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Investigation of Hydrous Pyrolysis on Type-II Kerogen-bearing Source Rocks from Iran and its Application in Geochemical and Kinetic Analyses of Hydrocarbon Products 
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下载免费PDF全文 Hydrous pyrolysis (HP) practiced on type-II kerogen-bearing oil shale samples from the Sargelu Formation in the Ghali-Kuh Area, western Iran, using a specially designed apparatus was performed at different temperatures (250–350°C), with hydrocarbon generation evaluated at each temperature. For comparison, the samples subjected to Rock-Eval pyrolysis before proceeding to HP resulted in Tmax = 418°C, HI = 102, and TOC = 4.33%, indicating immaturity and hence remarkable hydrocarbon (especially oil) generation potential, making them appropriate for HP. Moreover, the samples were deposited in a low-energy reductive marine environment, with maximum oil and gas generation (739 mg and 348 mg out of 50 g of rock sample, respectively) observed at 330°C and 350°C, respectively. The oil generated at 330°C was subjected to gas chromatography (GC) and isotopic analyses to assess hydrocarbon quality and composition. The hydrocarbon generation data was devised to estimate kinetic indices of the Arrhenius equation and to investigate the gas–oil ratio (GOR) and overall conversion yield. Based on the producible hydrocarbon quantity and quality, the findings contribute to the economic assessment of oil shales across the study area. The developed kinetic model indicates the history of hydrocarbon generation and organic matter (OM) maturity. 相似文献
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Application of Statistical Methods to Biomarkers for Geochemical Evaluation and Genetic Type Determination of Gas Condensates in the Persian Gulf and Coastal Fars, Southern Iran 下载免费PDF全文
下载免费PDF全文 In a comprehensive geochemical study, the genetic relationships among 14 samples of gas condensates from the Persian Gulf were investigated for the purpose of evaluating the respective source rocks in terms of both age and sedimentary paleoenvironment. Chemometric analysis was used for categorization and determination of a certitude range to determine the genetic type of the condensate families in the studied basin. The samples were collected from Late Permian – Triassic reservoirs (Dalan and Kangan formations) located in 6 gasfields (gas condensate) hosting some of Iran’s most important gas/gas condensate reserves. Obtained by gas chromatography-mass spectrometry (GC-MS), a total of 16 biomarker parameters (10 maturity-related parameters and 6 sedimentary environment-related parameters) were used to evaluate the samples in terms of thermal maturity (and hence their positions in the maturity chart), the sedimentary environment of the source rock and the lithology. Application of Hierarchical Clustering Analysis (HCA) and Principal Component Analysis (PCA) to the collected data led to the categorization of the samples into three main genetic groups, I–III. Groups I and III were found to be located in the east and the west of the Persian Gulf, respectively, while Group II was developed between the two other groups. 相似文献
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