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内蒙古阿拉善右旗杭嘎勒晚二叠世闪长岩地球化学特征和LA-ICP-MS锆石U-Pb定年 总被引：3，自引：0，他引：3
阿拉善右旗杭嘎勒地区晚三叠闪长岩轻稀土元素明显富集,大部分具正Eu异常,显示I型花岗岩的特点。Rb、Sr、Hf富集,而Nb、P、Ti亏损,显示出与俯冲有关的侵入岩特征。在R1-R2图解上,大部分样品集中在碰撞前花岗岩区;在Nb-Y图解上,样品落在火山弧-同碰撞花岗岩区;在Rb-(Y+Nb)图解上,样品点落在火山弧花岗岩区;在Rb-Hf-Ta图解上,样品全部落在弧系统岩石区。LA-ICP-MS锆石U-Pb定年表明其年龄为(257.1±4.0)Ma。杭嘎勒晚二叠世闪长岩为碰撞前火山弧花岗岩,研究区在晚二叠世时属于活动大陆边缘的火山弧。 相似文献
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杭嘎勒地区中二叠世石英闪长岩,轻重稀土分馏程度较强,无明显铕异常,稀土配分曲线为向右倾,属轻稀土富集型。中二叠世石英闪长岩显示了I型花岗岩的特点。中二叠世石英闪长岩表现出元素Th、Ta、Sr、Hf元素富集,而Nb、La、P元素亏损。AR-SiO2图解显示,主体与包体岩石虽同属钙碱性+拉斑玄武系列区,显示了同源岩浆演化的特点,在R1-R2图解上,大部分样品集中在碰撞前与碰撞后花岗岩区分界处,以碰撞前为主;在Nb-Y图解上,样品落在了火山弧-同碰撞花岗岩区;在Rb-Y+Nb图解上,样品落在了火山弧花岗岩区,反映石英闪长岩形成于板块边缘的岩浆弧环境。LA-ICP-MS锆石U-Pb定年表明主体岩石年龄(266.4±3.7)Ma。杭嘎勒晚二叠世花岗闪长岩为碰撞前火山弧花岗岩,研究区在晚二叠世时属于活动大陆边缘的火山弧。 相似文献
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杭嘎勒晚二叠世二长花岗岩富碱,贫MgO、TFeO、CaO,轻稀土元素明显富集,具弱负Eu异常,显示I型花岗岩的特点。Nb、Sr、P、Ti元素亏损,显示出与俯冲有关的侵入岩特征。在R1-R2图解上,大部分样品集中在碰撞前与碰撞后花岗岩区的分界处,以碰撞前为主;在Nb-Y图解上,样品落在火山弧-同碰撞花岗岩区;在Rb-（Y＋Nb）图解上,样品点落在火山弧花岗岩区;在Rb-Hf-Ta图解上,样品全部落在弧系统岩石区。主体岩石中锆石Th/U值高,显示出岩浆锆石的特征,稀土元素总量高,重稀土元素富集明显,球粒陨石标准化图解曲线左倾,与岩浆锆石稀土元素配分曲线总体特征趋于一致。LA-ICP-MS锆石U-Pb定年表明其年龄为（253.5±7.9）Ma。杭嘎勒晚二叠世二长花岗岩为碰撞前火山弧花岗岩,研究区在晚二叠世时属于活动大陆边缘的火山弧。 相似文献
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内蒙古阿拉善右旗杭嘎勒晚二叠世二长花岗岩
地球化学特征和LA-ICP-MS锆石U-Pb定年 总被引：5，自引：1，他引：4
杭嘎勒晚二叠世二长花岗岩富碱,贫MgO、TFeO、CaO,轻稀土元素明显富集,具弱负Eu异常,显示I型花岗岩的特点。Nb、Sr 、P、Ti元素亏损,显示出与俯冲有关的侵入岩特征。在R1-R2图解上,大部分样品集中在碰撞前与碰撞后花岗岩区的分界处,以碰撞前为主;在Nb-Y图解上,样品落在火山弧-同碰撞花岗岩区;在Rb-（Y+Nb）图解上,样品点落在火山弧花岗岩区;在Rb-Hf-Ta图解上,样品全部落在弧系统岩石区。主体岩石中锆石Th/U值高,显示出岩浆锆石的特征,稀土元素总量高,重稀土元素富集明显,球粒陨石标准化图解曲线左倾,与岩浆锆石稀土元素配分曲线总体特征趋于一致。LA-ICP-MS锆石U-Pb定年表明其年龄为（253.5±7.9）Ma。杭嘎勒晚二叠世二长花岗岩为碰撞前火山弧花岗岩,研究区在晚二叠世时属于活动大陆边缘的火山弧。 相似文献
