已造成重大灾害事件和严重损失.古滑坡的发育、变形影响因素多、机理复杂和识别难度大,本文采用SBAS-InSAR技术,结合遥感解译,获取了金沙江西岸雄巴村古滑坡2017年10月至2020年6月间的地表变形特征.研究表明,雄巴古滑坡方量巨大,可达2.6×108～6×108 m3,根据InSAR形变监测结果,滑坡前缘发育H1和H2等2个大型强变形区,变形级别分为4级:极强变形区(-132.1 mm/a≤VLOS＜-58.5 mm/a)、强变形区(-58.5 mm/a≤VLOS＜-20.3 mm/a)、中等变形区(-20.3 mm/a≤VLOS＜l.8 mm/a)和弱变形区(1.8 mm/a≤VLOS＜55.4 mm/a);其中H1变形区,最大累计变形量达203.8 mm,H2变形区变形量达302.1 mm.受金沙江河流侵蚀,特别是上游75 km的2018年10月和11月白格2次滑坡-堵江-溃坝-泥石流/洪水灾害链对雄巴古滑坡坡脚的侵蚀,加剧了雄巴古滑坡的变形,其中H1变形区的蠕滑速率是白格滑坡灾害链发生前的14～16倍,灾害链引起H2区发生变形,雄巴古滑坡整体呈现牵引式复活状态.基于SBAS-InSAR的形变监测结果得到了野外的验证,目前H1变形区前缘出现局部垮塌,滑体中横向和竖向裂缝发育,局部呈现拉张状态.雄巴古滑坡目前呈现持续变形中,部分地段为加速变形,雄巴古滑坡发生大规模复活将导致堰塞金沙江-溃坝-泥石流灾害链,应加强雄巴古滑坡的空—天—地一体化监测预警,为该区正在规划建设的重大工程和流域性地质安全风险提供技术支撑和科学依据.  相似文献   

The Impact of Climatic and Environmental Factors on n-Alkanes Indices in Southwestern Tibetan Plateau     

LING Yuan  ZHENG Mianping  WANG Shuxian  SUN Qing  XIE Bingjing  ZHANG Chengjun 《《地质学报》英文版》2021,95(2):648-658

n-Alkanes are widely used in paleoenvironmental reconstructions.However,our understanding of changes in the distribution of n-alkanes with climatic and environmental factors remains unclear in arid/semi-arid regions.We sampled 26 surface sediments from three climatic zones across the southwestern Tibetan Plateau to evaluate the sensitivity of chain length distributions of n-alkanes to climatic and environmental parameters.Our observations demonstrate that average chain length (ACL), proportion of aquatic macrophyte (Paq),carbon preference index (CPI) and ratio of the contents of nC27 and nC31 (nC27/nC31) are all sensitive to hydroclimatic conditions.In contrast to commonly-adopted assumptions,the correlations between these indices and hydrological parameters are not always good,which indicates that the interpretation of n-alkane indices is special on the southwestern Tibetan Plateau.These might be related to the vegetation characteristics and seasonality of biological activity,and need to be considered in paleoclimatic reconstruction.The impact of seasonal precipitation on n-alkanes indices was also evaluated.  相似文献   

绿色交通目标下集装箱“公转铁”的CO2减排潜力评估     

陶学宗  吴琴  尹传忠 《气候变化研究进展》2019,15(6):660-669

为提高集装箱“公转铁”减排潜力评估结果的准确性,在分析“公转铁”减排原理的基础上,综合考虑空箱调运和重箱运输“门到门”运输链的干线运输、端点装卸、电力设备作业、集卡短驳、公铁中转等排放,引入反映活动类型、设备结构、能源生命周期排放的参数,对作业活动-方式结构-能耗强度-排放因子（ASIF）方法进行改进,建立“公转铁”减排潜力评估框架。以义乌—宁波港域出口集装箱运输为例,通过实地调研和公开文献获取数据,进行实证研究。结果表明,如果忽略必要因素将会导致每TEU运输需求“公转铁”的CO₂减排率被高估0.50~36.73个百分点;最佳“公转铁”情景可减排3.42万t CO₂,相应减排率为13.58%。研究结果可为政府相关部门客观评估“公转铁”的减排潜力、制定有效的“公转铁”政策措施提供理论支持。  相似文献