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1.
以班公湖-怒江缝合带西段的去申拉组玄武岩和安山岩为研究对象,进行了岩石锆石测年和地球化学研究。测年结果显示,安山岩形成于108.5±1.5Ma,属于早白垩世晚期。岩石地球化学特征表明,野马去申拉组玄武岩Nb含量为10.5×10-6～11.1×10~(-6),Al_2O_3含量为17.63%～17.96%(平均值17.74%),属于富Nb高铝玄武岩,为中钾钙碱性系列;安山岩属于高钾钙碱性系列岩石。野马火山岩轻、重稀土元素分异明显,其中玄武岩稀土元素总量为119.20×10~(-6)～120.49×10~(-6),(La/Yb)_N值为5.17～5.53;安山岩稀土元素总量为179.97×10~(-6)～184.75×10~(-6),(La/Yb)_N值为13.83～15.12;二者在微量元素上表现出不同程度的富集轻稀土元素和大离子亲石元素,Nb、Ta、Ti等高场强元素相对亏损,具低Cr、Ni,高Sr、Nb、Zr含量,发育岛弧火山岩相关特征。其岩浆源区受俯冲流体的影响较大,后经历了不同程度的铁镁矿物的结晶分离作用。综合分析认为,野马去申拉组火山岩可能形成于弧后盆地构造环境下,是班公湖-怒江特提斯洋岩石圈南向俯冲过程中板片断离导致软流圈地幔上涌,诱发弧后拉张背景下的直接岩浆响应。 相似文献
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对孤山子基性-超基性岩体的岩相学、锆石U-Pb年代学和全岩地球化学等方面研究,确定了该岩体的形成时代、岩石成因及其形成的构造环境。该杂岩体主要由辉石岩和角闪辉石岩组成,元素地球化学上,贫SiO_2(34.28%~49.22%)、K_2ONa_2O、富MgO(4.54%~13.26%)特征,属碱性系列岩石。岩石稀土元素球粒陨石标准化配分模式为轻稀土富集型,(La/Yb)_N=8.14~36.19,Eu异常不明显,稀土元素原始地幔标准化分布模式相似,为上地幔富集地幔熔融。岩石富集大离子亲石元素(如Rb、Ba、K)和LREE(如La和Ce),明显亏损高场强元素(Nb、Ta、Ti)和HREE。样品Nb/U、Ce/Pb和La/Sm比值显示岩体经历了有限的地壳混染。锆石的LA-ICP-MS U-Pb年代学研究表明,岩石锆石U-Pb年龄分为3类:一类锆石U-Pb年龄为(1 392±10)Ma,应为孤山子超基性侵入体侵位过程中捕获的碎屑锆石;第二类锆石U-Pb年龄为(274.5±2.1)Ma,为岩浆侵位时形成的锆石;第三类锆石U-Pb年龄为(53.02±1.1)Ma,为热液锆石。研究认为,岩体的岩浆源区主要为亏损地幔,可能受晚古生代古亚洲洋俯冲洋壳的脱出流体迭加作用和地壳物质的混染。结合区域构造演化,认为岩体形成于古亚洲洋闭合后挤压向伸展转换的构造背景。 相似文献
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大西营子金矿区位于内蒙古赤峰地区,金矿赋存在玛尼吐组火山岩中。对大西营子金矿区赋矿围岩进行了岩石学、锆石U-Pb年代学和岩石地球化学研究。矿区火山岩主要包括安山岩、粗安岩、粗面岩和火山碎屑岩。通过锆石LA-ICP-MS U-Pb定年,获得安山岩和粗安岩年龄分别为(157.8±6.2)Ma和(156.9±7.4)Ma,应代表其形成年龄。岩石地球化学数据显示该套火山岩具有相对富碱、富铝的特征,属于高钾钙碱性和碱性岩石系列。岩石富集轻稀土元素和大离子亲石元素(Th、U、Zr、Hf),亏损重稀土元素和Nb、Ta、Ti等高场强元素。这些特征显示岩浆来自被俯冲流体交代富集的岩石圈地幔,且经历了以单斜辉石为主的结晶分异过程。结合区域地质资料,认为在大西营子金矿区火山岩形成于造山后伸展环境,与蒙古—鄂霍茨克洋闭合作用有关。 相似文献
