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1.
以吩嗪硫酸甲酯-NADH为超氧阴离子自由基(O_2~(·-))产生、检测体系和EDTANa_2-Fe(Ⅱ)-H_2O_2为羟自由基(~·OH)产生、检测体系,对壳聚糖硫酸酯铜、锌配合物和不同分子质量壳聚糖进行了抗O_2~(·-)和~·OH自由基的活性研究.结果表明,壳聚糖硫酸酯金属配合物对于O_2~(·-)自由基的清除能力明显高于壳聚糖,在质量浓度为0.025 g/L时,壳聚糖硫酸酯铜配合物对O_2~(·-)自由基的清除能力达到94.18%,壳聚糖硫酸酯锌配合物达到93.19%;壳聚糖硫酸酯铜、锌配合物对~·OH自由基的清除能力(67.39%、60.46%)低于相同分子质量的壳聚糖(88.06%),而高于高分子质量壳聚糖761 ku(18.71%);壳聚糖分子质量大小对O_2~(·-)和~·OH自由基的清除能力有较大影响,质量浓度为1.6 g/L壳聚糖分子质量为20 ku时,对O_2~(·-)清除率达54.69%,而分子质量在761 ku时,对O_2~(·-)清除率仅为35.50%;各样品对O_2~(·-)和~·OH自由基的清除能力均随着质量浓度的增加而上升,壳聚糖硫酸酯铜、锌配合物在相当低的浓度下(0.025 g/L)就可以达到明显清除O_2~(·-)自由基的效果(≥90%). 相似文献
2.
取代异噻唑啉酮类化合物抗菌活性的定量构效关系研究 总被引：1，自引：0，他引：1
用密度泛函理论(DFT)和逐步回归分析方法对具有抗菌活性的18种新合成的取代异噻唑啉酮类化合物进行了定量构效关系(QSAR)研究。在B3LYP/6-31G(d,p)水平上,对异噻唑啉酮类化合物进行了构型全优化,并提取部分量子化学参数,通过逐步多元回归分析,筛选了影响抗菌活性的主要因素,建立了定量构效关系方程。结果表明,C(5)的亲核电子密度fCN(5)与S(1)-N(2)的键级BS(1)-N(2),是影响异噻唑啉酮类化合物抗大肠杆菌活性的主要因素,所得QSAR模型对该类化合物抗菌活性有较好的预测效果。 相似文献
3.
Checklist of parasites of New Zealand fishes and of their hosts 总被引：1，自引：1，他引：0
Three hundred and fifty‐six species of parasites (70 Protozoa, 1 Aspidogastra, 82 Digenea, 37 Monogenea, 2 Cestodaria, 36 Cestoda, 59 Nematoda, 4 Acantho‐cephala, 6 Hirudinea, 53 Copepoda, 1 Branchiura, 2 Isopoda) are listed from 140 species of fish from New Zealand and the Subantarctic Islands. The hosts are divided into Agnatha (1 species), Elasmobranchii (21 species), Holocephali (1 species) and Teleostei (117 species) and listed within these groups in alphabetical order of genus and then species; parasites are listed with the species on which they occur and the site of parasitism is specified if known. Indexes are provided to the parasites and to the families of the host genera. 相似文献
4.
实验设置了一直投喂、周期性饥饿1,2,3,4d和一直饥饿6个处理组,采用轮虫单个体培养,检验周期性饥饿对褶皱臂尾轮虫(Brachionus plicatilis)实验种群特征参数的影响.结果表明:一直投喂组的生殖价最高,对轮虫种群的潜在增长最有利,随饥饿强度的增大,生殖价减小.不同处理下,轮虫个体寿命与其生殖期之间存在显著的正相关(r=0.747).轮虫在受到饥饿后,寿命略有增长,但不同处理对轮虫的平均寿命(10.8~13.1d)和生殖期(6.3~8.3d)均未达到显著差异(P>0.05).饥饿强度增大时,轮虫个体的总产幼数、总产卵量显著下降(P<0.05),产第1幼、最后1幼、第1卵、最后1卵时间显著延长(P<0.05);同时,种群参数的世代时间(T)随饥饿强度增加而增大,内禀增长率(rm)、周限增长率(λ)和净生殖率(R0)却明显下降. 相似文献
5.
