A Study on the Surface Wettability of Clastic Rocks with Potential Application for CO2 Storage Sites     

Umar  Bappah Adamu  Gholami  Raoof  Raza  Arshad  Downey  William Samuel  Sarmadivaleh  Mohammad  Shah  Afroz A.  Nayak  Prasanta 《Natural Resources Research》2020,29(3):2051-2061

Natural Resources Research - There have been many studies carried out in the past decades attempting to develop strategies for a safe injection of CO2 into storage sites without leakage and...  相似文献   

Quantitative elemental mapping of granulite-facies monazite: Textural insights and implications for petrochronology     

Owen M. Weller  Simon Jackson  William G. R. Miller  Marc R. St-Onge  Nicole Rayner 《Journal of Metamorphic Geology》2020,38(8):853-880

Texturally complex monazite grains contained in two granulite-facies pelitic migmatites from southern Baffin Island, Arctic Canada, were mapped by laser ablation-inductively coupled plasma-mass spectrometry (using spot sizes ≤5 µm) to quantitatively determine the spatial variation in trace element chemistry (with up to 1,883 analyses per grain). The maps highlight the chemical complexity of monazite grains that have experienced multiple episodes of growth, resorption and chemical modification by dissolution–precipitation during high-grade metamorphism. Following detailed chemical characterization of monazite compositional zones, a related U–Pb data set is re-interpreted, allowing petrologically significant ages to be extracted from a continuum of concordant data. Synthesis of these data with pseudosection modelling of prograde and peak conditions allows for the temporal evolution of monazite trace element chemistry to be placed in the context of the evolving P–T conditions and major phase assemblage. This approach enables a critical evaluation of three commonly used petrochronological indicators: linking Y to garnet abundance, the Eu anomaly to feldspar content and Th/U to anatectic processes. Europium anomalies and Th/U behave in a relatively systematic fashion, suggesting that they are reliable petrochronological witnesses. However, Y systematics are variable, both within domains interpreted to have grown in a single event, between grains interpreted to be part of the same age population, and between samples that experienced similar metamorphic conditions and mineral assemblages. These observations caution against generalized petrological interpretations on the basis of Y content, as it suggests Y concentrations in monazite are controlled by domainal equilibria. The results reveal a c. 45 Myr interval between prograde metamorphism and retrograde melt crystallization in the study area, emphasizing the long-lived nature of heat flow in high-grade metamorphic terranes. Such long timescales of metamorphism would be assisted by the growth, retention and dominance of high-Th suprasolidus monazite, as observed in this study, contributing to the radiogenic heating budget of mid- to lower-crustal environments. Careful characterization of monazite grains suggests that continuum-style U–Pb data sets can be decoded to provide insights into the duration of metamorphic processes.  相似文献   

Peroxymonosulfate Improves the Activity and Stability of Manganese Oxide for Oxidation of Arsenite to Arsenate     

Yong Liu  Fen Zhang  Jingtao Hou  William Hartley 《洁净——土壤、空气、水》2020,48(2)

Manganese oxide has been widely investigated for oxidation of arsenite (As(III)) to arsenate (As(V)) due to its high redox potential; however, it becomes extremely unstable after reuse. Here, As(III) oxidation activity and stability of manganese oxide in the presence of peroxymonosulfate (PMS) is investigated. Batch experimental results reveal that manganese oxide/PMS exhibits high catalytic activity for As(III) oxidation compared to manganese oxide or PMS alone. Addition of PMS to manganese oxide not only reveals long‐term stability for As(III) oxidation, but also shows high As(III) oxidation activity in the presence of coexisting ions such as As(V) and phosphate. Quenching tests reveal that As(III) oxidation in the manganese oxide/PMS system is attributed to activation of PMS by manganese oxide at different oxidation states (Mn(III) and Mn(IV)), and the generation of sulfate radicals that are responsible for As(III) oxidation.  相似文献   

Probabilistic seismic hazard assessment for some parts of the Indo-Gangetic plains,India     

Keshri  Chhotu Kumar  Mohanty  William Kumar  Ranjan  Pratul 《Natural Hazards》2020,103(1):815-843

Natural Hazards - Indo-Gangetic plains are seismically most vulnerable due to the proximity of adjacent great Himalayan earthquakes and thick alluvium deposits of the Ganga River system. As the...  相似文献   

Petrophysics and mineral exploration: a workflow for data analysis and a new interpretation framework     

Michael Dentith  Randolph J. Enkin  William Morris  Cameron Adams  Barry Bourne 《Geophysical Prospecting》2020,68(1):178-199