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西准噶尔松树沟地区地层主要由碎屑沉积岩和火山岩组成,以玄武岩、安山岩和火山碎屑岩为主,其中玄武岩属于钙碱性系列,安山岩属于拉斑系列。对岩石中锆石开展LA-ICP-MS锆石U-Pb年代学研究,安山岩锆石年龄表明其形成于(317.1±6.4)Ma,粗砂岩56颗锆石中仅有1颗锆石年龄((389±9)Ma)属于中泥盆世,其余主要集中在319~359 Ma,最小年龄(319±6)Ma。因此,该套地层并非形成于中泥盆世,很可能形成于晚石炭世早期。地球化学研究表明,玄武岩和安山岩具有相似的稀土配分曲线,轻稀土富集的右倾REE分配模式,富集大离子亲石元素K、Rb、Ba、Sr等,亏损高场强元素Nb、Ta、Th、Zr、Hf等,呈现出Ta、Nb、Ti负异常,认为该火山岩形成于岛弧环境,岩浆来源于俯冲板片脱水产生的流体不均一交代的地幔楔。该套岛弧火山岩的形成时代限定了斋桑洋盆的关闭时限(晚于317.1 Ma)。 相似文献
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内蒙古东南部巴林右旗地区发育晚二叠世埃达克质火山岩,岩石组合为安山岩、粗安岩、英安岩及辉石安山岩,其LA-ICP-MS锆石U-Pb测年结果为256.7±2.7Ma,指示其形成于晚二叠世。地球化学特征显示,该套火山岩属准铝质-弱铝质中钾钙碱性岩石系列,具富Si(SiO_256%)、高Al(Al_2O_315%)、富Na、贫K、高Sr、低Yb和Y等特征,Na_2O/K_2O值为2.33~3.90,Mg~#值为35.3~60.8;稀土元素总量为96.69×10~(-6)~192.4×10~(-6)、轻重稀土元素分馏较明显((La/Yb)_N值为6.27~13.82),具正的Eu(δEu=1~1.67)异常,在原始地幔标准化蛛网图中,富集大离子亲石元素Rb、Ba、U,亏损高场强元素Nb、Ta,为O型(大洋型)埃达克质火山岩地球化学特征。综合区域资料,巴林右旗埃达克质火山岩是残留在地幔中的古亚洲洋残余洋壳部分熔融并受到地幔橄榄岩混染形成的,暗示晚二叠世存在古亚洲洋向华北板块俯冲消亡事件。 相似文献
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南秦岭城口火山岩锆石LA-ICP-MS U-Pb定年和地球化学研究 总被引：3，自引：0，他引：3
南秦岭大巴山城口断裂带出露一套玄武安山岩、安山岩组合,火山岩锆石LA-ICP-MS U-Pb定年测试结果为716±4Ma,表明其为新元古代岩浆产物;岩石地球化学研究表明火山岩富集轻稀土元素,原始地幔标准化微量元素蛛网图显示以富集大离子亲石元素Cs、Ba、Th、U及高场强元素分异为特征,Nb、Ta强烈亏损以及低的Ti(Ti O_20.85%)含量,与典型的岛弧火山岩相似;微量元素La/Nb、Th/Yb及Hf/Ta比值特征也显示岛弧岩浆属性,相对高的Zr/Y、Ta/Yb和低的Zr/Nb比值区别于大洋岛弧火山岩,具有明显的大陆亲缘性,表明城口火山岩形成于陆缘岛弧环境。综合已有的地质、地球化学及同位素年代学研究表明新元古代晚期扬子板块北缘及南秦岭地区为一活动陆缘岩浆杂岩弧,暗示中国华南板块很可能位于Rodinia超大陆的边缘部位。 相似文献
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拉脊山构造带南东端磨沟地区出露一套变安山岩夹片理化变玄武岩组合,其原岩分别为亚碱性拉斑系列安山岩和玄武岩。研究表明,变安山岩锆石U-Pb年龄为503.1±6.6Ma,形成于中寒武世。玄武岩稀土元素总量为93.40×10~(-6)～135.39×10~(-6),(La/Yb)_N值为2.76～3.64,δEu为0.87～1.00,微量元素蛛网图具有不相容元素富集特征,没有明显的Nb、Ta负异常,与板内火山岩特征相似。安山岩稀土元素总量低于玄武岩,而微量元素蛛网图具有富集大离子亲石元素Cs、Rb、Ba等,亏损高场强元素Nb、Ta、Ti等特征。岩石成因研究表明,玄武岩没有经历显著的地壳混染,为软流圈地幔石榴子石+尖晶石二辉橄榄岩低程度部分熔融的产物,而安山岩为地壳部分熔融的产物。构造环境判别表明,深沟组火山岩形成于大陆裂谷环境,表明祁连地块中部的拉脊山构造带南东端可能没有发育成熟的洋盆系统,随后在南祁连洋早古生代俯冲消减过程中以裂谷型岩石圈碎片的方式构造侵位于中祁连地块南缘。 相似文献