中国沿海三疣梭子蟹的遗传结构和亲缘关系分析 总被引：3，自引：0，他引：3
应用CLUSTAL X 1.81对位排序软件和Molecular Evolutionary Genetics Analysis (MEGA) Version 3.1系统发育相关分析软件包,分析了渤海、黄海和东海不同群体的三疣梭子蟹mtDNA D-loop片段序列,(不包括引物)D-loop序列(不包括引物)长约1 241 bp,该片段AT、GC平均含量分别为75.8%和24.2%,AT含量均明显高于GC含量,种群间的遗传距离平均为0.025.依据D-loop序列,应用邻接法(NJ)、最小进化法(ME)及最大简约法(MP),构建中国沿海三疣梭子蟹亲缘关系的系统发生树,MP、NJ和ME树中所显示的三疣梭子蟹亲缘关系基本一致.NJ和ME树中来自东海的XM1与DT5聚为姊妹群;来自渤海的PL1与来自东海的YT1聚为姊妹群;来自东海的DT3与来自黄海的DD1聚为姊妹群,再与来自渤海的PJ1相聚形成一个单系;来自东海的ZS1与来自黄海的QD1聚为姊妹群;来自东海的DT4与来自黄海的YC1相聚,再与来自东海的YT2,YT3相聚.在MP树中,来自黄海的YC1与来自东海的DT4相聚为姊妹群,再与YT2相聚;来自渤海的PL1与来自东海的YT1聚为姊妹群;来自东海的XM1与DT5聚为姊妹群;来自东海的DT3与来自黄海的DD1聚为姊妹群,再与来自渤海的PJ1相聚;来自东海的ZS1与来自黄海的QD1聚为姊妹群;这些群最后再与来自东海的YT3相聚.结果显示中国沿海各海区三疣梭子蟹种群间存在明显的基因交流,亲缘关系的远近并不以海区划分和地理位置的远近为依据.洄游和长期以来跨海区的捕捞作业可能是三疣梭子蟹种群间基因交流的根本原因;蓬勃发展的三疣梭子蟹人工养殖和放流也会导致亲蟹和苗种跨海区交流,对三疣梭子蟹种质资源的保护将产生巨大影响. 相似文献
6.
Kongtae Ra Joung-Keun Kim Sang Hee Hong Un Hyuk Yim Won Joon Shim Seung-Yong Lee Young-Ok Kim Jaesoo Lim Eun-Soo Kim Kyung-Tae Kim 《Ocean Science Journal》2014,49(3):279-289
Heavy metal concentrations in the surface sediments of specially managed Ulsan Bay were investigated to determine metal distribution, pollution status and its ecological risk using pollution indices (enrichment factor and geo-accumulation index), potential ecological risk index and sediment quality guidelines (SQGs). The order of mean concentration (mg/kg) of metals was Zn (361.9) > Cu (95.6) > Pb (90.7) > Cr (64.7) > Ni (32.2) > Co (16.6) > As (15.8) > Cd (0.40) > Hg (0.16) in sediments of Ulsan Bay. Spatial distribution of metals in sediments showed a significantly higher concentration near industrial complexes, indicating that metal pollution is caused by anthropogenic sources. The results of enrichment factor (EF) and geo-accumulation index (Igeo) showed that sediments were significantly accumulated with Cu, Zn, As, Cd, Pb and Hg, indicating moderate to very severe enrichment (pollution) by these metals. Based on the potential ecological risk index, Hg and Cd posed a very high and a considerable potential ecological risk. Cu and As posed a moderate potential ecological risk, while, other metals (Cr, Co, Ni, Zn and Pb) rarely posed any potential ecological risk to the coastal environments. The sediments in Ulsan Bay showed a very high level of ecological risk, dominated by Hg and Cd. Metal concentrations in sediments were 80% for Cu, 96.7% for Zn, 50% for As, 70% for Pb and 50% for Hg above the threshold effects level (TEL), respectively. 相似文献
7.
R.W.P.M Laane 《Marine Chemistry》1982,11(4):395-401
During two surveys (June, 1980 and March, 1981) the influence of the pH on the fluorescence (mFl) was studied in the Ems-Dollart estuary. In the natural pH range (7–9) the fluorescence (mFl) increased by 16.4%. To express the fluorescence (mFl) at a fixed pH, a formula was derived (see eq. 1). From the results it is concluded that an increase in fluorescence (mFl) does not necessarily include an increase in the concentration of fluorescent matter. For areas where pH changes are possible, it is premature to infer from the increase in fluorescence that the fluorescent matter is produced in situ. 相似文献
8.
