Mineralogical characterization of a unique material having heavy oxygen isotope anomaly in matrix of the primitive carbonaceous chondrite Acfer 094     

Yusuke Seto  Naoya Sakamoto  Takashi Kaito  Hisayoshi Yurimoto 《Geochimica et cosmochimica acta》2008,72(11):2723-2734

We report the mineral compositions and micro-texture of the isotopically anomalous (δ^17,18O_SMOW ∼ +180‰) Fe-S-Ni-O material recently discovered in matrix of the primitive carbonaceous chondrite Acfer 094 [Sakamoto N., Seto Y., Itoh S., Kuramoto K., Fujino K., Nagashima K., Krot A. N. and Yurimoto H. (2007) Oxygen isotope evidence for remnants of the early solar system primordial water. Science317, 231-233]. Synchrotron radiation X-ray diffraction and transmission electron microscopy studies indicate that this material consists of the symplectitically intergrown magnetite (Fe₃O₄) and pentlandite (Fe_5.7Ni_3.3S₈) with magnetite/pentlandite volume ratio of ∼2.3. Magnetite forms column-shaped grains (10-30 nm in diameter and 100-200 nm in length); pentlandite occurs as worm-shaped grains or aggregates of grains 100-300 nm in size between magnetite crystals. Although both the X-ray diffraction and electron energy loss spectra support identification of iron oxide as magnetite, the electron diffraction patterns show that magnetite has a weak 3-fold superstructure, possibly due to ordering of vacancies. We infer that the isotopically anomalous symplectite formed by sulfurization and oxidization of metal grains either in the solar nebula or on an icy planetesimal. The intersite cation distribution of pentlandite suggests that timescale of oxidation was no longer than 1000 years.  相似文献   

Cycladophora davisiana (Radiolaria) in the Okhotsk Sea: A key for reconstructing glacial ocean conditions     

Yusuke Okazaki  Osamu Seki  Takeshi Nakatsuka  Tatsuhiko Sakamoto  Minoru Ikehara  Kozo Takahashi 《Journal of Oceanography》2006,62(5):639-648

Cycladophora davisiana, a radiolarian species dwelling at mesopelagic depths, is known as a representative glacial fauna due to its unique distribution during glacial periods. In the present ocean, abundant production of C. davisiana is only observed in the Okhotsk Sea, indicating an adaptation of C. davisiana for seasonal sea-ice covered conditions. We found pronounced abundant production of C. davisiana during the early to middle Holocene in the Okhotsk Sea, suggesting more favorable conditions for C. davisiana than the present Okhotsk Sea. In order to clarify the reason, oceanographic conditions during the Holocene were reconstructed based on biomarkers, lithogenic grains including ice-rafted debris (IRD), biogenic opal, and total organic carbon (TOC) in two sediment cores from the Okhotsk Sea. These indicators suggest that the pronounced C. davisiana production may be attributed to: 1) a supply to mesopelagic depths under intensified stratification of fine organic particles derived from coccolithophorids, bacteria, and detrital materials; and 2) cold, well-ventilated intermediate water formation.  相似文献   

类石材料--灰泥的冻融过程     

Takashi Ono 《冰川冻土》2004,26(Z1):64-69

Serious failure on the slope of rock ground can be caused by a cyclic action of freezing and thawing in the cold regions. The frost susceptibility and the effect of freezing and thawing onthe rock material, however, have not been well investigated. In order to find out the freezing effect on the rock materials, mortar specimens are frozen as a pseudo-rock material under the constant rate of freezing by means of controlling the temperature of both ends of specimen. The freezing process is given one-dimensionally to the cylindrical samples in the laboratory to simulate the in-situ freezing phenomena in the natural ground. Formation of ice lens, frost heave and water intake during freezing process are observed on the mortar specimen under constant freezing rate, which probably causes cracks or large deformation in the real rock ground. The values of the velocity of elastic wave propagation are compared before and after freezing process to estimate the degree of weathering due to freezing and thawing.  相似文献   

Theoretical and experimental evidence for the post-cotunnite phase transition in zirconia at high pressure     

Daisuke Nishio-Hamane  Haruhiko Dekura  Yusuke Seto  Takehiko Yagi 《Physics and Chemistry of Minerals》2015,42(5):385-392

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A diatom‐inferred record of lake variability during the last 900 years in Lützow–Holm Bay,East Antarctica          下载免费PDF全文

Rachel C. Rudd  Jonathan J. Tyler  John Tibby  Yusuke Yokoyama  Ines Tavernier  Elie Verleyen  Manabu Fukui  Yoshinori Takano 《第四纪科学杂志》2016,31(2):114-125