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内蒙古赤峰敖汉旗一带的朝吐沟组火山岩由变玄武岩、变流纹岩组成,是一套典型的"双峰式"火山岩组合。采用LA-ICP-MS锆石U-Pb测年方法,获得了流纹岩的锆石206Pb/238U加权平均年龄分别为(359±1)Ma和(360±1)Ma,形成于晚泥盆世法门期。火山岩的Si O2含量分布在46.24%~56.6%和77.59%~85.75%,分别属于变玄武岩(玄武安山岩)和变流纹岩。变玄武岩(玄武安山岩)轻稀土元素弱富集而重稀土元素略亏损,(La/Yb)N=2.4~8.76,有弱Eu负异常,富集大离子亲石元素和高场强元素,Nb、Ta、Ti有明显负异常,87Sr/86Sr初始比值为0.705076~0.707770,具有高的正εNd(t)值(+0.51~+4.90)和年轻的模式年龄TDM(964~1090 Ma),推断其源于遭受地壳物质混染的亏损地幔;变流纹岩富硅、钾和钠,贫镁,具有轻稀土元素富集而重稀土元素略亏损,(La/Yb)N=7.07~11.07,有强烈的Eu负异常(δEu=0.12~0.43),Ti、P、Sr、Ba相对强烈亏损,Nb、Ta亏损,Rb、Th、U、K相对富集;其87Sr/86Sr初始比值为0.713757~0.739647,εNd(t)值为-1.75~+2.54),和年轻的模式年龄TDM(846~1156 Ma);多数锆石的εHf(t)为-2.3~+6.9,年轻的模式年龄TDM(707~1074 Ma),具有A型花岗岩的特征,推测其来源为新元古代时新生的年轻陆壳。综合前人区域研究成果、地球化学特征,朝吐沟组"双峰式"火山岩形成于晚泥盆世板内伸展构造背景。 相似文献
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大兴安岭十八站—韩家园地区发育晚中生代基性-中酸性火山岩。选取粗面安山岩、粗面岩、流纹岩进行年代学和岩石地球化学研究。粗面安山岩LA-ICP-MS锆石U-Pb年龄为125.2±0.9 Ma,为早白垩世火山作用的产物。岩石地球化学特征表明,中酸性火山岩属于高钾钙碱性-钾玄岩系列。岩石稀土元素总量∑REE=121.42×10~(-6)~154.43×10~(-6),轻、重稀土元素分异明显(La/Yb)_N=19.25~31.98,在稀土元素配分图上显示右倾型,除一个流纹岩样品具显著负Eu异常外,多数样品无明显Eu负异常(δEu=0.45~0.90)。岩石具弱富集大离子亲石元素Ba、Sr,明显亏损高场强元素Nb、Ta、Ti的特征。结合区域资料,认为十八站—韩家园地区早白垩世中酸性火山岩形成于蒙古-鄂霍茨克洋闭合机制下后碰撞伸展背景。粗面安山岩、粗面岩和流纹岩系同源岩浆部分熔融与结晶分异作用的结果,岩浆来源于受俯冲流体交代的富集岩石圈地幔。 相似文献
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位于南海北部陆缘的珠江口盆地发育中生代岩浆岩,记录了古太平洋板片俯冲消亡的动力学过程。本项研究以钻井揭露的晚侏罗世火山岩为研究对象,开展系统的岩石学、岩相学、年代学和地球化学研究,探讨其成因机制和动力学背景。岩石学及地球化学分析显示,这套火山岩由玄武岩、玄武安山岩、安山岩和粗面安山岩组成。LA-ICP-MS锆石U-Pb年代学分析表明,玄武安山岩的结晶年龄为154.0±3.2 Ma。岩石的SiO2含量为49.54%～58.22%,K2O含量为0.71%～3.00%,MgO含量为5.29%～11.05%,Mg#值介于52～66之间,属于高钾钙碱性系列中基性火山岩。岩石的轻重稀土元素分馏明显,(La/Yb)N比值为5.00～6.93,且具有轻微的铕负异常,δEu值为0.73～1.04。样品显著富集大离子亲石元素Rb、Ba、Th和U等,相对亏损高场强元素Nb、Ta、Ti和P等。岩石成因分析表明,晚侏罗世中基性火山岩主要起源于受俯冲板片流体交代的富集岩石圈地幔熔融,且岩浆经历了辉石、角闪石等矿物的分离结晶。综... 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
19.
Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
20.
Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献