本文采用美国伍兹霍尔研究所研发的海洋-大气-波浪-泥沙输运耦合模式COAWST(Coupled Dcean-Atmosphere-Wave-Sediment Transport)对南海及邻近海域进行了9 km分辨率的数值模拟研究。结果表明,南海贯穿流的季节变化再现了冬强夏弱的特征,在南海内部冬季呈现气旋环流结构,夏季呈现反气旋环流结构,尤其在冬季其流轴结构更为清晰和稳定,海水从吕宋海峡进入南海,从民都洛海峡、卡里马塔海峡、台湾海峡和巴拉巴克海峡流出,吕宋海峡断面流量与其他4个海峡流量合计在数量级上相当,保持南海海水总量不变。吕宋海峡、卡里马塔海峡、民都洛海峡的流量呈现明显相关性,吕宋海峡流量增大时,民都洛海峡和卡里马塔海峡的流量也相应增大,相关系数分别达到0.78和0.9。通过更适于分析中短期变化的简化绕岛环流理论,定量计算2019年吕宋海峡、黑潮和棉兰老流流量与北赤道流分叉点位置的关系,发现夏季北赤道流分叉点NECBL(North Equatorial Current Bifurcation Latitude)偏南,在13.6°N附近;冬季NECBL偏北,在15.6°N左右,同期黑潮流量减少,棉兰老流流量增加,作为南海贯穿流入流的吕宋海峡流量可达13.4 Sv。吕宋海峡输运补偿了北赤道流到达菲律宾海岸后的北向分支的流量,与棉兰老流的流量呈正相关,相关系数达到0.5361。 相似文献
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10.
Three methods for identification cyclones in extratropical latitudes of the Northern Hemisphere (NH) (20°–80° L) are compared
based on reanalysis data (1948–2007) for the fields of the sea level pressure (SLP). Different characteristics of extratropical
cyclones, namely, their number, intensity, size, and lifetime, are analyzed. The effect of orographic effects for the identification
of cyclones and their trajectories is evaluated. The characteristics of extratropical cyclones are compared based on different
reanalysis data (National Center for Environmental Prediction (NCEP)/National Center for Atmospheric Research (NCAR), ERA-40,
and ERA-INTERIM) with different spatial resolutions. 相似文献
11.
壬基酚对栉孔扇贝组织抗氧化酶活性的影响 总被引：3，自引：1，他引：3
研究不同浓度的壬基酚(0.05,0.10,0.20,0.40,0.80,1.60mg/L)对扇贝组织超氧化物歧化酶(SOD)和过氧化氢酶(CAT)活性的影响。试验进行6h,24h和48h后,分别测定扇贝鳃和消化盲囊组织中2种酶的活性。结果显示:①鳃组织中,0.05,0.10和0.20mg/L处理组中的SOD和CAT活性在试验6h后被轻度激活,24h和48h后出现抑制;0.40,0.80和1.60mg/L处理组的酶活性在整个试验过程中均被抑制。②消化盲囊中,0.05和0.10mg/L处理组中的SOD和CAT活性在试验6h后被轻度激活,24h和48h后被抑制;0.40,0.80和1.60mg/L处理组在整个试验过程中均被抑制。③扇贝消化盲囊组织中的SOD和CAT活性均高于鳃组织,对壬基酚的敏感性也高于后者。④扇贝消化盲囊和鳃组织中的SOD和CAT活性对壬基酚的反应变化趋势相似,二者结合,可以作为壬基酚污染的生物标志物。 相似文献
12.
应用灰色系统理论对海面溢油物理化学性质(蒸发率、溶解率、表面张力、黏度和密度)在风化过程中的变化进行研究,建立了溢油物理化学性质在风化过程中的预测模式GM(1,1)和GM(0,m).结果表明,在风化过程中,溢油物理化学性质的GM(1,1)和GM(0,m)模式预测精度令人满意,皆符合统计学检验的要求;在风化过程中,溢油物理化学性质所具有的灰色相关性可用GM(0,m)模式的灰色辨识参数来表征;在风化过程中,溢油的蒸发率和溶解率可分别用表面张力、黏度和密度作为预报因子。 相似文献
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14.