As mineral exploration seeks deeper targets, there will be a greater reliance on geophysical data and a better understanding of the geological meaning of the responses will be required, and this must be achieved with less geological control from drilling. Also, exploring based on the mineral system concept requires particular understanding of geophysical responses associated with altered rocks. Where petrophysical datasets of adequate sample size and measurement quality are available, physical properties show complex variations, reflecting the combined effects of various geological processes. Large datasets, analysed as populations, are required to understand the variations. We recommend the display of petrophysical data as frequency histograms because the nature of the data distribution is easily seen with this form of display. A petrophysical dataset commonly contains a combination of overlapping sub-populations, influenced by different geological factors. To understand the geological controls on physical properties in hard rock environments, it is necessary to analyse the petrophysical data not only in terms of the properties of different rock types. It is also necessary to consider the effects of processes such as alteration, weathering, metamorphism and strain, and variables such as porosity and stratigraphy. To address this complexity requires that much more supporting geological information be acquired than in current practice. The widespread availability of field portable instruments means quantitative geochemical and mineralogical data can now be readily acquired, making it unnecessary to rely primarily on categorical rock classification schemes. The petrophysical data can be combined with geochemical, petrological and mineralogical data to derive explanations for observed physical property variations based not only on rigorous rock classification methods, but also in combination with quantitative estimates of alteration and weathering. To understand how geological processes will affect different physical properties, it is useful to define three end-member forms of behaviour. Bulk behaviour depends on the physical properties of the dominant mineral components. Density and, to a lesser extent, seismic velocity show such behaviour. Grain and texture behaviour occur when minor components of the rock are the dominate controls on its physical properties. Grain size and shape control grain properties, and for texture properties the relative positions of these grains are also important. Magnetic and electrical properties behave in this fashion. Thinking in terms of how geological processes change the key characteristics of the major and minor mineralogical components allows the resulting changes in physical properties to be understood and anticipated.  相似文献   

Subsurface flow measurements using passive flux meters in variably-saturated cold-regions landscapes     

Élise G. Devoie  Ryan F. Connon  James R. Craig  William L. Quinton 《水文研究》2020,34(23):4541-4546

To date, passive flux meters have predominantly been applied in temperate environments for tracking the movement of contaminants in groundwater. This study applies these instruments to reduce uncertainty in (typically instantaneous) flux measurements made in a low-gradient, wetland dominated, discontinuous permafrost environment. This method supports improved estimation of unsaturated and over-winter subsurface flows which are very difficult to quantify using hydraulic gradient-based approaches. Improved subsurface flow estimates can play a key role in understanding the water budget of this landscape.  相似文献   

Clinoforms and clinothems: Fundamental elements of basin infill     

Claudio Pellegrini  Stefano Patruno  William Helland-Hansen  Ronald J. Steel  Fabio Trincardi 《Basin Research》2020,32(2):187-205

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ISA-Hypoplasticity accounting for cyclic mobility effects for liquefaction analysis     

Fuentes  William  Wichtmann  Torsten  Gil  Melany  Lascarro  Carlos 《Acta Geotechnica》2020,15(6):1513-1531

Acta Geotechnica - The hypoplastic model for sands proposed by Wolffersdorff (Mech Cohes Frict Mater 1: 251–271, 1996) combined with the intergranular strain anisotropy by Fuentes and...  相似文献   

Urban Primacy before Mark Jefferson     

William B. Meyer 《Geographical review》2019,109(1):131-145

The phenomenon of urban primacy has been much studied in the social sciences since Mark Jefferson introduced the term in 1939. It is less well recognized that many European and American writers of stature from the late seventeenth century onward had discussed the same phenomenon under other names, often that of a “capital” or its cognates in other languages. Their work attests to the wide currency that the concept enjoyed and offered many important suggestions regarding urban primacy's causes and consequences. Jefferson nonetheless remains a central figure in the history of the idea for having inaugurated the coordinated academic study of the topic.  相似文献   

The impact of submersed aquatic vegetation on the development of river mouth bars     

Sara Lera  William Nardin  Lawrence Sanford  Cindy Palinkas  Roberto Guercio 《地球表面变化过程与地形》2019,44(7):1494-1506

This work is inspired by the sudden resurgence of the submersed aquatic vegetation (SAV) bed in the Chesapeake Bay (USA). Because the SAV bed occurs at the mouth of the Bay's main tributary (Susquehanna River), it plays a significant role in modulating sediment and nutrient inputs from the Susquehanna to the Bay. Previous model studies on the impact of submersed aquatic vegetation on the development of river mouth bars lacked a complete mechanistic understanding. This study takes advantage of new advances in 3D computational models that include explicit physical-sedimentological feedbacks to obtain this understanding. Specifically, we used Delft3D, a state-of-the-art hydrodynamic model that provides fine-scale computations of three-dimensional flow velocity and bed shear stress, which can be linked to sediment deposition and erosion. Vegetation is modeled using a parameterization of hydraulic roughness that depends on vegetation height, stem density, diameter, and drag coefficient. We evaluate the hydrodynamics, bed shear stresses, and sediment dynamics for different vegetation scenarios under conditions of low and high river discharge. Model runs vary the vegetation height, density, river discharge, and suspended-sediment concentration. Numerical results from the idealized model show that dense SAV on river mouth bars substantially diverts river discharge into adjacent channels and promotes sediment deposition at ridge margins, as well as upstream bar migration. Increasing vegetation height and density forms sandier bars closer to the river mouth and alteration of the bar shape. Thus, this study highlights the important role of SAV in shaping estuarine geomorphology, which is especially relevant for coastal management. © 2019 John Wiley & Sons, Ltd.  相似文献