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内蒙古狼山山脉西侧分布有大面积的晚古生代岩浆岩,其时代集中在早石炭世—晚二叠世,不同时代岩浆岩岩石组合对于认识狼山地区晚古生代构造背景具有重要的意义。文章通过岩石学、岩相学、地球化学及Hf同位素等方法,对狼山地区查干乃呼都格一带花岗闪长岩体进行了研究。该岩体岩性为花岗闪长岩,LA-ICP-MS锆石U-Pb年龄显示,其206Pb/238U加权平均年龄为(299±1)～(293±2) Ma。岩石暗色矿物为角闪石及黑云母,富含闪长质包体,P_2O_5含量与SiO_2含量之间显示良好的负相关性,富钠(Na_2O含量为3.45%～4.96%),高钠钾比值(Na_2O/K_2O比值为1.33～2.52),岩石地球化学特征显示花岗岩成因类型为Ⅰ型花岗岩。岩石具有负的ε_(Hf)(t)值(-6.3～-2.0)及T_(DM2)为1437～1704 Ma(平均值为1606 Ma),显示了古—中元古代古老地壳熔融的特点,ε_(Hf)(t)-t及角闪石成因图解显示源区有幔源岩浆参与。花岗岩富集大离子亲石元素Rb、K、Pb,不同程度的亏损高场强元素Nb、Ta、P、Ti,轻稀土富集,重稀土亏损,弱的负Eu异常,显示了岩浆弧的地球化学特征。结合晚石炭世—早二叠世狼山地区侵入岩岩石组合为闪长岩+石英闪长岩+花岗闪长岩(英云闪长岩),早—中二叠世大石寨组火山岩岩石组合为玄武岩+玄武安山岩+安山岩+英安岩,总体反映了陆缘弧的岩石组合;狼山地区早二叠世处于大陆边缘弧的构造背景,与华北地块北缘中东部可以对比。 相似文献
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对伊春地区南部中寒武世细中粒二长花岗岩进行LA-ICP-MS锆石U-Pb定年,岩石年龄为(504.1±5.4)Ma,是中寒武世岩浆活动的产物。岩石地球化学特征显示该岩石具富碱、富钾的特征,高K2O/Na2O,低TFeO,属钾玄至高钾钙碱性系列。岩石总体上相对富集大离子亲石元素,亏损高场强元素,A/CNK＞1.1,为强过铝质,显示出S型花岗岩的特征。R1-R2图解上大部分样品集中在同碰撞区和造山晚期花岗岩区;Rb-Hf-Ta图解上样品落在同碰撞-碰撞后构造花岗岩区;在Nb-Y图解上样品落在火山弧-同碰撞花岗岩区;在Rb-(Y+Nb)图解上,样品落在同碰撞花岗岩区。该地区中寒武世细中粒二长花岗岩揭示了岩石形成于板块碰撞作用,表明伊春地区在中寒武世存在碰撞造山事件。在该时期佳木斯与松嫩—张广才岭板块已经拼合,并形成具有壳源特征的同碰撞花岗岩。 相似文献
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东昆仑东段发育了一条晚二叠世-中三叠世以花岗质岩石为主的巨型弧岩浆岩。本文对东昆仑东段的中三叠世乌妥花岗岩体开展了岩石学、LA-ICP-MS锆石U-Pb年代学及地球化学研究。结果表明,乌妥花岗岩体主要包括花岗闪长岩、斑状二长花岗岩和正长花岗岩三种岩石类型,对应的锆石U-Pb年龄分别为248Ma、247Ma和245Ma,形成时代为中三叠世。主量元素特征显示其具有高钾钙碱性、准铝质-弱过铝质的I型花岗岩的属性。球粒陨石标准化稀土元素配分图解具轻稀土明显富集、重稀土亏损和Eu弱负异常-强负异常特征。原始地幔标准化微量元素蛛网图显示富集大离子亲石元素(Cs、Rb、Th、Ba、U等)、亏损高场强元素(Nb、Ti、Ta等)、而Zr和Hf无明显异常的特点。乌妥岩体总体具有负的Hf同位素组成特征,花岗闪长岩εHf(t)为-1. 5～+3. 4、斑状二长花岗岩εHf(t)为-4. 1～-0. 6、正长花岗岩εHf(t)为-6. 9～-0. 9。多种微量元素构造环境判别图解表明其形成于类似安第斯型陆缘弧的构造环境。岩石成因研究表明洋壳俯冲带上部壳幔接触过渡部位多次岩浆MASH过程及分离结晶作用是形成乌妥花岗岩体的重要方式。综合前人东昆仑地区有关三叠纪沉积地层及岩浆岩资料,认为布青山-阿尼玛卿古特提斯洋于晚二叠世向北俯冲于东昆仑地块之下,弧岩浆岩记录的布青山古特提斯洋盆向北俯冲过程一直持续到中三叠世晚期。晚三叠世,东昆仑南缘古特提斯洋盆关闭,东昆仑造山带转换为碰撞及后碰撞造山阶段,并形成了区域上具碰撞构造属性的侵入岩。 相似文献