Decadal–centennial‐scale climate variability in coastal Antarctica remains poorly understood due to the limited number of highly resolved, well‐dated records. We present a 900‐year, decadal‐scale reconstruction based on sedimentary diatoms from Lake Abi in Lützow–Holm Bay, East Antarctica. Hydrological change is inferred from diatom ecological preferences in conjunction with an existing regional training set and implies that lake water specific conductivity, depth and nitrogen availability are the key drivers of diatom assemblage change. Lake Abi underwent a series of subtle environmental changes related to these environmental variables, possibly driven by changes in catchment snow melt and the duration of seasonal ice cover. Ordination is used to trace the major patterns of change in the diatom community, with notable shifts identified between 470 and 400 and at ～350 cal a BP (where present = CE 1950). The frequency of environmental variability at Lake Abi is broadly consistent with a record of the Interdecadal Pacific Oscillation during the last millennium, but contrasts with the apparent climate stability elsewhere in eastern Antarctica. Further research is required to constrain the limnological and ecological responses of lakes in coastal Antarctica to obtain more rigorous palaeoclimate reconstructions from these sites of immense potential.  相似文献   

The multiple chronological techniques applied to the Lake Suigetsu SG06 sediment core,central Japan     

Richard A. Staff  Takeshi Nakagawa  Gordon Schlolaut  Michael H. Marshall  Achim Brauer  Henry F. Lamb  Christopher Bronk Ramsey  Charlotte L. Bryant  Fiona Brock  Hiroyuki Kitagawa  Johannes van der Plicht  Rebecca L. Payne  Victoria C. Smith  Darren F. Mark  Alison Macleod  Simon P. E. Blockley  Jean‐Luc Schwenninger  Pavel E. Tarasov  Tsuyoshi Haraguchi  Katsuya Gotanda  Hitoshi Yonenobu  Yusuke Yokoyama  Suigetsu Project Members 《Boreas: An International Journal of Quaternary Research》2013,42(2):259-266

The varved sediment of Lake Suigetsu (central Japan) provides a valuable opportunity to obtain high‐resolution, multi‐proxy palaeoenvironmental data across the last glacial/interglacial cycle. In order to maximize the potential of this archive, a well‐constrained chronology is required. This paper outlines the multiple geochronological techniques being applied – namely varve counting, radiocarbon dating, tephrochronology (including argon–argon dating) and optically stimulated luminescence (OSL) – and the approaches by which these techniques are being integrated to form a single, coherent, robust chronology. Importantly, we also describe here the linkage of the floating Lake Suigetsu (SG06) varve chronology and the absolute (IntCal09 tree‐ring) time scale, as derived using radiocarbon data from the uppermost (non‐varved) portion of the core. This tie‐point, defined as a distinct (flood) marker horizon in SG06 (event layer B‐07–08 at 1397.4 cm composite depth), is thus derived to be 11 255 to 11 222 IntCal09 cal. years BP (68.2% probability range).  相似文献   

Corrigendum to “Global ice volumes at the Last Glacial Maximum and early Lateglacial” [Earth Planet. Sci. Lett. 181 (2000) 513–527]     

Kurt Lambeck  Yusuke Yokoyama  Paul Johnston  Anthony Purcell 《Earth and Planetary Science Letters》2001,190(3-4):275

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Alkaline leaching characteristics of biogenic opal in Eocene sediments from the central Arctic Ocean: a case study in the ACEX cores     

Shinya Iwasaki  Kozo Takahashi  Yusuke Ogawa  Seiichiro Uehara  Christoph Vogt 《Journal of Oceanography》2014,70(3):241-249

Accurate knowledge of the extent of biogenic opal preservation in marine sediment cores is important for paleoceanographic reconstructions. The alkaline leaching method is widely employed for %biogenic opal analysis due to its ease and speed. In this study, a revised method for measuring %biogenic opal in sediment from arctic coring expedition samples was suggested. The studied middle Eocene sediments from the central Arctic Ocean presented a problem in insufficiently leaching biogenic opal with a Na₂CO₃ solution. Based on XRD analysis, it was suggested that such an alkaline resistance results from slight diagenesis of biogenic opal. In order to solve this problem, an alkaline leaching method utilizing a 2 M NaOH solution was suggested for the accurate measurement of %biogenic opal in the Eocene sediments from the central Arctic. Furthermore, dissolution rates from lithogenic matter by NaOH solution were measured in order to correct the %biogenic opal values.  相似文献   