利用1973-2016年日本西海水产研究所提供的日本鲐(Scomber Japanicus)对马群系的资源量与渔获量数据,结合产卵场1(SG1, 26°~31°N,122°~127°E)、产卵场2(SG2, 30°~35°N,128°~131°E)、索饵场(FG, 35°~38°N,127°~138°E)的海表面温度、太平洋年代际振荡指数(PDO)和Nino3.4区海表温距平值(SSTA),建立基于灰色系统的日本鲐对马群系资源丰度预测模型。灰色关联和相关系数分析结果显示:选择产卵场2的4月、9月海表面温度和索饵场4月海表面温度作为日本鲐资源丰度关键影响因子。建立的模型有:分别包含产卵场2的4月、9月和索饵场4月的海表面温度3个因子的GM(1,2),GM(1,3),GM(1,4)的7种模型。这7种模型的相对残差Q检验值分别为:0.131 0,0.140 2,0.145 9,0.149 3,0.176 7,0.140 3和0.173 5。结果表明,基于产卵场2的4月海表面温度所建立的GM(1,2)模型是对日本鲐对马群系资源丰度最优预测模型。 相似文献
15.
不同品系条斑紫菜光合效率比较研究 总被引：4，自引：0，他引：4
用叶绿素荧光仪测试了7个品系紫菜叶状体在不同光照和温度条件下的光合效率,分析了受强光抑制后光合效率恢复的情况,并测试了这些品系的光合色素含量。结果显示,随着光照强度从20μmol.m-2.s-1提高到1 200μmol.m-2.s-1,总的趋势是光合效率逐渐降低,但下降幅度在不同品系间又有差异:相比20μmol.m-2.s-1光照下条件下光合效率,Yjs在1 200μmol.m-2.s-1时的光合效率下降了27%,Yw下降了33%,Gm下降了53%,Yqd下降了50%。在120μmol.m-2.s-1光照条件,5~20℃实验范围内,15~20℃条件下光合效率最高,除Yh2和Wjs,其它品系叶状体均在15℃达到顶峰,Yh2和Wjs则在20℃达到顶峰。在受到高光抑制(200μmol.m-2.s-1)后,处于光照60μmol.m-2.s-1,温度12℃条件下紫菜光合效率可在30~60 min内恢复。未发现光合色素含量与光合效率的相关性。文章还对紫菜光合效率与生态条件的关系进行了分析和讨论。 相似文献
16.
本文利用2011年8月至2014年3月Aquarius卫星盐度产品结合Argo等实测盐度资料,探讨了孟加拉湾海表盐度的季节及年际变化特征。结果显示,Aquarius与Argo盐度呈显著线性正相关,总体较Argo盐度值低,偏差为-0.13,其中在孟加拉湾北部海域负偏差值比南部海域更大,分别为-0.28和-0.10。Aquarius卫星与Argo浮标在表层盐度观测深度上的差别是造成此系统偏差的主因。Aquarius盐度资料清晰显示了孟加拉湾海表盐度具有明显的季节变化特征,包括阿拉伯海高盐水的入侵引起湾南部海域盐度的变化以及湾北部淡水羽分布范围的季节性迁移等主要特征。此外,分析还揭示了2011(2012)年春季整个湾内出现异常高盐(低盐)现象。研究表明,2010(2011)年湾北部夏季降雨减少(增加)导致该海域海水盐度偏高(偏低),并通过表层环流向南输运引起次年春季湾内表层盐度出现异常高盐(低盐)现象,春季风应力旋度正(负)距平通过影响盐度垂直混合过程对同期表层盐度异常高盐(低盐)变化也有影响。 相似文献
17.
北部湾东北部表层沉积物主微量元素空间分布特征 总被引：1，自引：0，他引：1
A multi-index analysis including grain size, major and trace elements is performed on the surface sediments from the northeastern Beibu Gulf to trace the sources of the sediments and to understand the controlling factors for elements distribution. The mean grain size exhibits a wide variation ranging from 0.09Φ to 8.05Φ with an average value of 5.33Φ. The average contents of major elements descend in an order of c(SiO_2)c(Al_2O_3)c(Fe_2O_3)c(CaO)c(MgO)c(K_2O)c(Na_2O)c(TiO_2)c(P_2O_5)c(MnO), while those of trace elements exhibit a descending order of c(Sr)c(Rb)c(V)c(Zn)c(Cr)c(Pb)c(Ni)c(Cu)c(As). On the basis of elementary distribution characteristics and statistical analyses, the study area is divided into the four zones: Zone I is located in the northeastern coastal area of the gulf, which receives large amount of fluvial materials from local rivers in Guangxi and Guangdong, China, and the Qiongzhou Strait; Zone Ⅱ is located in the center of the study area, where surface sediments exhibits a multiple source; Zone Ⅲ is located in the Qiongzhou Strait, where surface sediments are dominated by materials from the Zhujiang River and Hainan; Zone IV is located in the southwest of the study area, where surface sediments are mainly originated from the Red River and Hainan. The statistical analyses of sediment geochemical characteristics reveal that the grain size, which is mainly influenced by hydrodynamics and mineral composition of terrigenous materials, is the leading factor controlling the elementary distribution.Meanwhile, impacts from anthropogenic activities and marine biogenic process will also be taken into consideration. 相似文献
18.