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滇西粱河勐养花岗岩的锆石U-Pb年龄、地球化学特征及其地质意义 总被引：3，自引：0，他引：3
勐养侵入岩体位于滇西腾冲地块梁河县南勐养镇一带,主要由黑云母二长花岗岩和花岗闪长岩组成,其中发育闪长质包体。闪长岩包体与寄主岩石黑云母二长花岗岩和花岗闪长岩之间呈渐变过渡关系。锆石U-Pb LA-ICP-MS定年表明,黑云母二长花岗岩形成年龄为127.7Ma±0.7Ma,花岗闪长岩形成年龄为115.2Ma±1.1Ma。闪长岩包体形成年龄为122.6Ma±0.8 Ma。表明该花岗岩体的形成时代属于早白垩世。地球化学特征研究表明,闪长岩包体为准铝质、钙碱性系列,具有低SiO2、高MgO、高K20和Mg#的特征。Sm/Nd为0.18～0.20,ΣLREE/ΣHREE=2.91～4.64,Eu存在弱到中等程度的负异常。相对富集U,Th,Rb,Ba等大离子亲石元素(LILE),亏损Tb,Nb,Zr,Hf等高场强元素(HFSE);反映勐养闪长岩包体岩浆成分主要为幔源的特点。根据地球化学特征和微量元素构造判别图解判别结果表明,勐养早白垩世侵入岩形成于碰撞后岩浆弧环境。闪长岩包体的原生岩浆应是地幔橄榄岩部分熔融的产物。黑云二长花岗岩浆可能来源于本区中晚元古代高黎贡山群为代表的地壳物质的部分熔融。花岗闪长岩为幔源岩浆与高黎贡山群古老地壳部分熔融的岩浆混合的产物。腾冲地块早白垩世侵入岩与班公湖—怒江—泸水—瑞丽洋盆的闭合、洋壳向南西俯冲及板块间的碰撞造山作用密切相关。 相似文献
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内蒙古阿拉善右旗塔木素地区酸性侵入岩锆石U-Pb年龄与地球化学特征 总被引：1，自引：0，他引：1
内蒙古阿拉善地块北缘塔木素地区酸性侵入岩发育,主要岩性为黑云母花岗岩、花岗闪长岩、二长花岗岩、英云闪长岩,其中花岗闪长岩、英云闪长岩、二长花岗岩构成塔木素地区侵入岩的主体,岩体侵入晚石炭世—早二叠世阿木山组,又被白垩系、侏罗系不整合覆盖,区域上呈近东西向展布。采用LA-ICP-MS技术,测得内蒙古阿拉善右旗塔木素地区的塔木素二长花岗岩和笋布尔英云闪长岩中锆石的206Pb/238U年龄分别为264.2±3.3Ma和273.0±3.3Ma,这2个年龄被解释为各自的侵位年龄,即二者均形成于中二叠世。花岗闪长岩、二长花岗岩和英云闪长岩在Si O2-K2O图解中落入钙碱系列和高钾钙碱性系列,A/CNK值分别为0.874~1.01、1.06~1.54和0.91~1.03;Ba、Rb、Th、K等大离子亲石元素富集,Nb、Ta、P、Ti等高场强元素相对亏损;稀土元素总量分别介于156.99×10-6~212.87×10-6、126.92×10-6~212.98×10-6和128.13×10-6~214.5×10-6之间,均呈负Eu异常;在构造环境Rb-(Yb+Nb)和Rb-(Yb+Ta)判别图解中均落入火山弧花岗岩区。结合区域背景分析,阿拉善北缘在早二叠世时可能存在与弧物质有关的岩浆活动。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
18.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
19.
Marta L. PATINO-DOUCE Alberto PATINO-DOUCE Mazhar QAYYUM Roger L. NIELSEN 《Geostandards and Geoanalytical Research》1994,18(2):195-198
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2 O3 -SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses. 相似文献
20.
Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献