Micro-X-ray fluorescence-based comparison of skeletal structure and P, Mg, Sr, O and Fe in a fossil of the cold-water coral Desmophyllum sp., NW Pacific     

Toshihiro Yoshimura  Atsushi Suzuki  Yusuke Tamenori  Hodaka Kawahata 《Geo-Marine Letters》2014,34(1):1-9

Micro-scale distributions of trace and minor elements in, for example, coral skeletons are crucial as geochemical tracers of past environmental conditions, because they have the inherent advantage of accounting for confounding diagenetic and physiological effects. To extract reproducible paleoceanographic records from coral skeletons, a selective measurement of specific ultrastructures at high spatial resolution is required. Compared to warm-water reef-building corals, such data are limited in cold-water corals and, to the best of the authors’ knowledge, the latter have to date not been examined by means of micro-X-ray fluorescence. This technique was used for micrometer-scale imaging of P, Mg, Sr, O, and Fe intensities (counts per unit time) in a fossil specimen (as yet unknown age) of the cold-water coral Desmophyllum sp. from surface sediments of the NW Pacific. Cross plots confirmed that the micro-XRF signals were associated with corresponding trends in elemental concentration (ppm). Two major structural components of the septum—centers of calcification (COCs) and the surrounding fibrous aragonite portion—differed in composition. The COCs were characterized by higher intensities of P and Mg (650 and 220 counts per 5 s, respectively), and lower intensities of Sr (2,800) and O (580; corresponding values for the fibrous aragonite are 370, 180, 3,300 and 620 counts per 5 s, respectively). Oxygen intensity values were mostly homogeneous, but slightly lower in COCs and substantially higher in a well-defined patch in the fibrous aragonite. The mostly homogeneous P signals in the fibrous aragonite confirm the utility of this structural component and of coral septa in general for tracer studies of oceanic P. Nevertheless, spot occurrences of elevated P (>950 counts per 5 s) spanning tens of micrometers in specific parts of the fibrous region of the septum would cause overestimates of oceanic P, and should evidently not be overlooked in future research. The distribution of Fe showed no correlation with P, indicating no significant contamination in the form of P-bearing diagenetic ferromanganese precipitates. Such hotspots plausibly reflect the presence of other mineral phases, such as crystalline hydroxylapatite inclusions or contamination with organic material. The P signal intensity was positively correlated with Mg (r=0.553, p<0.001), and negatively with Sr (r=–0.489, p<0.001) and O (r=–0.311, p<0.001). There was no discernible evidence of control by water temperature in the Sr distribution pattern. These findings establish micro-X-ray fluorescence as a highly suitable pre-screening tool in cold-water coral sclerochronology, which can serve to refine sampling strategies without sample damage, and complement other micrometer-scale spatial distribution analyses of elements (notably, Ca) based on well-known approaches involving micro-milling, electron microprobes, secondary ion mass spectrometry, and laser ablation.  相似文献   

Holocene migration of oceanic front systems over the Conrad Rise in the Indian Sector of the Southern Ocean     

Kota Katsuki  Minoru Ikehara  Yusuke Yokoyama  Masako Yamane  Boo‐Keun Khim 《第四纪科学杂志》2012,27(2):203-210

There has been limited previous research about Holocene climate variability in the Indian Sector of the Southern Ocean. Here we examine centennial‐scale changes in diatom assemblages and stable isotopic ratios since 10 000 cal a BP in a high‐accumulation‐rate sediment core from the Conrad Rise. Although abundances of dominant diatom taxa (Fragilariopsis kerguelensis and Thalassiothrix antarctica) are comparatively constant, relative abundances of secondary taxa fluctuate. Before c. 9900 cal a BP, winter sea‐ice and cold water covered the Conrad Rise. Following deglaciation the sea‐ice retreated from the Conrad Rise, lagging that of the Atlantic and eastern Indian Sectors by about 1500 a. The Polar Front moved southward during the early Holocene optimum and north Antarctic Zone waters covered the Conrad Rise for about 650 a. After 9300 cal a BP, solar insolation strongly influenced sea surface temperature and primary productivity in the Southern Ocean. In the high‐latitude Indian Sector, productivity increased 1500 a after the onset of late Holocene neoglaciation. Periodic δ¹⁸O and cold‐water diatom taxa spikes (at intervals of 200 and 300–500 a, respectively) occurred after 9300 cal a BP, probably associated with solar activity. Fluctuations in short‐term sea surface temperature and cold‐water taxa are synchronous with changes in δD observed in an east Antarctic ice core. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献