Nicholas DODD 《中国海洋工程》1999,(2)
-A nonlinear model of mean free surface of waves or wave set-up is presented.The model isbased on that of Roelvink(1993),but the numerical techniques used in the solution are based on theWeighted-Average Flux(WAF)method(Watson et al,1992),with Time-Operator-Splitting(TOS)usedfor the treatment of the source terms.This method allows a small number of computational points to beused,and is particularly efficient in modeling wave set-up.The short wave(or primary wave)energy equa-tion is solved by use of a more traditional Lax-Wendroff technique.A nonlinear wave theory(James,1974)is introduced.The model described in this paper is found to be satisfactory in most respects whencompared with the measurements conducted by Stive(1983)except in modeling the mean free surface veryclose to the mean shoreline. 相似文献
19.
以凡纳滨对虾(Litopnnaus vannamei)幼虾为实验动物,在其基础饲料中分别添加芽孢杆菌(Bacillus sp.)胞外蛋白粗提物(1.0%,胞外蛋白组)、胞内多糖粗提物(1.0%,胞内多糖组),以基础饲料为对照组饲料,进行为期28d的养殖实验,探讨芽孢杆菌胞外蛋白和胞内多糖粗提物对幼虾生长、能量代谢及抗病能力的影响。研究表明,芽孢杆菌2种粗提物对凡纳滨对虾的生长和成活率影响不显著(P>0.05)。饲喂2种粗提物影响了凡纳滨对虾肝胰腺和肌肉中能量代谢相关酶活力。胞外蛋白组肝胰腺中磷酸果糖激酶(PFK)、乳酸脱氢酶(LDH)活力在养殖实验前期显著高于对照组(P<0.05),而肌肉中PFK、LDH活力显著低于对照组(P<0.05);胞内多糖组肝胰腺中己糖激酶(HK)活力及肌肉中PFK、LDH活力显著低于对照组(P<0.05)。饲喂2种粗提物均显著提高了凡纳滨对虾肌肉中琥珀酸脱氢酶(SDH)活力和肝胰腺中电子传递系统(ETS)活力(P<0.05),胞外蛋白粗提物对肝胰腺中的SDH活力也有显著的提高作用(P<0.05)。饲喂2种粗提物显著降低了凡纳滨对虾肝胰腺及肌肉组织中脂肪酸合酶(FAS)含量(P<0.05)。此外,饲喂2种粗提物均会显著提高凡纳滨对虾肠道蛋白酶活力(P<0.05),而胞外蛋白粗提物使凡纳滨对虾肠道脂肪酶活力显著降低(P<0.05)。白斑综合征病毒(WSSV)感染后,与对照组相比,胞外蛋白组和胞内多糖组凡纳滨对虾半致死时间分别延长了26.19%和7.14%。根据以上结果推测,芽苞杆菌2种粗提物能够影响凡纳滨对虾能量代谢水平并提高其抗WSSV能力,且二者之间密切相关。 相似文献
20.
《Deep Sea Research Part I: Oceanographic Research Papers》2005,52(9):1745-1765
Occurrence of 130 species of decapod crustaceans was compared between the continental slope (200–2500 m) and the abyssal plain (2500–3840 m) of the Gulf of Mexico. We compiled records of these species from published literature and from the crustacean catalogue of the Marine Invertebrate Collection of Texas A&M University. Each species was scored as present or absent in each of 10 polygons that were defined by physiographic features of the sea floor. Using cluster analysis, we identified inherent patterns of species richness. A distinct faunal assemblage occurred in the Sigsbee Abyssal Plain. This deep plain was a potential “coldspot” in terms of the number of species in the basin, compared to a “hotspot” in the vicinity of De Soto Canyon. Polygons of the eastern upper slopes (i.e. calcareous substrate of western Florida) contained the most species that were not found elsewhere in the Gulf of Mexico. Using an inductive approach, we identified the following hypotheses: (1) most crustacean species of the deep Sigsbee Abyssal Plain occur in oceans world-wide, (2) overall, almost a quarter of the deep sea species in the Gulf of Mexico range from the western Atlantic (south of Cape Hatteras) to the Caribbean, and (3) the Gulf of Mexico is particularly rich in species of Munidopsis (25 species). 相似文献